锂二次电池中的原位聚合电解质

聚合物电解质主要分为凝胶聚合物电解质和固态聚合物电解质两种类型,均能够提升锂二次电池的性能。其中,凝胶聚合物电解质是利用增塑剂实现聚合物基质的凝胶化,将有机液态电解液固定在三维网络结构中,因此同时具备液态的离子扩散速率和固态材料的机械性能;而固态聚合物电解质是一种完全没有液态电解质的体系,利用聚合物基体的极性实现锂盐的解离,以聚合物分子链的运动实现离子传输。相对于传统的非原位法制备的聚合物电解质而言,原位聚合反应制备的聚合电解质能够有效改善电解质与电极的界面相容性、简化电池组装工艺、降低制造成本。本文综述了当前原位聚合电解质在锂二次电池中应用的研究进展,并展望了原位聚合电解质的应用前景和未来挑战。     

Effect of aluminum co-doping on the formation of Yb2+ in Ytterbium-doped high silica glass

Yb3+ singly doped and Yb3+/Al3+ co-doped high silica glass samples are prepared,and their luminescent properties are investigated.Al3+ is considered as a beneficial activator for Yb3+-doped glass.However,the experimental result shows that the addition of Al3+ results in the transformation from Yb3+ to Yb2+ and the improvement in the photon luminescence of Yb2+.These characteristics indicate the role of Al3+ in Yb3+-doped glass.     

Investigations of ionization-induced injection of laser wake field acceleration using phenomenological model

We develop a phenomenological model to investigate dynamics of ionization-induced injection. In the ＂bubble＂ regime of laser wakefield acceleration （LWFA）, it is found that there is an upper limit for laser intensity of ionization-induced injection. In the plane perpendicular to the laser polarization, when the laser pulse is linearly polarized, ionization-induced injected electrons exhibit a filamented structure and semi-coherent betatron oscillation.     

地方应用型本科院校大学数学课程考研策略探索与研究

将差异化、个性化的课堂教学和针对性、系统性的考研辅导进行有机结合,对大学数学课程的考研策略进行了探索和研究.     

采用量子含时波包方法研究H/D+Li_2→LiH/LiD+Li反应

采用量子波包方法和二阶分裂算符方法对H/D+Li_2→LiH/LiD+Li反应在0.01到0.4 eV的碰撞能范围内进行了动力学计算.在态分辨的理论水平上计算了反应概率、积分截面、微分截面等动力学性质并与之前的理论结果进行了比较.结果表明:由于本文的计算中包含了总角动量J在体固定坐标轴上的所有投影所得,结果更加精确;此外,当H原子被重的同位素原子D取代,反应概率、积分截面增大,然而这并没有对反应机理产生大的影响.前后对称的微分截面表明插入反应机理在反应过程中占据主导地位.     

二维非均匀水沙模型的有限元数值模拟

利用差分流线扩散法和特征有限元方法对二维水沙数学模型进行了数值模拟,并给出了相应的误差分析.     

Developments in laser wakefield accelerators:From single-stage to two-stage

Laser wakefield accelerators(LWFAs)are compact accelerators which can produce femtosecond high-energy electron beams on a much smaller scale than the conventional radiofrequency accelerators.It is attributed to their high acceleration gradient which is about 3 orders of magnitude larger than the traditional ones.The past decade has witnessed the major breakthroughs and progress in developing the laser wakfield accelerators.To achieve the LWFAs suitable for applications,more and more attention has been paid to optimize the LWFAs for high-quality electron beams.A single-staged LWFA does not favor generating controllable electron beams beyond 1 Ge V since electron injection and acceleration are coupled and cannot be independently controlled.Staged LWFAs provide a promising route to overcome this disadvantage by decoupling injection from acceleration and thus the electron-beam quality as well as the stability can be greatly improved.This paper provides an overview of the physical conceptions of the LWFA,as well as the major breakthroughs and progress in developing LWFAs from single-stage to two-stage LWFAs.     

六甲氧基甲基三聚氰胺-多元醇-丙烯酸酯混杂聚合体系的研究

六甲氧基甲基三聚氰胺 (HMMM) 多元醇 丙烯酸酯 酸催化剂混杂聚合体系在高温下同时进行缩聚和自由基聚合并表现出协同效应 .体系中的活泼亚甲基在HMMM的催化下被空气氧化成过氧化氢物 ;过氧化氢物在酸催化下分解成自由基进而引发自由基聚合反应 .研究结果表明 ,体系中存在固化加速的协同效应 ;同时体系中还存在热互补效应 ,丙烯酸酯的自由基聚合反应放出的热可以传递给缩聚反应 ,满足缩聚反应吸热的要求 .混杂聚合得到的高分子合金膜具有优良的机械性能和耐溶剂性能 ,这是由于在混杂聚合过程中形成了互穿聚合物网络 (IPN)结构 .使用潜酸催化剂作为酸的来源 ,可以提高体系的储存稳定性 ;交联 引发剂的使用可以拓宽它的使用范围 ;对超枝化聚合物在混杂体系中的应用也进行了初步研究     

双官能度自由基引发剂应用研究的进展

双官能度引发剂在自由基聚合中的应用不断受到重视，本文介绍了常用的双官能度引发剂，并综述了其在制备嵌段共聚物及引发乙烯类单体（如苯乙烯、氯乙烯、丙烯酰胺等）聚合的研究进展。