对乙酰基偶氮氯膦光度法测定烟草中钙的方法研究

研究了对乙酰基偶氮氯膦 ( ACCPP)与钙的显色反应 ,在 p H=8.5的氯化铵 -氨水缓冲介质中 ,乳化剂 - OP存在下 ,ACCPP与钙反应生成 1∶ 1稳定络合物 ,λmax=680 nm,ε=4 .0 1× 10 4 L· mol-1· cm-1。钙含量在 0— 2 0μg/2 5m L范围内符合比耳定律 ,方法用于烟草样品中钙含量的测定 ,结果令人满意。     

偶氮胂-Ⅲ光度法测定烟草中的钙

本文研究了偶氮胂－Ⅲ与钙的显色反应,在pH=8.5氯化铵－氨水缓冲液介质中,乳化剂－OP存在下,偶氮胂－Ⅲ与钙反应生成1：1稳定络合物,λmax=680nm,ε=2.13*10^4L.mol^-1.cm^-1 ,钙含量在0－30ug/25mL范围内符合比耳定律,该方法用于草样品中钙量的测定,结果令人满意。     

2-(2-喹啉偶氮)-1,5-苯二酚光度法测定钴的研究

钴是人体生命活动不可缺少的重要元素 ,痕量钴的测定具有重要意义。吡啶偶氮类试剂、苯并噻唑偶氮类试剂和 8-氨基喹啉类试剂用于钴的测定已有不少报道 ,但是用 2 -氨基衍生物作钴的显色剂的研究报道较少。我们合成了新试剂 2 - ( 2 -喹啉偶氮 ) - 1 ,5 -苯二酚 ( QADHB) ,并研究了其和钴的显色反应 ,方法用于维生素 B12 针剂及烟草样品中钴含量的测定 ,结果满意     

对磺酸基苯基亚甲基若丹宁光度法测定三醋酸甘油酯中的铅

本文研究了对磺酸基苯基亚甲基若丹宁与铅的显色反应,在硝酸介质中,吐温－８０存在下,ＳＢＤＲ与铅反应生成２：１稳定络合物,λｍａｘ＝５２０ｎｍ,ε＝２．９１＊１０＾４Ｌ．ｍｏｌ．ｃｍ＾－１。     

Construction of Complete Orthogonal Genuine Multipartite Entanglement State

With the development of quantum information processing, multipartite entanglement measures are needed in many cases. However, there are still no complete orthogonal genuine multipartite entanglement(GME) bases available as Bell states to bipartite systems. To achieve this goal, we find a method to construct complete orthogonal GME states, and we exclude many equivalent states by leveraging the group theory. We also provide the case of a 3-order 3-dimensional Hilbert space as an example and study the application of general results in the dense coding scheme as an application. Moreover, we discuss some open questions and believe that this work will enlighten extensive studies in this field.     

高压下MgN8晶体结构理论模拟与物性研究

基于密度泛函理论第一性原理的方法,使用CALYPSO结构搜索技术结合VASP软件,在0~100 GPa压强范围内对MgN8的晶体结构进行预测,并对预测的结构进行系统研究。结果表明:在常压下,空间群为P4/mbm的α-MgN8晶体结构的焓值最低;当压强达到24.3 GPa和68.3 GPa时发生相变,分别相变成空间群为P4/mnc的β-MgN8相和空间群为Cmcm的γ-MgN8相,两次相变均为对应体积坍塌的一级相变。电子性质计算结果表明,α-MgN8相的导带与价带之间具有3.09 eV的带隙,表明该结构具有非金属性;β相和γ相具有明显的金属特征。Bader电荷转移计算表明,随着压力的增加,Mg原子向N原子转移的电荷逐渐增多。     

基于Elman神经网络的252Cf源核系统随机中子脉冲信号识别方法

 针对²⁵²Cf自发裂变中子源构成的核信息系统,以实际所测随机中子脉冲数据的自相关函数为研究对象,借助仿真实验, 利用Elman神经网络对不同质量核材料进行识别。在实测数据的基础上,通过叠加随机抖动,模拟产生了不同质量核材料的相关函数样本,并将其用于神经网络的训练与测试,实验结果表明,训练过的Elman神经网络能够较好地识别相关函数的特征,分辨不同质量的核材料,平均识别率达到85%,综合平均误差为0.04,且具有较高的鲁棒性。     

Robustness of two-qubit and three-qubit states in correlated quantum channels

We investigate how the correlated actions of quantum channels affect the robustness of entangled states. We consider the Bell-like state and random two-qubit pure states in the correlated depolarizing, bit flip, bit-phase flip, and phase flip channels. It is found that the robustness of two-qubit pure states can be noticeably enhanced due to the correlations between consecutive actions of these noisy channels, and the Bell-like state is always the most robust one. We also consider the robustness of three-qubit pure states in correlated noisy channels. For the correlated bit flip and phase flip channels, the result shows that although the most robust and most fragile states are locally unitary equivalent, they exhibit different robustness in different correlated channels, and the effect of channel correlations on them is also significantly different. However, for the correlated depolarizing and bit-phase flip channels, the robustness of two special three-qubit pure states is exactly the same. Moreover, compared with the random three-qubit pure states, they are neither the most robust states nor the most fragile states.     

烟草制品中硫含量测定的研究

本文研究了在聚乙烯醇－乙醇介质中,硫酸根离子能和钡离子形成稳定的胶体沉淀,硫含量在０－１．０ｍｇ／２５ｍＬ范围内符合比耳定律,本方法稳定性明显优于传统的硫酸钡比浊法,与重量法无显著差异,用于烟草制品中硫的沉淀,结果令人满意。     

机械载荷作用下单边裂纹载流薄板的应力场

采用坐标变换的方式，将单边裂纹载流薄板通电瞬间由温度产生的应力场表达式中的各应力分量分离，并用极坐标进行表示．给出了Ⅰ型穿透裂纹尖端附近的应力场的表达式．最后将温度产生的应力场与单向拉伸载荷作用产生的应力场相叠加，推导出用极坐标表示的机械载荷作用下单边裂纹载流薄板的应力场的表达式，并给出算例．