微课在高中化学教学中应用的初步探索——以“乙醛”教学的微课应用模型为例

通过微课在高中化学教学中应用模型的构建,介绍了微课的选点、形式、制作、使用和管理要求,阐述了微课在课前、课堂、课后使用的方法,结合案例解析了微课的课堂教学应用。     

I2催化β-酮腈与1H-吡唑-5-胺的环化反应(英文)

开发了一种碘催化的1H-吡唑-5-胺和β-酮基腈的环化反应,用来合成吡唑并[1,5-a]嘧啶.该方法提供了获得结构多样的吡唑并[1,5-a]嘧啶衍生物的有效途径,其产率可达到良好至优秀.该方法具有反应条件简单温和、底物范围广等优点,并可以克级规模放大反应.     

中子单粒子效应研究现状及进展

回顾了中子单粒子研究的国内外发展情况,介绍了近几年西北核技术研究所在西安脉冲堆开展的低能中子单粒子效应研究进展。比较了稳态与脉冲工况下中子单粒子效应的异同性;分析了含有SRAM结构器件随着特征尺寸的减小,中子单粒子效应敏感性加剧的物理机制。分析认为目前中子单粒子效应已成为小尺寸大规模互补金属氧化物半导体器件的主要中子效应表现;中子辐射效应研究中,除了位移损伤效应以外还必需重视由中子电离造成的中子单粒子效应。     

一种摩擦学状态在线监测系统的研究

研制了一种用于船用柴油机的摩擦学状态在线监测系统。它集磨粒监测，润滑油质量监测，柴油机扭矩及时转速监测于一体，利用在线铁谱技术监测润滑油中的铁磁性磨粒，利用容栅型电容传感器在线监测污染物引起的润滑油介电常数的变化，利用光电传感器和随轴转动齿盘产生的脉冲及相位差在线测量柴油机输出轴的扭矩及瞬时转速。此外，该监测系统还可将柴油机的磨损状态与动力状态相关联，监测由于各缸爆排压力变化造成的瞬时转速变化，从     

量子点@SiO_2微球的水相合成及其在流式分析技术中的应用

通过表面配体交换将巯基硅烷包覆在量子点(QDs)表面,并与过量的硅烷共水解制备出包覆QDs的荧光硅球。该方法通过化学键合避免了QDs的泄露以及QDs荧光性质的改变,而且微球表面富集大量的巯基,为后续的反应提供活性位点。研究了反应时间、温度和搅拌速度对荧光微球形成的影响,优化条件得到了尺寸均一、单分散性的荧光微球。将荧光微球用于流式细胞分析检测,微球的数量和荧光强度能够满足流式分析检测的需要,适合制备成编码微球。     

Optical and atomic force microscopic study on step bunching in BaB2O4 crystal growth

The formation of macrostep during high-temperature phase of barium meta-borate (α-BaB 2 O 4) single crystal growth has been investigated by both optical in-situ observation system and atomic force microscopy (AFM).The insitu observation results demonstrate that the critical linear size of growing facet exceeding the size that the macrostep generates is significantly anisotropic.The critical linear sizes are around 280 μm and 620 μm for {1010} and {1010} planes,respectively.AFM study illustrates that macrostep train with a height of 150 nm～200 nm is one typical morphological feature of the as-grown crystal surface.The riser of each macrostep consists of several straight and parallel sub-steps,indicating the occurrence of step bunching.Additionally,triangular sub-steps with heights of several nanometers on the treads of the macrosteps are found to be another typical feature of surface morphology,which implies a microscopically competitive bunching of sub-steps between various crystallographic orientations.     

Deep-ultraviolet surface plasmon resonance of Al and Al_(core)/Al_2O_(3shell) nanosphere dimers for surface-enhanced spectroscopy

The localized surface plasmon resonance properties of Al and Alcore/Al2O3 shell nanosphere dimers with Al and Al core nanosphere radii of 20 nm and Al2O3 shell of 2 nm in the deep-ultraviolet region have been studied using the finite difference time domain method. The extinction spectra and the electric field distribution profiles of the two dimers for various gap distances between two individual nanospheres are compared with those of the corresponding monomers to reveal the extent of plasmon coupling. It is found that with the interparticle distance decreasing, a strong plasmon coupling between two Al or Alcore/Al2O3 shell nanospheres is observed accompanied by a significant red shift in the extinction spectra at the parallel polarization direction of the incident light related to the dimer axis, while for the case of the perpendicular polarization direction, a weak plasmon coupling arises characterized by a slight blue shift in the extinction spectra. The electric field distribution profiles show that benefiting from the dielectric Al2O3 shell, the gap distance of Alcore/Al2O3 shell nanosphere dimers can be tailored to < 1 nm scale and results in a very high electric field enhancement. The estimated surface-enhanced Raman scattering enhancement factors suggests that the Alcore/Al2O3 shell nanosphere dimers with the gap of < 1 nm gave rise to an enhancement as high as 8.1 × 107 for interparticle gap = 0.5 nm. Our studies reveal that the Alcore/Al2O3 shell nanosphere dimers may be promising substrates for surface-enhanced spectroscopy in the deep-ultraviolet region.     

基于自适应EKF的弱GNSS信号跟踪算法

弱GNSS信号跟踪技术是卫星导航接收机关键技术之一,跟踪技术的好坏将直接影响卫星导航接收机在弱信号条件下的跟踪性能;在动态环境和先验信息不充分的情况下,由于扩展卡尔曼滤波(EKF)的固定设计使其不能满足要求,针对此不足引入一种自适应扩展卡尔曼滤波(AEKF)的信号跟踪算法;该自适应滤波算法能够实时监测残差或滤波器新息的动态变化,来修正观测噪声方差和状态噪声方差,以此调整滤波器增益,观测值和控制预测值在滤波结果中的权重;理论分析和结果表明,该算法能够充分利用观测信号的统计特性,克服了传统EKF算法不足,获得更好的跟踪性能。     

平面图的圈基内插性质

图Ｇ的一个圈基的长度是该自基中所有圈的长度之和．设Ｃ－、Ｃ－分别是Ｇ的最小、最大圈基长度．如果对任一自然数Ｃ，Ｃ－＜Ｃ＜Ｃ－，都存在Ｇ的一个长为Ｃ的圈基，则称Ｇ有圈基内插性质．本文证明了无三角形的外平面图没有圈基内插性质，并说明存在围长任意大且有圈基内插性质的平面图．