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991.
We present a density matrix of a mesoscopic RLC circuits to make it possible to analyze the connection between the initial
condition and the certain temperature. Our results show that the quantum state evolution will be closely related to the initial
condition; the system evolves to generalized coherent state if it is in ground state initially, and evolves to squeezed state
if it is in excited state initially. In addition, we also obtain squeezed minimum uncertainty state with satisfying certain
condition in mesoscopic RLC circuit. 相似文献
992.
The spinel structure LiV2O4 is studied by local density approximation (LDA) as well as including strong correlation correction potential, i.e. the LDA+U scheme, which concerns the strongly correlated interaction. With LDA, the orbitals of V 3d and O 2p are well separated so that it presents purely metallic heavv fermion behaviour. The total energy of ferromagnetic phase is slightly lower than that of paramagnetic phase within the LDA ap- proach. This implies that the ferromagnetic instability as a consequence of spin frustrated magnetism can be observed in experiments. The strong correlation interaction by using LDA+U enhances the exchange splitting. The heavy-fermion feature can be derived from the sharp peak around the Fermi level from the density of states. 相似文献
993.
Zhang B Li JF Zhong QL Ren B Tian ZQ Zou SZ 《Langmuir : the ACS journal of surfaces and colloids》2005,21(16):7449-7455
Core-shell Au-Pt nanoparticles were synthesized by using a seed growth method and characterized by transmission electron microscopy, X-ray diffraction, and UV-vis spectroscopy. Au(core)-Pt(shell)/GC electrodes were prepared by drop-coating the nanoparticles on clean glassy carbon (GC) surfaces, and their electrochemical behavior in 0.5 M H2SO4 revealed that coating of the Au core by the Pt shell is complete. The electrooxidation of carbon monoxide and methanol on the Au(core)-Pt(shell)/GC was also examined, and the results are similar to those obtained on a bulk Pt electrode. High quality surface-enhanced Raman scattering (SERS) spectra of both adsorbed CO and thiocyanate were observed on the Au(core)-Pt(shell)/GC electrodes. The potential-dependent SERS features resemble those obtained on electrochemically roughened bulk Pt or Pt thin films deposited on roughened Au electrodes. For thiocyanate, the C-N stretching frequency increases with the applied potential, yielding two distinctly different dnu(CN)/dE. From -0.8 to -0.2 V, the dnu(CN)/dE is ca. 50 cm(-1)/V, whereas it is 90 cm(-1)/V above 0 V. The bandwidth along with the band intensity increases sharply above 0 V. At the low-frequency region, Pt-NCS stretching mode at 350 cm(-1) was observed at the potentials from -0.8 to 0 V, whereas the Pt-SCN mode at 280 cm(-1) was largely absent until around 0 V and became dominant at more positive potentials. These potential-dependent spectral transitions were attributed to the adsorption orientation switch from N-bound dominant at the negative potential region to S-bound at more positive potentials. The origin of the SERS activity of the particles is briefly discussed. The study demonstrates a new method of obtaining high quality SERS on Pt-group transition metals, with the possibility of tuning SERS activity by varying the core size and the shell thickness. 相似文献
994.
Zhang G Wang L Fu P Hu M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,82(1):424-431
The mechanism and conformational changes of farrerol binding to bovine serum albumin (BSA) were studied by spectroscopic methods including fluorescence quenching technique, UV–vis absorption, circular dichroism (CD) spectroscopy and Fourier transform infrared (FT-IR) spectroscopy under simulative physiological conditions. The results of fluorescence titration revealed that farrerol could strongly quench the intrinsic fluorescence of BSA through a static quenching procedure. The thermodynamic parameters enthalpy change and entropy change for the binding were calculated to be −29.92 kJ mol−1 and 5.06 J mol−1 K−1 according to the van’t Hoff equation, which suggested that the both hydrophobic interactions and hydrogen bonds play major role in the binding of farrerol to BSA. The binding distance r deduced from the efficiency of energy transfer was 3.11 nm for farrerol–BSA system. The displacement experiments of site markers and the results of fluorescence anisotropy showed that warfarin and farrerol shared a common binding site I corresponding to the subdomain IIA of BSA. Furthermore, the studies of synchronous fluorescence, CD and FT-IR spectroscopy showed that the binding of farrerol to BSA induced conformational changes in BSA. 相似文献
995.
RuCl?·3H?O was found to be an effective catalyst for reactions of indoles, 2-methylthiophene, and 2-methylfuran with aldehydes to afford the corresponding bis(indolyl)methanes, bis(thienyl)methanes, and bis(fur-2-yl)methanes in moderate to excellent yields. Experimental results indicated that mono(indolyl)methanol is not the reaction intermediate under these reaction conditions. 相似文献
996.
A three-component reaction of (E)-2-ethynylphenylchalcone, sulfonyl azide, and amine catalyzed by copper(I) chloride (5 mol%), in the presence of triethylamine, under mild conditions is described. This transformation proceeds efficiently to generate 1,2-dihydroisoquinolin-3(4H)-imines in good to excellent yields. 相似文献
997.
Dan Su Yonggui Song Lulu Geng Binbin Wei Pu Xie Yue Qi Chao Ma Shilin Yang Kaishun Bi Xiaohui Chen 《Chromatographia》2011,73(11-12):1189-1195
In order to provide useful information for rational drug design, the ocular pharmacokinetics of l-carnosine (CAR) and its acetylized prodrug N-acetyl-l-carnosine (NAC) were investigated. The in vivo microdialysis sampling coupled with ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS-MS) was developed for continuously simultaneous monitoring of CAR and NAC in rabbit aqueous humor. The measured in vitro recoveries of the probe were 61.3% for CAR and 65.8% for NAC, while in vivo recoveries decreased to 43.1% for CAR and 43.0% for NAC, respectively. The method was sensitive with LLOQ 20.5 ng mL?1 for CAR and 20.4 ng mL?1 for NAC. The initial data indicated that the value of C max and AUC(0?C??) of NAC were higher than these of CAR (C max 2305 vs. 1,802 ng mL?1), (AUC(0?C??) 1,337 vs. 1,891 ng h mL?1), which indicated that the NAC exhibited better ocular bioavailability and duration. The method was rapid, specific and sensitive for continuously monitoring of aqueous humor and it was successfully applied to pharmacokinetic studies of CAR and NAC. 相似文献
998.
We propose a square-core metallic nanotube array and investigate its optical transmission property theoretically. We find that the transmission spectra can be tuned by the width of square-core edge, the intertube spacing and the dielectric constants of the core and the embedding medium between the nanotubes. We show that there is a band gap over a wide optical wavelength, and its width, number and position are sensitive to the tunable parameters. We also discuss the situation of the rectangular-core nanotube arrays and present that modification of the size of internal holes leads to redshift of the transmission spectra. Based on the localized nature of the field distributions, we show that there are local plasmonic resonant modes that originate from multipolar plasmon polaritons and a large number of opposing surface charges build up in the gap between adjacent nanotubes. 相似文献
999.
Luo X Chen Z Xiao W Li Z Wang Q Zhong J 《Journal of colloid and interface science》2011,362(1):113-117
The complexes of maleic N-monoalkylamides and aliphatic amines lead to the formation of sheet-like and fiber-shaped aggregates in diverse organic solvents. Their morphologies and microstructures were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), as well as small angle X-ray diffraction (SA-XRD). The results reveal that the alkyl chain lengths of 8-12 carbons for maleic N-monoalkylamides, and 12-18 carbons for aliphatic amines, are suitable for obtaining highly efficient two-component gelators. 相似文献
1000.
In this paper we show that the problem to decide whether the hamiltonian index of a given graph is less than or equal to a given constant is NP-complete (although this was conjectured to be polynomial). Consequently, the corresponding problem to determine the hamiltonian index of a given graph is NP-hard. Finally, we show that some known upper and lower bounds on the hamiltonian index can be computed in polynomial time. 相似文献