全文获取类型
收费全文 | 586篇 |
免费 | 87篇 |
国内免费 | 98篇 |
专业分类
化学 | 572篇 |
晶体学 | 11篇 |
力学 | 14篇 |
综合类 | 11篇 |
数学 | 27篇 |
物理学 | 136篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 8篇 |
2018年 | 12篇 |
2017年 | 6篇 |
2016年 | 4篇 |
2015年 | 5篇 |
2014年 | 42篇 |
2013年 | 52篇 |
2012年 | 49篇 |
2011年 | 15篇 |
2010年 | 8篇 |
2009年 | 9篇 |
2008年 | 29篇 |
2007年 | 27篇 |
2006年 | 22篇 |
2005年 | 25篇 |
2004年 | 35篇 |
2003年 | 39篇 |
2002年 | 88篇 |
2001年 | 196篇 |
2000年 | 33篇 |
1999年 | 22篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 1篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1988年 | 1篇 |
排序方式: 共有771条查询结果,搜索用时 774 毫秒
91.
Polymer-supported reagents for organic synthesis are enjoying a renewed popularity with the emergence of combinatorial chemistry in recent years1. 4-(Arylseleno)morpholines formed in situ are useful -seleno-introducing reagents for saturated aldehydes2. -Sele- noaldehydes, as a frequently used intermediates, can be converted into -haloaldehydes by halogenating reaction3. However, organic selenium reagents always have a foul smell and are quite toxic, which is often problematic in organic sy… 相似文献
92.
Yun Yan GAO Chang Jiang YOU Jin Ping CHEN Yong Yong LIU Bao Wen ZHANG Yi LI* Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(12)
The photochemistry of the vitamin D family and their precursors has been the subject of extensive studies for many years1-4. Most of the studies focus on the photoisomer- ization of 7-dehydrocholesterol and that of tachysterol to previtamin D3, which is of commercial importance in the synthesis of vitamin D34, 5. Recently the cis/trans isomerization of vitamin D analogs (Scheme 1) draws attention because of its importance in the synthesis of hydroxylated vitamin D metabolites6. However, o… 相似文献
93.
Jian Fang Zhong De Liang He~* Zhou Zhou Yi Bin Xu State Key Laboratory of Chemo/Biosensing Chemometrics College of Chemistry Chemical Engineering Hunan University Changsha China 《中国化学快报》2008,19(3):319-323
The similar electrochemical oxidation behaviors of hydroxypivalaldehyde in ionic liquids (ILs) medium, C4MIMPF6, C4MIMBF4 and CsMIMPF6, are investigated using classic electrochemical methods, respectively. Only the product, hydroxypivalic acid is detected by high performance liquid chromatography (HPLC). It can be conferred that the electrochemical oxidation of hydroxypivalaldehyde consists of two successive one-electron irreversible reactions at glass carbon (GC) electrode and the possible reaction mechanism in the ILs is proposed firstly. The diffusion coefficients of hydroxypivalaldehyde are obtained according to the electrochemical characteristics of hydroxypivalaldehyde in C4MIMPF6, C4MIMBF4 and CsMIMPF6. 相似文献
94.
Hydrogen peroxide biosensor based on electrodeposition of zinc oxide nanoflowers onto carbon nanotubes film electrode 总被引:2,自引:0,他引:2
Hui Ping Bai Xu Xiao Lu Guang Ming Yang Yun Hui Yang~* Department of Chemistry Chemical Engineering Yunnan Normal University Kunming China 《中国化学快报》2008,19(3):314-318
A new amperometric biosensor for hydrogen peroxide was developed based on adsorption of horseradish peroxidase at the glassy carbon electrode modified with zinc oxide nanoflowers produced by electrodeposition onto multi-walled carbon nanotubes (MWNTs) film. The morphology of the MWNTs/nano-ZnO electrode has been investigated by scanning electron microscopy (SEM), and the electrochemical performance of the electrode has also been studied by amperometric method. The resulting electrode offered an excellent detection for hydrogen peroxide at -0.11 V with a linear response range of 9.9×10^-7 to 2.9×10^-3 mol/L with a correlation coefficient of 0.991, and response time 〈5 s. The biosensor displays rapid response and expanded linear response range, and excellent stability. 相似文献
95.
~~Formation of α,α'-Bis(substituted benzylidene)cycloalkanones from Masked Aldehydes Promoted by Samarium(III) Triiodide~~ 相似文献
96.
Jing Lin CHEN Gang Qiang YIN Zhong Ning CHEN* State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Fuzhou 《中国化学快报》2003,(5)
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl… 相似文献
97.
98.
酶解鲐鱼蛋白制取低分子肽的进一步研究 总被引:5,自引:0,他引:5
确定了用胰蛋白酶-木瓜蛋白酶混合酶法水解鲐鱼蛋白制取低分子肽的最适工艺条件为:胰蛋白酶和木瓜蛋白酶的酶量比为1:4(W/W),肉水比为1:1,温度55℃,pH7.0。在加酶量为鱼糜中蛋白质含量的1.25%,反应时间6h的条件下,制得的低分子肽无苦味,氮利用率可达78.5%,平均链长为2.80,游离氨基酸含量为26.57%,必需氨基酸含量占总氨基酸的41.8%,且比例合理,富含镁,是一种很有开发前途的功能食品原料。 相似文献
99.
IBONACCISEQUENCEANDCANTOR′STERNARYSETTONGJINGCHENGSAMONS,J.ManuscriptreceivedSeptember12,1994.RevisedDecember15,1996.Depar... 相似文献
100.
在C60单晶(111)解理面上制备出厚度约30 nm的K3C60单晶膜.利用同步辐射光源,在低温下(约150K)测量了样品法向发射的角分辨光电子谱.观察到K3C60导带和价带明显的色散.导带的光电子谱峰可清晰分辨出4个子峰,这些子峰的最大色散超过0.5eV,并且色散曲线与K3C60的一维无序晶体结构模型下的能带理论基本吻合,只是子带间隔差异较大. 相似文献