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91.
采用失重法、电化学法、X射线光电子能谱(XPS)和扫描电子显微镜(SEM)研究了0.5 mol/L NaCl溶液中,山梨酸钾(PS)与Zn2+对Q235钢的缓蚀协同效应。 失重实验结果表明,在0.5 mol/L NaCl溶液中,PS对Q235钢具有一定的缓蚀效果,缓蚀效率随PS质量浓度的增加而增大,当添加PS的质量浓度为25.0 g/L时,最大缓蚀效率仅为38.37%,而PS与Zn2+复配后存在显著的缓蚀协同作用,缓蚀效率高达91.03%。 动电势极化结果表明,PS与Zn2+混合物可同时抑制Q235钢的阴、阳极反应,属于阳极型缓蚀剂。 阻抗谱表明,该混合物可在电极表面形成致密的保护膜。 XPS分析证明保护膜是由PS、铁的氧化物/氢氧化物和Zn(OH)2沉淀组成。 相似文献
92.
Massimo Tosolini Teresa Gianferrara Giuliana Mion Luca Dovigo Fabrizio Mancin 《Supramolecular chemistry》2020,32(2):91-105
ABSTRACTA new family of conjugates between the Hoechst minor groove binder and the TACN metal ion ligand connected through hydrophobic alkyl or more hydrophilic oxyethyl linkers of different length has been prepared. The linkers are connected to the convex side of the Hoechst skeleton thus forcing the TACN ligand to exit the minor groove and interact with the phosphate backbone of DNA. The conjugates preserve the binding mode of Hoechst with an affinity influenced by the nature of the linker, the more hydrophobic being the more efficient. Coordination of Cu(II) or Zn(II) poorly affect these parameters. Nevertheless, the Zn(II) complex bearing a C6 linear alkyl linker induced a modest but reproducible acceleration of the hydrolytic cleavage of DNA which can be ascribed to the ability of the conjugate to deliver the hydrolytic subunit close to the DNA phosphodiester bonds. 相似文献
93.
94.
Permeability enhancement by induced displacement current in magnetic material with high permittivity
Based on a analytical model, this paper reveals that instead of demagnetization, the induced displacement current in a Mn–Zn ferrite core due to its high permittivity can produce a magnetic field that effectively adds to the incident magnetic field in the low-loss frequency region. This leads to a resultant magnetic field being larger than incident field in magnitude, and results in measured permeability being higher than its intrinsic value in the low-loss frequency region. It is also found that such effect is more pronounced in large core than in small core. With increasing frequency and consequently the core being more lossy, the induced magnetic field due to both conductivity and imaginary part of complex permittivity demagnetize the magnetic material and counteracts the incident magnetic field. In consequence, the measured real part of complex permeability becomes smaller than its intrinsic value. The larger the core dimension, the smaller the real part of complex permeability is. These conclusions based on the numerical analysis are in good agreement with the experimental observation in the aspect of change tendency of permeability versus frequency. 相似文献
95.
96.
A novel dinucleating pentadentate Schiff base, resulting from the condensation of 2,6-diformyl-p-cresol and N-methyl-indolyl-3-thiohydrazide, and its Zn complex have been prepared and characterized on the basis of elemental
analysis, IR, UV-Visible,1H NMR and13C NMR studies. The ligand is acyclic and consists of a phenolate head unit, with two inbuilt azomethine shoulders and two
indole thiohydrazide arms forming SNONS coordinating sites. NMR and IR spectral studies show that the ligand exists in thioketo
form. Each Zn ion in the dinuclear core is in tetrahedral environment with endogenous phenolate bridging and exogenous acetate
bridging. The zinc complex in DMF exhibits fluorescence. 相似文献
97.
A new one-dimensional dicyanamide bridged zinc(II) complex containing nitronyl nitroxide radicals Zn(NO3)(NIT-1'-MeBzIm)(dca)n·(H2O)n(NIT-1'-MeBzIm = 2-{2'-(l'-me-thyl)benzimidazolyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, dca = dicyanamide anion) has been prepared and structurally characterized by single-crystal X-ray diffraction.The complex crystallizes in triclinic, space group P1, with a = 7.428(3), b = 9.839(3), c = 16.708(6), α = 93.270(4), β = 101.642(4), γ = 100.632(4)°, C17.5H21N8O5.5Zn, Mr = 496.79, V = 1169.7(7) 3, Dc = 1.411 g/cm3, μ(MoKα) = 1.096 mm-1, Z = 2, F(000) = 512, R = 0.0583 and wR = 0.1663 for 4295 observed reflections with I > 2σ(I).X-ray analysis reveals that the zinc(II) ion is six-coordinated with a distorted octahedral geometry.These units develop as 1D species where dicyanamide ligands bridge zinc(II) ions.In addition, molecules are linked by π-π piling interactions to form 1-D double-chains.Magnetic investigation indicates that the weak intramolecular interactions are antiferromagnetic with J =-0.27 cm?1, where the spin Hamitonian is defined as H =-2∑i,jJi,jSiS within the complex. 相似文献
98.
William S. Epling Gar B. Hoflund David M. Minahan 《Reaction Kinetics and Catalysis Letters》1999,67(2):225-232
Promoter loading level significantly affects the catalytic behavior of Zn/Cr spinel higher alcohol synthesis (HAS) catalysts.
In this study a 5.9 wt.% Pd-promoted Zn/Cr spinel with a 5 and 7 wt.% K promoter have been tested and compared. At 1500 psig
and 400°C, the catalyst containing 5 wt.% K results in the production of slightly more butanol, less methanol and more hydrocarbons.
Using ion scattering spectroscopy and X-ray photoelectron spectroscopy, differences are found between the two catalyst surfaces
which must be responsible for the differences in catalytic behavior. 相似文献
99.
P. Schmid K. Uran F. Macherey M. Ebert H.-J. Ullrich D. Sommer F. Friedel 《Analytical and bioanalytical chemistry》2009,393(8):1863-1870
The formation of Fe–Zn intermetallic compounds, as relevant in the commercial product galvannealed steel sheet, was investigated
by scanning electron microscopy and different methods of X-ray diffraction. A scanning electron microscope with high resolution
was applied to investigate the layers of the galvannealed coating and its topography. Grazing incidence X-ray diffraction
(GID) was preferred over conventional Bragg–Brentano geometry for analysing thin crystalline layers because of its lower incidence
angle α and its lower depth of information. Furthermore, in situ experiments at an environmental scanning electron microscope (ESEM)
with an internal heating plate and at an X-ray diffractometer equipped with a high-temperature chamber were carried out. Thus,
it was possible to investigate the phase evolution during heat treatment by X-ray diffraction and to display the growth of
the ζ crystals in the ESEM. 相似文献
100.
《Biomedical chromatography : BMC》2018,32(10)
Quantitation of Zn‐DTPA (zinc diethylenetriamene pentaacetate, a metal chelate) in complex biological matrix is extremely challenging on account of its special physiochemical properties. This study aimed to develop a robust and specific liquid chromatography–tandem mass spectrometry (LC–MS/MS) method for determination of Zn‐DTPA in human plasma and urine. The purified samples were separated on Proteonavi (250 × 4.6 mm, 5 μm; Shiseido, Ginza, Tokyo, Japan) and a C18 guard column. The mobile phase consisted of methanol–2 mm ammonium formate (pH 6.3)–ammonia solution (50:50:0.015, v/v/v), flow rate 0.45 mL/min. The linear concentration ranges of the calibration curves for Zn‐DTPA were 1–100 μg/mL in plasma and 10–2000 μg/mL in urine. The intra‐ and inter‐day precisions for quality control (QC) samples were from 1.8 to 14.6% for Zn‐DTPA and the accuracies for QC samples were from −4.8 to 8.2%. This method was fully validated and successfully applied to the quantitation of Zn‐DTPA in plasma and urine samples of a healthy male volunteer after intravenous infusion administration of Zn‐DTPA. The result showed that the concentration of Zn‐DTPA in urine was about 20 times that in plasma, and Zn‐DTPA was completely (94.7%) excreted through urine in human. 相似文献