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91.
最近20年以来,国内高校的本科基础化学实验教学从理念、内容、标准,到组织机构和评价方法,都经历了一系列变化和改革。立足于新的历史机遇和时代,有必要深刻理解和厘清本科阶段基础化学实验教学的本质和角色,既不轻视和简慢其地位、也不夸大和拔高其效用;须还基础实验教学以其本来面目,着重深挖其在传播"第三类知识"(Knowhow)以及培养"元认知"能力当中的不可替代作用,才能在化学实验教学改革大潮中不懈怠、不迷惘。  相似文献   
92.
《中国化学快报》2022,33(9):4208-4212
Since the concept of aptamer emerged, many scientists have launched a rich field of research around it. However, few nucleic acids aptamer which use cell as target can be put into practical applications. We believe that a great deal of this lies in the complexity and irreproducibility of aptamer screening experiments themselves. The complexity is due to the cumbersome processes and the technical requirements for laboratory personnel, whereas irreproducibility arises from the fact that the starting point of such screens is nucleic acid libraries with random fragments, and that different libraries directly determine the differences or even the success or failure of screening results. The complexity and irreproducibility mentioned above, in turn, lead to the inability of this experiment to unfold on a large scale, which naturally cannot lead to excellent results for practical applications. In response to this problem, our group has developed an instrument for automated screening of tumor cell nucleic acid aptamers and characterized the properties of nucleic acid aptamers obtained using this instrument in a comprehensive manner.  相似文献   
93.
Zhang  Pei  Qing  Hai 《应用数学和力学(英文版)》2021,42(10):1379-1396

In this work, the static tensile and free vibration of nanorods are studied via both the strain-driven (StrainD) and stress-driven (StressD) two-phase nonlocal models with a bi-Helmholtz averaging kernel. Merely adjusting the limits of integration, the integral constitutive equation of the Fredholm type is converted to that of the Volterra type and then solved directly via the Laplace transform technique. The unknown constants can be uniquely determined through the standard boundary conditions and two constrained conditions accompanying the Laplace transform process. In the numerical examples, the bi-Helmholtz kernel-based StrainD (or StressD) two-phase model shows consistently softening (or stiffening) effects on both the tension and the free vibration of nanorods with different boundary edges. The effects of the two nonlocal parameters of the bi-Helmholtz kernel-based two-phase nonlocal models are studied and compared with those of the Helmholtz kernel-based models.

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94.
95.
Recently,the negative differential thermal resistance effect was discovered in a homojunction made of a negative thermal expansion material,which is very promising for realizing macroscopic thermal transistors.Similar to the Monte Carlo phonon simulation to deal with grain boundaries,we introduce positive temperature-dependent interface thermal resistance in the modified Lorentz gas model and find negative differential thermal resistance effect.In the homojunction,we reproduce a pair of equivalent negative differential thermal resistance effects in different temperature gradient directions.In the heterojunction,we realize the unidirectional negative differential thermal resistance effect,and it is accompanied by the super thermal rectification effect.Using this new way to achieve high-performance thermal devices is a new direction,and will provide extensive reference and guidance for designing thermal devices.  相似文献   
96.
Considering the random impulses of mechanical noise and the limitations involved while identifying mechanical fault impulse signals via traditional measurement indices of signal-to-noise ratio, which require the characteristic frequency to be known in advance, this study proposes an adaptive unsaturated stochastic resonance method employing maximum cross-correlated kurtosis as the signal detection index. The proposed method combines the features of a cross-correlated coefficient to indicate periodic fault transients and those of spectrum kurtosis to locate these transients in the frequency domain. Actual vibration signals collected from motor and gear bearings subjected to heavy noise are used to demonstrate the effectiveness of the proposed method. Through a coarse tree-based machine learning method, the proposed method is verified to be more suitable for explaining the periodic impulse components of bearing signals, as compared to the ensemble empirical mode decomposition denoising method and unsaturated stochastic resonance using the kurtosis-intercorrelation index.  相似文献   
97.
近年来,基于透射电子显微技术、微纳加工技术和薄膜制造技术的发展,原位液相透射电子显微技术产生,为构建多种纳米级分辨率尺度下的微实验平台,发展新型纳米表征技术和众多领域的相关研究提供了途径.本文首先介绍了应用于原位液相透射电子显微技术的液体腔设计要求,然后介绍了液体腔的发展和典型的制备工艺,最后综述了近年来液体腔透射电子显微镜在纳米粒子成核和生长方面的应用研究,并探讨了该技术前沿发展面临的机遇和挑战.本文将为提高我国先进纳米表征技术和原子精准构筑技术提供相关讨论和支持.  相似文献   
98.
胡海岩  王立峰 《力学进展》2021,51(2):386-405
张阿舟先生是我国著名的航空工程专家、固体力学家、教育家. 在20世纪后半叶,尤其是在新中国工业化初期的艰苦条件下,他面向我国航空工业发展需求,攻坚克难、培养后学,取得了突出成就. 本文全面回顾张阿舟先生的学术生涯, 介绍他在飞机结构强度、结构动力学、工程动力学反问题三个领域的主要学术贡献, 归纳他的治学特点. 文中介绍了张阿舟先生的航空报国情怀,以丰富的事例说明:他在主持新中国第一架飞机静力试验研究中发挥了核心作用, 在开拓我国飞机结构静/动强度等研究领域中发挥了引领作用, 在培养航空、力学领域的优秀人才中发挥了重要指导作用.   相似文献   
99.
为了研究当量比对汽油燃料两相旋转爆轰发动机工作特性的影响,开展了以高总温空气为氧化剂的气液两相旋转爆轰实验研究。旋转爆轰发动机环形燃烧室外径、内径和长度分别为202、166和155 mm。汽油和高温空气采用高压雾化喷嘴与环缝对撞喷注的方式混合,以此提高推进剂的掺混效果与活性,采用预爆轰管作为点火装置。实验通过改变汽油质量流量改变推进剂当量比,并基于燃烧室内测得的高频动态压力和平均静压,对气液两相旋转爆轰波的传播模态和传播特性以及发动机的工作特性进行了详细分析。实验结果表明:在当量比为0.79~1.25时,燃烧室内均实现了旋转爆轰波的连续自持传播,且随着当量比的增加,爆轰波传播模态从双波对撞/单波的混合模态转变为单波模态;降低当量比至0.61~0.66,爆轰波传播稳定性变差,传播模态表现为间断爆轰以及零星爆轰;进一步降低当量比至0.53,爆轰波起爆失败。此外,燃烧室平均绝对压力与爆轰波平均传播频率均随着当量比的增加呈先增大后减小的趋势,极大值出现在当量比1.19附近。在此工况下获得了最佳实验结果,旋转爆轰波的平均传播频率为1 900.9 Hz,平均传播速度为1 110.8 m/s,与高频压力信号经快速傅里叶变换得到的主频基本一致,爆轰波传播速度存在严重亏损。  相似文献   
100.
This paper studies the coordinated aggregation problem of a multi-agent system. Particularly, all the agents reach a consensus within a pre-specified target region. However, only a subset of agents have access to this target region, and each agent merely interacts with its neighbors by communication. Moreover, there exist unknown heterogeneous delays in communication channels. The underlying communication topology is characterized by a digraph. To accommodate the practical digital disposal, a sampled-data distributed protocol is proposed, where the sampling is asynchronous in the sense that the sampling periods of distinct agents are heterogeneous. The resulting closed-loop system from the proposed sampled-data distributed protocol is in a hybrid fashion that the continuous system is fed-back by using discrete states at sampling instants. The convergence performance of this hybrid closed-loop system is analyzed based on the contraction theory. More specifically, it is first shown that all the states are coordinated to aggregate within the target region, i.e., coordinated aggregation. With this result, it is next shown that all the states are coordinated towards a consensus, i.e., state agreement. These together guarantee the fulfillment of the concerned coordinated aggregation objective. Finally, a simulation example is given to validate the theoretical results.  相似文献   
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