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91.
Ling Tang Xiao Juan Wu Bao Min Feng Li Ying Shi Xue Yan Fu Yong Qi Wang Mei Feng Liu 《中国化学快报》2011,22(7):835-838
Two new acetylated kaempferol glycosides were isolated from the seeds of Camellia semiserrata Chi,their structures were elucidated as kaempferol-3-O-[(3-O-acetyl)-α-L-rhamnopyranosyl(1→3)(4-O-acetyl)-α-L-rhamnopyranosyl(1→6)-β-D-glucopyranoside] (1) and kaempferol-3-O-[(2-O-acetyl)-α-L-rhamnopyranosyl(1→3)(4-O-acetyl)-α-L-rhamnopyranosyl(1→6)-β-D-gluco -pyranoside](2) by spectral experiments(including ESI-MS,1D- and 2D-NMR). 相似文献
92.
通过建立一般情况下的两人进化博弈模型,给出了系统均衡点对应的矩阵行列式和迹表达式的经济含义,分析了16种典型情形下的进化稳定策略,详细讨论了均衡点稳定性分析结果所对应的博弈双方决策过程,从策略权衡的视角揭示了策略选择的内在机制。研究结果表明:不同策略前提下的相对净支付决定了系统的进化稳定策略,对方的策略选择以及自身可选策略的支付比较是影响博弈主体策略选择的两个基本要素,博弈主体会趋向于选择在对方策略既定下能够带来更大支付的策略。最后以环境治理中地方政府与企业以及地方政府之间的博弈关系为例,从对称博弈和非对称博弈两方面阐明了本文所构建模型在政策设计中的应用价值:针对不同案例,只要明确了两人博弈的支付矩阵,就可以通过计算相对净支付确定博弈双方的行为演化规律和稳定策略,从而简化计算过程,更加直接和更为便捷地为政策设计提供理论参考。 相似文献
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94.
骨组织具有适应变化力学环境的能力.通过分析骨组织适应力学环境的调控机制,吸纳工程强度设计准则思想,提出考虑载荷特性的骨重建力学调控机制,探讨载荷特性对力学激励的影响,对牙槽骨“张力区骨增生和压力区骨吸收”的现象进行分析和数值模拟.结果表明考虑载荷特性的骨重建力学调控机制是合理的,是骨重建力学调控机制理论的补充和完善. 相似文献
95.
Lei Wang Jiayao Huang Prof. Xiaojie Gong Prof. Dr. Jian Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(23):7555-7560
A general, organocatalytic inverse‐electron‐demand [3+2] cycloaddition reaction between a range of carbonyl compounds and diazoacetates has been developed. This reaction is catalyzed by secondary amines as a “green promoter” to generate substituted pyrazoles with high levels of regioselectivity. It is noteworthy that this [3+2] cycloaddition reaction proceeds efficiently at room temperature with a simple and inexpensive catalyst. Considering the large variety and ready availability of the starting materials (e.g. ketones, β‐ketoesters, β‐diketones, and aldehydes), as well as the operational simplicity of this process, a convenient, practical, and highly modular pyrazole synthesis has been developed. We believe that this work will arouse more research interest in the organocatalytic synthesis of other biologically active heterocycles. Such studies are currently underway in our laboratory. 相似文献
97.
开设了超声波专题设计综合实验,测量得空气、水和白油中超声波传播速度,研究了同一介质中接收到的交变电压随传播距离的变化规律,空气、水和白油中超声波的损耗系数,水中超声波的损耗系数最大。使用Origin软件直线拟合,对实验结果进行分析和评价。 相似文献
98.
A polydimethylsiloxane microfluidic chip has been developed for the estimation of toxic heavy metals based on measurement of mobility of marine microalgae. The chip is mainly composed of an upstream concentration gradient generator and a downstream perfusion-based chemotatic module. The processes of toxic liquid dilution and diffusion, microalgal culturing, cell stimulation, and online screening can be integrated in this chip, which makes it an attractive approach to simplify toxicity testing procedures. The microalgal motility was adopted as a microfluidic bioassay signal and was evaluated as the percentage of motile cells, curvilinear velocity, average path velocity, and straight line velocity. Two mobile marine microalgae, Platymonas subcordiformis and Platymonas helgolandica var. tsingtaoensis, were confined in the chemotatic module and stimulated by the eight concentration gradients of Cu and Cd generated by the concentration gradient generator. In all cases, a toxic response was detected (i.e., a dose-related inhibition of motility was observed). Only 1.5?h was needed to predict EC50 values. Thus, the microfluidic chip developed was proved to be useful as a simple and rapid approach in heavy metal detection and might be expanded as a conventional test method in environmental toxicity assessment. 相似文献
99.
通过羰基将两分子2-(4-氨基-2-羟苯基)苯并咪唑(4-AHBI)连接,合成了结构高度对称的新化合物N,N′-二-[3-羟基-4-(2-苯并咪唑)苯基]脲(C27H20N6O3,1),测试了不同溶剂条件下1的紫外吸收和荧光发射光谱,研究了1对Zn2+的选择性识别作用。结果表明,随着溶剂极性的增大,1的紫外吸收峰发生蓝移,激发态分子内质子转移(ESIPT)荧光发射峰明显增强。与4-AHBI相比,1在乙腈溶液中的紫外吸收强度增强约3.5倍,最大吸收峰红移8 nm,荧光发射增强8倍多。1在乙腈溶液中的Zn2+荧光响应行为表明1与Zn2+的结合将导致1在445 nm处的荧光强度不断降低,而在395 nm处出现的新峰的荧光强度不断增强,具有比率荧光探针的特点,而且检测范围较宽,可达1×10-6-1×10-2 mol.L-1。 相似文献
100.
We investigate bifurcation structures in the parameter space of a one-dimensional piecewise linear map with two discontinuity points. This map describes endogenous bull and bear market dynamics arising from a simple asset-pricing model. An important feature of our model is that some speculators only enter the market if the price is sufficiently distant to its fundamental value. Our analysis starts with the investigation of a particular case in which the map is symmetric with respect to the origin, associated with equal market entry thresholds in the bull and bear market. We then generalize our analysis by exploring how novel bifurcation structures may emerge when the map’s symmetry is broken. 相似文献