Electron Spin Resonance Studies of Mn^2＋ in Freshwater Snail Shells： Pomacea Canaliculata Lamarck and Fossilized Snail Shell

We study paramagnetic Mn^2 ions present in the nowadays shells of univalve freshwater snails of Pomacea canaliculata lamarck (PCL) and the fossilized freshwater snail (FFS), Viviparus. All these shells are abundant in Thailand. The PCL shells were ground into fine powder. A set of seven samples were then separately annealed for 2 h in air atmosphere at different annealing temperatures while the FFS powder was characterized as-received. The PCL shells mainly consist of aragonite and a fraction of calcite. The heat treatments of the PCL powder samples at temperature higher than 450℃ resulted in an irreversible phase transformation from aragonite to calcite. However, it is found that the FFS shell is mainly made of calcite, with a minor fraction of aragonite. The crystal structure of the high-temperature-annealed PCL samples are quite similar to that of FFS, which indicates that the metamorphosis (aragonite→calcite) in the FFS shell had occurred but was not yet completed, although it had remained under the pressure and temperature of the Earth‘s crusts over millions of years. Our detailed ESR spectral analyses of PCL and FFS show that Mn^2 ions enter the Ca^2 sites during a biomineralization process. Simulated ESR parameters of PCL-500 of Mn^2 at a uniaxial site of calcite are reported. It is surprising to And that the ratio of Mn^2 concentration present in FFS to those in PCL shells evaluated from ESR spectra is as much as 10:1.     

溴分子[^2Π3／2]4d里德堡态的转动谱的计算模拟

对溴分子在６８８００－７２００ｃｍ＾－１范围内的两个被观察到的［＾２Π３／２］４ｄ偶宇称里堡态的转动光谱进行了计算模拟，确定了转动常数，并且证实了原先对实验光谱的传动结构和电子角动量的标识。     

量子计算与超冷离子

通过介绍量子计算的基本概念和特点，并对比目前人们使用的计算机的计算方式，对于如何利用囚禁在离子阱中的超冷离子进行量子计算作了简要的叙述．     

三维流动传热空隙率计算程序FASTOR—3D开发研究

1引言大粘度（大r）和大系数（ss和sc）法是处理流动区域中障碍物的常用方法山。但当流动区域中障碍物数量较多时，宜采用空隙率来模拟障碍物，如模拟反应堆流动传热的商用程序COMMIX［’］。我们根据空隙率模拟的基本概念，针对采用交错网格的压力校正法，自行编制了多障碍物流动传热三维计算的全部源程序代码，应用于某核反应堆钠池流动传热的数值模拟，获得了比较合理的结果。2数学模型和数值方法2．1控制方程空隙率修整的质量、动量、能量及湍流动能与耗散率的守恒方程通式的三维柱坐标形式为其中中一1，。，。，。，T，k，。分别表…     

非共沸制冷剂R417A在水平光滑管内的沸腾传热

应用一种快速、准确的隐式格式迭代数值计算方法 ,对非共沸制冷剂 R41 7A在水平光滑管内的蒸发过程进行了数值模拟。通过应用纯质的传热公式计算后与实验值相比较 ,数值计算结果高于实验值。     

高功率弯波导TE01-TM11模式变换临界角分析

在模式耦合理论的基础上，采用传统的波导轴线圆弧弯曲的方法，对TE01－TM11模式变换器的临界角进行了全面的优化分析。得出在临界角情况下，若考虑多模因素，则不能使TE01－TM11的能量发生全转换，而真正的最优化能量全转换角在临界角的附近，且转换的效率与弯波导曲率相关。     

用模拟万用表测电容

介绍了用模拟万用表和秒表测量电容的简单方法，对测量结果的误差原因进行了分析，给出了提高测量精度的几点措施。     

自相似结构壳模型

为了扩展以简谐振子为基矢的常规壳模型（ＳＭ）计算到晕核，提出了自相似结构壳模型（ＳＳＭ）．通过对简谐振子动能项和势能项的重度规以及单粒子平均场模拟，可以得到ＳＳＭ中的单粒子轨道有态相关的圆频率，在ＳＳＭ中，晕核大的均方根半径、厚的中子皮以及Ｂｏｒｒｏｍｅａｎ晕核和的束缚态性质能够再现出来。