以聚α,α-二甲基-β-丙内酯为硬段的三嵌段共聚物的合成与性质

合成了以聚α,α-二甲基-β-丙内酯(PPVL)为硬段,聚己二酸1,2-丙二醇酯(PPA)、聚丁二烯(PBD)及氢化聚丁二烯(HPBD)为软段的ABA型嵌段共聚物及以聚α-甲基苯乙烯(PαMS)和PPVL为硬段,PBD为软段的ABC型嵌段共聚物。发现嵌段共聚物中PPVL的1/T_m∝[软段]/[PPVL],软段含量对降低T_m与力学性能的影响均为PPVL-PPA-PPVL>PPVL-HPBD-PPVL>PPVL-PBD-PPVL,符合软硬段相容性下降的趋势;PPVL-PBD-PαMS的力学性能低于PPVL-PBD-PPVL与PαMS-PBD-PαMS,是因结晶的PPVL与无规的PαMS互不相容。     

叶醇及其衍生物的立体有择合成

叶醇的结构为z-己-3-烯-1-醇,本世纪二十年代首次从茶叶中分离并鉴定。在洋槐和桑树的叶油中含量达50％,绿茶中30％,叶醇几乎存在于所有绿色植物中,所谓象征植物“绿色”的本体在气味上的休现就是叶醇。     

“空间四点定球”的探索

在平面几何中,不在同一直线上的三点可以确定一个圆:若三点连线组成三角形,且三角形的三边己知,则此三角形的外接圆的半径可以求出。在空间中不在同一平面内的四点可以确定一个球,若四点连线组成四面体,且四面体的六条棱长已知,那末此四面体的外接球半径是否可以求出?本文对此问题进行探索。设四面体D—ABC中,BC=a、AC=b、AB=c其相对棱DA、DB、DC的长分别为a、b、c,求DABC的外接球的半径。解:在平面ABC中过A作AE⊥BC于E,在平面DBC中过D作DF⊥BC于F,则平面ABC与平面DBC所成二面角的平面角,是异面直线DF与AE所成的角,或此角的补角,由于棱长已知,所以各个     

电感耦合等离子体原子发射光谱法快速测定水泥中三氧化硫

水泥样品经硝酸-盐酸(2+6)混合溶液溶解后,采用电感耦合等离子体原子发射光谱法测定水泥中的三氧化硫的含量。在基体中不含有钙元素时,选择波长为180.7 nm谱线的作为测定三氧化硫的分析线;当基体中含有钙元素时,选择波长为182.0 nm的谱线作为分析线。方法的检出限(3s)为20μg·L~(-1)。该方法用于测定标准物质(GBW 03201a,GBW 03205)中三氧化硫的含量,相对标准偏差(n=10)在1.00%～0.56%之间,所得结果与标准值相一致。     

CSPD-1溶液物理显影研究

本文介绍了命名为CSPD-1溶液物理显影处理工艺,用于中国全息干板的实验研究结果;全面地总结了实验操作中的技术关键问题;对观察到的新工艺优越性产生的机制,作了初步的理论讨论。     

自由电子激光放大器频谱振荡现象的研究

本文从单粒子模型出发,导出了考虑相对论能量因子一级扰动量影响的色散方程。结果表明:当入射电子能量足够大时,自由电子激光放大器出现频谱振荡现象,产生这种现象的原因是由于相对论能量因子的扰动作用。文中对此进行了比较详细的讨论。 关键词：     

A mini-review on econophysics:Comparative study of Chinese and western financial markets

We present a review of our recent research in econophysics, and focus on the comparative study of Chinese and western financial markets. By virtue of concepts and methods in statistical physics, we investigate the time correlations and spatial structure of financial markets based on empirical high-frequency data. We discover that the Chinese stock market shares common basic properties with the western stock markets, such as the fat-tail probability distribution of price returns, the long-range auto-correlation of volatilities, and the persistence probability of volatilities, while it exhibits very different higher-order time correlations of price returns and volatilities, spatial correlations of individual stock prices, and large-fluctuation dynamic behaviors. Furthermore, multi-agent-based models are developed to simulate the microscopic interaction and dynamic evolution of the stock markets.     

Rotational properties in even-even superheavy 254-258Rf nuclei based on total-Routhian-surface calculations

High-spin yrast structures of even-even superheavy nuclei ^254-258Rf are investigated by means of total-Routhian-surface approach in three-dimensional (β₂, γ, β₄) space. The behavior in the moments of inertia of ²⁵⁶Rf is well reproduced by our calculations, which is attributed to the j_15/2 neutron rotation-alignment. The competition between the rotationally aligned i_13/2 proton and j_15/2 neutron may occur to a large extent in ²⁵⁶Rf. High-spin predictions are also made for its neighboring isotopes ^254,258Rf, showing that the alignment of the j_15/2 neutron pair is more favored than that of the i_13/2 proton pair.     

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在"星光Ⅱ"钕玻璃激光装置上,开展了脉宽约0.8ns、能量~70J的351nm激光在不同条件下辐照Au盘靶的实验,研究了激光光束质量对受激布里渊散射(SBS)谱的影响。SBS散射光谱测量结果表明,在激光束未匀滑条件下,SBS散射谱范围为352~360nm;在采用透镜列阵将激光束匀滑聚焦的条件下,激光等离子体密度变得更加均匀,SBS散射光谱范围变为351~351.5nm。实验数据为透镜列阵对光束的匀滑效果提供了直接支持。