CO2对Ba0.5Sr0.5Co0.8Fe0.2O3−δ表面氧交换的影响

采 用 了 一 种 新 的 脉 冲 同 位 素 交 换 技 术 , 研 究了CO₂对Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3?δ(BSCF)的表面氧交换动力学的毒害作用．当BSCF暴露于CO₂时,由于在材料表面形成了碳酸盐,其表面交换率严重降低．在低CO₂浓度(1%)时,毒害作用从375 oC开始,并且随着温度的上升而变得更加明显．同时,表面交换动力学的下降导致BSCF在CO₂条件下氧渗透性能快速下降．     

共同基金和无风险资产投资的最优策略

利用均值-方差模型,分析了非线性交易成本下的共同基金与无风险资产投资组合的有效边界和在一般的效用函数下讨论了投资者的最优投资策略.     

HWE生长PbTe单晶薄膜及生长机理的研究

本文介绍了一种简单的热壁外延(HWE)装置,和利用它在BaF2(111)衬底上生长PbTe(111)单晶薄膜的工艺,并讨论了生长机理.     

紫外光谱研究β-环糊精衍生物与α-环己基扁桃酸的包结作用

用紫外光谱分别研究了在水溶液和50%乙醇水溶液两种不同介质中,羟丙基β-环糊精(HPβ-CD 1)、羟乙基β-环糊精(HE-β-CD 2)和甲基β-环糊精(Me-β-CD 3)与α-环己基扁桃酸(CHMA)形成的包结物的稳定性.研究结果表明主客体的包结比为1:1,在水溶液中,三种主体的包结能力均较弱,其包结能力的强弱顺序为:3＞2＞1.而在50%乙醇水溶液中,主客体包结物的稳定性大大提高,并且三种主体的包结能力强弱顺序发生改变,依次为:1＞2＞3.     

阿罗不可能性定理的几个等价形式

在这篇短中。给出了关于社会福利函数F的防止策略性操纵的概念,并且证明了如果备选对象至少有三个。则下面结论是相互等价的：(1)F满足Pareto与IIA性质;(2)F满足Pareto与RID性质;(3)F是独裁的;(4)F是满的、正向响应的;(5)F是防止策略操纵的且F是满的。     

疏水性L-酒石酸酯/羟丙基β-环糊精分离体系分离反式第一菊酸对映体

手性拆分;酒石酸酯;羟丙基β-环糊精;反式第一菊酸     

线性随机结构的平稳随机响应

对于不仅结构参数具有随机性,而且外载是平稳随机激励的问题,给出了随机响应变异系数的计算方法。应用虚拟激励法先将随机荷载转化为确定性的简谐荷载,使双随机问题得以精确地转化为单随机问题进行分析。求解过程显著简化,而且包含了二种随机因素之间的耦合效应。用数值模拟法对方法的精度作了估计。     

线框馈电抛物反射面高功率电磁脉冲辐射天线

 研制了一种由高功率宽带模式转换结构、导电线框TEM喇叭馈电结构及抛物反射面构成的天线,用其辐射高功率亚纳秒电磁脉冲。时域测试表明,在半宽为700ps、峰值电压为200kV脉冲激励下,天线的主瓣宽度约为±3.8°,辐射效率约为37%。     

Electron-transfer fluorescence quenching processes in coaggregates between excited N-alkylcarbazoles as electron donors and 2, 4-dinitrophenyl carboxylates or pentafluorophenyl carboxylates as acceptors

Electron-transfer processes facilitated by hydrophobic-lipophilic interaction ( HLI) between excited N-alkylcar-bazoles (1-n, n=4, 8, 12, 16) as electron donors and 2,4-dintrophenyl carboxylates (2-n, n = 4, 8, 12, 16) or pentafluorophenyl carboxylates (3-n, n = 4, 8, 12, 16) as electron acceptors have been investigated by means of fluorescence spectroscopy in aqueous or aquiorgano binary mixtures. The fluorescence quenching of -n * by 2-n or -n indicates that preassociation precedes the electron transfer. The extent of HLI-driven coaggregation of the acceptor and the donor may be assessed from the B value of the equation I0/I = A B [Q]. The chain-length effect and possibly also a chain-fold-ability effect, as well as the solvent aggregating power (SAgP) effect have been observed. Comparison of the quenching constants (B) for 1-n * /2-n combinations and 1-n * / 3-n combinations shows that the order of increasing R values for the quenching processes is 3-n < 2-n.     

Aggregating tendencies of some N-alkylcarbazoles

Aggregation of some nitrogen-containing heterocyclic compounds have been investigated by means of fluorescence spec-troscopy in aqueous or aquiorgano binary mixtures of different Φ values for the first time. The aggregators studied are N-butylcarbazole (CBZ-4), N-octylcarbazole (CBZ-8), N-do-decylcarbazole (CBZ-12), and N-hexadecylcarbazole (CBZ-16). Their aggregating tendencies have been evaluated by measuring their critical aggregate concentration values (CAgC's). Our results indicate that the N-alkylcarbazoles, just like the anthracene derivatives with different chain-lengths, can also be used as fluorescence probes for evaluating aggregating tendencies or CAgC values.