全文获取类型
收费全文 | 273篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 192篇 |
晶体学 | 1篇 |
数学 | 60篇 |
物理学 | 27篇 |
出版年
2023年 | 2篇 |
2021年 | 9篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 12篇 |
2017年 | 6篇 |
2016年 | 10篇 |
2015年 | 5篇 |
2014年 | 13篇 |
2013年 | 26篇 |
2012年 | 19篇 |
2011年 | 23篇 |
2010年 | 16篇 |
2009年 | 10篇 |
2008年 | 16篇 |
2007年 | 10篇 |
2006年 | 24篇 |
2005年 | 5篇 |
2004年 | 12篇 |
2003年 | 7篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1984年 | 3篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1972年 | 2篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有280条查询结果,搜索用时 31 毫秒
81.
Reversible interconversion of thiazolidine-tetrahydrothiazine in the thiadiazabicyclooctanone system
Mirjana Tomić Jure J. Herak Miće Kovačević 《Monatshefte für Chemie / Chemical Monthly》1989,120(3):237-241
Summary The interconversion of thiazolidine-tetrahydrothiazine in some derivatives of thiadiazabicyclooctanone in aqueous HCl has been studied. In the case of 6- and 7-substituted hydroxy or methoxy thiadiazabicyclooctanone a reversible rearrangement was found. The sulfoxide of thiadiazabicyclooctanone under the same reaction conditions undergoes epimerisation, while reaction with PCl5 — via a corresponding sulfenyl chloride — affords a mixture of 6-and 7-substituted hydroxy or methoxy derivatives of thiadiazabicyclooctanone.The authors dedicate this paper to Dr. B. Gapert for his 60th birthday 相似文献
82.
Urszula Rychlewska Beata Warajtis Milo I. Djuran Duanka D. Radanovi Mirjana Dj. Dimitrijevi Sneana Rajkovi 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(6):m217-m220
The title compound, {[CoLi2(C11H14N2O8)(H2O)3]·2H2O}n, constitutes the first example of a salt of the [MII(1,3‐pdta)]2− complex (1,3‐pdta is propane‐1,3‐diyldinitrilotetraacetate) with a monopositive cation as counter‐ion. Insertion of the Li+ cation could only be achieved through application of the ion‐exchange column technique which, however, appeared unsuccessful with other alkali metals and the ammonium cation. The structure contains two tetrahedrally coordinated Li+ cations, an octahedral [Co(1,3‐pdta)]2− anion and five water molecules, two of which are uncoordinated, and is built of two‐dimensional layers extending parallel to the (010) lattice plane, the constituents of which are connected by the coordinate bonds. O—Hwater...O hydrogen bonds operate both within and between these layers. The crystal investigated belongs to the enantiomeric space group P21 with only one (Λ) of two possible optical isomers of the [Co(1,3‐pdta)]2− complex. A possible cause of enantiomer separation during crystallization might be the rigidification and polarization of the [M(1,3‐pdta)]2− core, resulting from direct coordination of Li+ cations to three out of four carboxylate groups constituting the 1,3‐pdta ligand. The structure of (I) differs considerably from those of the other [MII(1,3‐pdta)]2− complexes, in which the charge compensation is realized by means of divalent hexaaqua complex cations. This finding demonstrates a significant structure‐determining role of the counter‐ions. 相似文献
83.
Biljana Jani Mirjana Medenica Darko Ivanovi Anelija Malenovi Igor Popovi 《Chromatographia》2008,67(1):123-127
In this paper, the chromatographic characterization of fosinopril sodium and fosinoprilat is presented. The first stept was pK a determination for the active substance and its degradation product using RP-LC. It was followed by optimization employing the combination of experimental design and artificial neural networks. For the definition of input and output variables, the central composite design for three factors was built. Back propagation algorithm was applied to model the system, and then the optimization of the experimental conditions was carried out in the neural network with 3-8-2 structure, which confirmed to be able to provide the maximum performance. From the method optimization, the most appropriate experimental conditions for fosinopril sodium and fosinoprilat analysis were extracted. The optimized method was validated and applied in the quality control of tablets and for forced degradation studies. 相似文献
84.
Mieusset JL Bespokoev A Pacar M Abraham M Arion VB Brinker UH 《The Journal of organic chemistry》2008,73(17):6551-6558
The chemistry of endo-tricyclo[6.2.1.0 (2.7)]undec-9-en-11-ylidene (10), an archetypal foiled carbene, has been investigated. The intermolecular reactions of 10 are most conveniently performed with oxadiazoline 6 because the corresponding diazirine can be obtained only in very low yield. Furthermore, the aziridinyl imine is difficult to decompose and the tosylhydrazone sodium salt poorly soluble in common organic solvents. Photolysis of 6 in diethylamine leads merely to a reduction of the diazo group and regeneration of acetyl hydrazone 5, whereas thermolysis cleanly affords tertiary amine 12(anti) in 77% yield. Calculations show that even stabilized-nucleophilic carbenes react with amines through an ylidic pathway and not by a concerted insertion into the N-H bond. Nevertheless, in the gas phase, norbornen-7-ylidene (13) is predicted to be stabilized by one molecule of NH3 more efficiently through a hydrogen bond than by ylide formation. 相似文献
85.
Interactions of Molecules with cis and trans Double Bonds: A Theoretical Study of cis‐ and trans‐2‐Butene 下载免费PDF全文
Milana M. Zarić Prof. Dr. Branko Bugarski Prof. Dr. Mirjana Lj. Kijevčanin 《Chemphyschem》2016,17(2):317-324
Noncovalent interactions of cis‐ and trans‐2‐butene, as the smallest model systems of molecules with cis and trans double bonds, were studied to find potential differences in interactions of these molecules. The study was performed using quantum chemical methods including very accurate CCSD(T)/CBS method. We studied parallel and displaced parallel interactions in 2‐butene dimers, in butane dimers, and between 2‐butene and saturated butane. The results show the trend that interactions of 2‐butene with butane are the strongest, followed by interactions in butane dimers, whereas the interaction in 2‐butene dimers are the weakest. The strongest calculated interaction energy is between trans‐2‐butene and butane, with a CCSD(T)/CBS energy of ?2.80 kcal mol?1. Interactions in cis‐2‐butene dimers are stronger than interactions in trans‐2‐butene dimers. Interestingly, some of the interactions involving 2‐butene are as strong as interactions in a benzene dimer. These insights into interactions of cis‐ and trans‐2‐butene can improve understanding of the properties and processes that involve molecules with cis and trans double bonds, such as fatty acids and polymers. 相似文献
86.
In this paper we consider some special characteristics of distances between vertices in the \(n\)-dimensional hypercube graph \(Q_n\) and, as a consequence, the corresponding symmetry properties of its resolving sets. It is illustrated how these properties can be implemented within a simple greedy heuristic in order to find efficiently an upper bound of the so called metric dimension \(\beta (Q_n)\) of \(Q_n\), i.e. the minimal cardinality of a resolving set in \(Q_n\). This heuristic was applied to generate upper bounds of \(\beta (Q_n)\) for \(n\) up to \(22\), which are for \(n\ge 19\) better than the existing ones. Starting from these new bounds, some existing upper bounds for \(23\le n\le 90\) are improved by a dynamic programming procedure. 相似文献
87.
This paper considers a recently introduced NP-hard problem on graphs, called the dominating tree problem. In order to solve this problem, we develop a variable neighborhood search (VNS) based heuristic. Feasible solutions are obtained by using the set of vertex permutations that allow us to implement standard neighborhood structures and the appropriate local search procedure. Computational experiments include two classes of randomly generated test instances and benchmark test instances from the literature. Optimality of VNS solutions on small size instances is verified with CPLEX. 相似文献
88.
Anne Klaproth Maria Najdanova Mirjana Minceva Dieter Sicker Hans‐Ullrich Siehl Klaus‐Peter Zeller Stefan Berger 《Chemie in Unserer Zeit》2016,50(4):260-274
Chlorophyll exists since ca. 3 billion years and is at begin of the evolution. This chiral, green Mg‐porphyrin‐complex absorbs as a photosensitizer in the antennas of the light‐harvesting complexes of chloroplasts all parts of visible light except of green light. This energy is transferred to the reaction centres of oxygenic photosynthesis. By this redox reaction carbon dioxide and water are transformed into carbohydrates and oxygen. We describe how the structures of chlorophylls were elucidated, discuss structure‐property relations, the relationship to heme of blood, everyday uses, and how Green has influenced our language. The isolation of pure chlorophyll a from spinach is an experimental challenge, which we report in detail. All analytical spectra were recorded and are reproduced and interpreted either in the main part or in the supporting information. 相似文献
89.
In this paper a commercial electronic tongue (αAstree, Alpha M.O.S.) was applied for botanical classification and physicochemical characterization of honey samples. The electronic tongue was comprised of seven potentiometric sensors coupled with an Ag/AgCl reference electrode. Botanical classification was performed by PCA, CCA and ANN modeling on 12 samples of acacia, chestnut and honeydew honey. The physicochemical characterization of honey was obtained by ANN modeling and the parameters included were electrical conductivity, acidity, water content, invert sugar and total sugar. The initial reference values for the physicochemical parameters observed were determined by traditional methods. Botanical classification of honey samples obtained by ANN was 100% accurate while the highest correlation between observed and predicted values was obtained for electrical conductivity (0.999), followed by acidity (0.997), water content (0.994), invert sugar content (0.988) and total sugar content (0.979).All developed ANN models for rapid honey characterization and botanical classification performed excellently showing the potential of the electronic tongue as a tool in rapid honey analysis and characterization. The advantage of using such a technique is a simple sample preparation procedure, there are no chemicals involved and there are no additional costs except the initial measurements required for ANN model development. 相似文献
90.
Škorić I Pavošević F Vazdar M Marinić Ž Šindler-Kulyk M Eckert-Maksić M Margetić D 《Organic & biomolecular chemistry》2011,9(19):6771-6778
The first example of thermal (8π,6π)-electrocyclisation of 1,3,5,7-octatetraene with one double bond embedded in an aromatic moiety is described. By this process, [3,4]-benzo-8-substituted octatetraene derivatives, the cis,trans-1-(o-vinylphenyl)-4-(R = Me, Ph, 2-furyl)buta-1,3-dienes were transformed to a new endo-7-(R = Me, Ph, 2-furyl) and exo-7-(R = Me)-2,3-benzobicyclo[4.2.0]octa-2,4-dienes. Mechanism of reaction was also studied by DFT quantum-chemical calculations. The M06/6-311+G(d,p)//M06/6-31+G(d,p) calculations indicate that formation of the single endo-isomer in the case of phenyl and 2-furyl substituents is determined by higher activation barriers for exo-6π-electrocyclisation than for 8π-cycloreversion. 相似文献