全文获取类型
收费全文 | 574篇 |
免费 | 86篇 |
国内免费 | 108篇 |
专业分类
化学 | 588篇 |
力学 | 15篇 |
综合类 | 7篇 |
数学 | 22篇 |
物理学 | 136篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 2篇 |
2016年 | 2篇 |
2015年 | 5篇 |
2014年 | 34篇 |
2013年 | 50篇 |
2012年 | 48篇 |
2011年 | 16篇 |
2010年 | 4篇 |
2009年 | 7篇 |
2008年 | 24篇 |
2007年 | 29篇 |
2006年 | 20篇 |
2005年 | 29篇 |
2004年 | 40篇 |
2003年 | 44篇 |
2002年 | 91篇 |
2001年 | 200篇 |
2000年 | 41篇 |
1999年 | 24篇 |
1998年 | 10篇 |
1997年 | 11篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1985年 | 1篇 |
排序方式: 共有768条查询结果,搜索用时 15 毫秒
761.
WU Shi-hua* * WEI Wei ZHU Chang-ying HUANG Wei-pingZHANG Shou-min ZHENG Xiu-cheng ZHANG Shu-hong ZHAO Wei-jun 《高等学校化学研究》2001,17(4):439-444
Co-Pd bimetallic catalysts immobilized with four kinds of resins with different specific areas were prepared by means of the solvated metal atom impregnation (SMAI) method. The results of the XRD and the magnetic measurement showed that as the specific area of the resin increased, the particle sizes of Co and Pd on the catalysts with the same metal content decreased, so the catalytic activity of the catalysts for the hydrogenation of diacetone alcohol as well as the reduction of oxygen on the fuel cell electrode increased. Below 140 , the conversion of diacetone alcohol increased as the reaction temperature increased, and above 140 , the conversion decreased because of the rupture of the resin. 相似文献
762.
LI Bo * Yoshifumi KOIDE Kunio ESUMI . Toyota Central R & D Labs. Inc. Yokomichi Nagakute Aichi Japan . Departemnt of Applied Chemistry Institute of Colloid Interface Science Science University of Tokyo 《高等学校化学研究》2002,18(2):206-210
IntroductionInclusioncompoundshavebeennotedinrecentyearsandresorcinol typecalix [4 ]arenehasbeenstudiedfortheirinclusionabilitiesbyScheiderandBugleretal[1— 3] .Thepolyolmoietiesincalix[4 ]re sorcinareneformrigidhydrogen bondingnetworks[4 ] ,andcalix [4 ]resorcinare… 相似文献
763.
CHEN Wei YUAN Hong-ming JIANG Yu-sheng HUO Hua CHEN Jie-sheng *State Key Laboratory of Inorganic Synthesis Preparative Chemistry Jilin University Changchun P. R. China 《高等学校化学研究》2002,18(4):375-379
IntroductionSince Wilson and co- workers successfullysynthesized three- dimensional microporousaluminophosphates (Al PO4 - n ) [1] in the 1 980 s,much attention has been focused on the explorationof1 - D chain,2 - D layer and3 - D open- frameworkmetal phosphates from aqueous or non- aqueoussystems.The number of metals incorporated intothe frameworks of these materials is continuouslyincreasing and the metals include Be[2 ] ,Ga[3] ,In[4 ] ,Sn[5] ,Sb[6 ] ,and the transition metals Zn[7] ,Ni… 相似文献
764.
Antioxidative Effect of Schiff Bases with o-Hydroxybenzylidene Groupon Free Radical Induced Hemolysis of Human Red Blood Cell 总被引:1,自引:0,他引:1
LUO Xu yang ZHAO Jian zhang LIN Ying jie LIU Zai qun * College of Chemistry Jilin University Changchun P. R. China 《高等学校化学研究》2002,18(3):287-289
IntroductionThe recent development of free radical biologyand medicine has provided a great deal of clinicaland experimental evidence indicating that the freeradical induced peroxidation of membrane lipids isassociated with a variety of chronic healthproblems,such as cancer,atherosclerosis andageing[1,2 ] . Both natural and synthetic antioxidantshave been used to trap peroxyl radicals and/orinitiating radicals to protect the membrane lipidsagainst free radical chain reactions,and hence mayhave… 相似文献
765.
WANG Wei WANG Yu-hong Li Wei * *Biological Macromolecular Laboratory College of Life Science Jilin University Changchun P. R. China 《高等学校化学研究》2002,18(4):491-494
IntroductionBioinformatics is coming with Human GenomeProject(HGP) . With the explosions of sequence,structural and other information available ,bioinformatics is playing an increasingly large rolein the study of fundamental biomedical problems.At present and in the near future,it is the mainchallenge for bioinformatists to make gene dicoveryand annotation of human genome sequences whenthe vast amount of data is produced by the highthroughput genome sequencing in a large scale andautomated m… 相似文献
766.
IntroductionAmrinon,asyntheticbipyridinederivative,nonglycosideandnoncatecholaminecar-diotonicstimulant,iscurrentlyusedinthetreatmentoftheheartfailureandforcardiovascu-larsupportinpediatricpatients.Itpossessespotentcardiacandbloodvesselspreadingef-fe… 相似文献
767.
二过碘酸含铜(Ⅲ)配离子氧化异丙胺的动力学及机理 总被引:1,自引:0,他引:1
在碱性价质中于30~45℃区间,用分光光度法研究了二过碘酸含铜(Ⅱ)配离子(DPC)氧化异丙胺(PA)的动力学.结果表明:反应对DPC为一级,对PA的表观反应级数为1.15~1.39级;准一级([PA]0≥[Cu(Ⅲ)]0)速率常数kobs随[OH-]和[IO4-]cx的增加而减小;在氮气保护下反应体系能引发丙烯酰胺聚合,表明有自由基参与反应.此外,还观察到对速率有负盐效应.据此,提出了包括DPC离解出一个H2IO63-的前期平衡和[Cu(HIO6)]-与PA之间生成加成物的反应机理. 相似文献
768.
Weinan E~* Jianfeng LU~ 《数学年刊B辑(英文版)》2007,28(6):665-676
The authors consider the simplest quantum mechanics model of solids,the tight binding model,and prove that in the continuum limit,the energy of tight binding model converges to that of the continuum elasticity model obtained using Cauchy-Born rule.The technique in this paper is based mainly on spectral perturbation theory for large matrices. 相似文献