纳米TiO_2电极的特殊光电化学响应

应用涂膜法、电沉积法和溶胶-凝胶法制备纳米TiO2电极.实验发现,纳米TiO2具有特殊的光电化学响应,其光电流~电位变化出现光电流峰,这一特殊的光电化学性质乃与纳米半导体电极的纳米结构及其特殊的光诱导氧化还原反应机理密切相关.     

鹅膏菌的傅里叶变换红外光谱研究

利用傅里叶变换红外光谱对云南野生鹅膏科蘑菇子实体及孢子进行了研究,二者的光谱差异显著。子实体光谱的最强峰出现在蛋白质酰胺Ⅰ的特征峰1 655 cm-1附近,在碳水化合物的C—O特征振动峰1 077, 1 042 cm-1附近也有强吸收,表明鹅膏科蘑菇子实体的主要成分是蛋白质和碳水化合物;孢子的三个强峰在2 926,2 855,1 747 cm-1,归属为脂类物质的吸收。在1 800～750 cm-1,不同属、不同种的鹅膏科蘑菇光谱有区别,以此可以区分不同种类的蘑菇。此外,隐花青鹅膏菌不同部位的光谱也有差异,表明蘑菇的化学组分在子实体的不同部位有不同分布。利用傅里叶变换红外光谱可以区分不同种类的蘑菇。     

腈类与BH3络合的量子化学研究

经过以AO和孤立MO为基组的半经验自洽场MNDO计算,研究了RCN(R=F,OH,NH₂,CH₃)与BH₃之间的络合规律、取代基效应,对比了给体的"软端"和"硬端"与BH₃络合的情况。结果表明,决定络合作用力相对顺序的主要因素是给受电子共价作用。     

Novel Synthesis,Crystal Structure,and Plant-growth Regulation Activity of(1S,4R)-4,7,7-Trimethyl-6-oxabicyclo[3.2.1]octane-1,4-diol

The title compound,(1S,4R)-4,7,7-trimethyl-6-oxabicyclo [3.2.1] octane-1,4-diol(C_(10)H_(18)O_3), has been synthesized from terpinolene via one-step catalytic synthetic method and structurally characterized by means of HRMS, IR, ~1H-NMR, ~(13)C-NMR and single-crystal X-ray diffraction. The compound crystallizes in trigonal, space group R-3, with a = 27.892(9), b = 27.892(9), c = 6.720(2) ?, γ = 120°, Z = 18, V = 4527(3) ?~3, D_c = 1.230 g/cm~3, Mr = 186.24, λ(Mo Kα) = 0.71073?, μ = 0.09 mm~(-1), F(000) = 1836, the final R = 0.051 and wR = 0.161. The title compound molecule contained a 6-oxabicyclo[3.2.1]octane skeleton and two hydroxyl groups, which were connected through intermolecular O–H???O hydrogen bonds to generate a two-dimensional network. Especially, the preliminary bioassay showed that the title compound can promote the root growth and shoot elongation of rape(Brassica campestris) at low concentration(0.625~70 mmol·L~(-1)) and inhibit them at high concentration( 70 mmol·L~(-1)).     

实例统计翻译混合策略的汉民病历翻译的研究

针对民族地区不同语言民族患者看病求医中汉文处方理解难、病历及药物信息不易读懂等问题,本文研讨基于实例及基于短语的统计机器翻译混合策略的汉民电子病历、门诊处方及药物信息等医疗卫生用文机器翻译方法,试图实现高精度保质量的医药文翻译系统,提升民族地区公共卫生服务水平.本次汉-维门诊处方文本翻译试验结果BLUE值显示,本文提出方法比单一翻译方法(如实例或者统计翻译)显著提高了译文质量.     

Structure and Wettability Engineering of Polycrystalline Diamond Films Treated by Thermally Oxidation,Second Growth and Surface Termination

High-quality polycrystalline diamond films with dominated(100)-oriented grains are realized by combining the thermally oxidation and the homogeneous second growth processes. Moreover, we investigate the wettability property of the polycrystalline diamonds in various stages. Different surface structures(with various grain sizes,voids, and orientations, etc.) and terminations(hydrogen or oxygen) have significant effects on the wettability of polycrystalline diamond films. The wettability is furthe...     

Synthesis,Crystal Structure,and Herbicidal Activity of(3R,4R)-4,7,7-Trimethyl-6-oxabicyclo[3.2.1]octane-3,4-diol Mono-fatty Acid Esters

Four mono-fatty acid esters(Ia～d) were synthesized via the esterification of(3R,4R)-4,7,7-trimethyl-6-oxabicyclo[3.2.1]octane-3,4-diol(I) with fatty acid chlorides(CH_3(CH_2)_nCOCl, n = 0, 2, 4, 6) and structurally characterized by means of H RMS, IR, ~1 H-NMR, ~(13)C-NMR and X-ray diffraction. Compounds Ia～d all belong to monoclinic system, P2_1/c space group. Intermolecular O(2)–H(2)···O(1) hydrogen bonds, intramolecular O(2)–H(2)···O(3) hydrogen bonds and van der Waals' interaction between fatty acid ester groups link each of the mono-fatty acid ester molecules into a bilayer structure similar to liposome with the exposed hydrophobic moiety and the sandwiched lipophilic moiety. Especially, compounds Ia～d could be dissoluble or scattered in aqueous solution and showed hydrophilic/lipophilic property-dependent herbicidal activity against the dicotyledon plant rape(Brassica campestris) and the monocotyledon plant barnyard grass(Echinochloa crus galli). At the concentration of 10 mmol·L~(-1), the inhibition rates of compounds Ia～d against the root growth of rape are 31.9, 90.8, 99.5 and 100%, respectively and the inhibition rates against the shoot elongation of barnyard grass are 19.3, 50.0, 80.2 and 100%, respectively.     

实时直接分析-静电场轨道阱高分辨质谱法应用于化妆品中15种抗过敏药物的定性和定量分析

提出了应用实时直接分析(DART)-静电场轨道阱高分辨质谱法对化妆品中15种抗过敏药物的定性和定量检测方法。称取样品0.50g,加入50%(体积分数)乙醇溶液1.0mL,于超声波水浴中超声处理5min,涡旋振荡10min后离心5min,取上清液0.50mL,加水0.5mL混匀后再次离心5min,取上清液,按仪器工作条件进行分析。采用Dip-it Samplers模式进样,进样量为1μL。在正离子模式下,以一级全扫描-数据依赖性二级扫描(Full MS-ddMS2)进行定性分析,与自建二级(MS2)谱库进行比对,得到定性筛查结果;随即以平行反应监测(PRM)模式进行定量分析。所测的15种抗过敏药物的线性范围均在10mg·L~(-1)以内。由于所测得的15种药物的测定下限的信噪比远大于10倍,故本方法将测定下限定为0.5mg·kg~(-1)。用空白样品为基体,加入混合标准溶液进行回收试验,测得回收率在82%以上;测定值的相对标准偏差(n=6)均小于16%。应用本方法分析了20个市售化妆品样品,在其中的7个样品中检出苯海拉明,在1个样品中检出氯苯那敏,且所得结果与液相色谱-串联质谱法(LC-MS/MS)所测结果一致。     

基于云计算的多特征疲劳驾驶检测系统研究与设计

随着私家车的普及,人们对汽车安全性、舒适性要求不断提高,通过对当前车载系统分析和汽车驾驶员疲劳驾驶状态研究,提出了一种基于信息融合的多特征疲劳驾驶检测方案。方案采用高性能嵌入式系统平台与云计算相结合的方式,首先,通过嵌入式系统采集驾驶员面部图像;然后,将数据传输到Face+ 云计算平台,分析当前驾驶人员身份、年龄与微笑程度;最后,采用数字图像处理技术计算驾驶员头部位移以及统计眼睛眨动规律,综合三种指标预测驾驶员是否处于疲劳状态,实时监测驾驶员驾驶全过程。当检测到驾驶员处于疲劳驾驶状态,则通过语音的方式提醒驾驶员注意行车安全、谨慎驾驶。测试结果表明：该方案检测精度高、实时性强,并且易于和车载系统整合并推广使用。     

光催化CO_2转化为碳氢燃料体系的综述

传统化石能源燃烧产生CO2引起的地球变暖和能源短缺已经成为一个严重的全球性问题.利用太阳光和光催化材料将CO2还原为碳氢燃料,不仅可以减少空气中CO2浓度,降低温室效应的影响,还可以提供碳氢燃料,缓解能源短缺问题,因此日益受到各国科学家的高度关注.本文综述了光催化还原CO2为碳氢燃料的研究进展,介绍了光催化还原CO2的反应机理,并对现阶段报道的光催化还原CO2材料体系进行了整理和分类,包括TiO2光催化材料,ABO3型钙钛矿光催化材料,尖晶石型光催化材料,掺杂型光催化材料,复合光催化材料,V、W、Ge、Ga基光催化材料及石墨烯基光催化材料.评述了各种材料体系的特点及光催化性能的一些影响因素.最后对光催化还原CO2的研究前景进行了展望.