2，6-二氰基苯胺衍生物的合成

以1-芳基亚乙基丙二腈(1),取代醛(2)和丙二腈(3)为原料,在吡咯烷催化下合成了一系列多取代2,6-二氰基苯胺类衍生物.较佳的反应条件为:11 mmol,n(1):n(2):n(3)=1:1:2,吡咯烷0.2 mol,THF 3mL,于40℃反应30 min,收率70%.     

反相高效液相色谱法测定硝酸咪康唑及其相关物质的含量

在LUNAC18色谱柱(250×4.6mmI.D,5μm)上,研究了硝酸咪康唑(Mi conazoleNitrate)及其相关物质(Alpha (2,4 Dichlorophenyl) 2 1H Imidazole 1 Ethanol)的反相高效液相色谱分离检测的最适宜条件,采用乙腈∶缓冲溶液=70∶30(V/V)为流动相,流速为1.0mL/min,检测波长为235nm,经实际样品测定,结果满意。这为跟踪产品的合成工艺,提高产品的质量提供了一个快速有效的检测方法。     

全球总闪电的天基光学实时探测技术综述

强对流天气是发生最频繁、影响最广泛的气象灾害,造成了巨大经济损失,严重威胁人民和社会安全,更是航空航天和信息通信等技术领域的重大威胁。闪电作为全球性强对流天气的典型要素,对强对流具有重要指示作用,因此闪电探测和强对流预警预报成为天基遥感的重要任务之一。系统地总结了闪电危害,闪电探测体系的发展历程和现状,天基闪电光学探测的技术难点、实现途径和发展现状;同时详细阐述了我国FY-4A闪电成像仪技术实现途径及在轨应用成果。FY-4A闪电成像仪利用时间滤波、空间滤波、超窄带光谱滤波、星上时空域多维融合点目标检测等多维技术实现了天基闪电光学探测载荷的研制与在轨应用,国内气象部门和众多科研院所利用FY-4A闪电成像仪的闪电探测结果实现了强对流灾害的精确预警预报,产生了重大经济效益与社会效益。最后,针对目前闪电探测体系存在的问题,分析了我国未来天基闪电探测系统的发展趋势,为我国后续闪电探测发展提供了参考。     

低气压闭式等离子体放电实验及光谱诊断

闭式等离子体可以克服等离子体隐身技术在开放环境中等离子体难以维持及能耗过大的问题。针对等离子体隐身应用,设计了一种封闭式的等离子体发生装置,选用微秒脉冲电源,以氩气为工质气体,在低气压环境下进行了放电实验。采用发射光谱法,测量了密闭腔体内部厚度方向上的Ar谱线强度,并将碰撞-辐射模型用于分析等离子体参数的分布规律。当放电参数确定时,给定电子温度和电子密度,可通过碰撞-辐射模型计算得到2p能级上的布居分布比值,将其与从光谱数据中得到的布居分布比值进行比较,当差异值最小时,即可确定相应的等离子体参数。通过对电子温度在1～5 eV范围内的2p9和2p1能级布居分布比值进行计算,分析了碰撞-辐射模型计算可能存在的误差。实验结果表明,在厚度方向上,封闭式腔体中的等离子体电子密度达到1011 cm-3量级且呈一定的梯度分布,但变化幅度不大,其分布情况有利于等离子体隐身技术的应用。     

Influence of air pressure on the performance of plasma synthetic jet actuator

Plasma synthetic jet actuator(PSJA) has a wide application prospect in the high-speed flow control field for its high jet velocity.In this paper,the influence of the air pressure on the performance of a two-electrode PSJA is investigated by the schlieren method in a large range from 7 k Pa to 100 k Pa.The energy consumed by the PSJA is roughly the same for all the pressure levels.Traces of the precursor shock wave velocity and the jet front velocity vary a lot for different pressures.The precursor shock wave velocity first decreases gradually and then remains at 345 m/s as the air pressure increases.The peak jet front velocity always appears at the first appearance of a jet,and it decreases gradually with the increase of the air pressure.A maximum precursor shock wave velocity of 520 m/s and a maximum jet front velocity of 440 m/s are observed at the pressure of 7 k Pa.The averaged jet velocity in one period ranges from 44 m/s to 54 m/s for all air pressures,and it drops with the rising of the air pressure.High velocities of the precursor shock wave and the jet front indicate that this type of PSJA can still be used to influence the high-speed flow field at 7 k Pa.     

UAV flight test of plasma slats and ailerons with microsecond dielectric barrier discharge

Plasma flow control(PFC) is a promising active flow control method with its unique advantages including the absence of moving components, fast response, easy implementation, and stable operation. The effectiveness of plasma flow control by microsecond dielectric barrier discharge(μs-DBD), and by nanosecond dielectric barrier discharge(NS-DBD) are compared through the wind tunnel tests, showing a similar performance between μs-DBD and NS-DBD. Furthermore, theμs-DBD is implemented on an unmanned aerial vehicle(UAV), which is a scaled model of a newly developed amphibious plane. The wingspan of the model is 2.87 m, and the airspeed is no less than 30 m/s. The flight data, static pressure data,and Tufts images are recorded and analyzed in detail. Results of the flight test show that the μs-DBD works well on board without affecting the normal operation of the UAV model. When the actuators are turned on, the stall angle and maximum lift coefficient can be improved by 1.3° and 10.4%, and the static pressure at the leading edge of the wing can be reduced effectively in a proper range of angle of attack, which shows the ability of μs-DBD to act as plasma slats. The rolling moment produced by left-side μs-DBD actuation is greater than that produced by the maximum deflection of ailerons,which indicates the potential of μs-DBD to act as plasma ailerons. The results verify the feasibility and efficacy of μs-DBD plasma flow control in a real flight and lay the foundation for the full-sized airplane application.     

Ag@Fe3O4@C-CdTe@SiO2磁性荧光复合微球的制备与光学特征

先采用一步溶剂热法和水热法制备了碳包覆的Ag@Fe₃O₄核壳型磁性纳米粒子,然后通过表面氨基化改性后与巯基乙酸修饰的CdTe量子点反应,将量子点键合到磁性微球上,最后在其表面包覆上一层二氧化硅壳层,制备出具有荧光增强的Ag@Fe₃O₄@C-CdTe@SiO₂磁性荧光复合材料。实验结果表明,该纳米粒子的平均粒径大约为150 nm,磁饱和强度为224 A/g（22.4 emu/g）,在室温下具有较好的磁性能。其中Ag@Fe₃O₄@C-CdTe磁性荧光纳米粒子的荧光强度大于Fe₃O₄@C-CdTe,其主要原因是内核为45 nm的Ag纳米粒子具有表面等离子体共振作用,能够使其表面或附近的量子点荧光得到增强。     

基于等离子体环量控制的翼型气动特性

为了研究等离子体环量控制对翼型的影响特性,采用基于唯象学的等离子体气动激励数学模型和二维雷诺平均N-S方程,选取NCCR 1510-7067N环量控制翼型,数值模拟后缘半径对升力和效费比的影响规律,并进行优化。设计最佳后缘半径模型进行低速风洞实验,获得迎角-4~12,速度6,10,15 m/s下的压力分布和升力特性。研究表明:后缘半径过大或过小都不利于Coanda效应的产生,确定最佳后缘半径与弦长的比值为0.048,效费比97.69。低雷诺数下,随着迎角的增加,出现了层流长泡分离和短泡分离,等离子体射流不仅改善了尾部流场,还通过环量增加抑制层流分离,提高了升力。     

新显色剂2-(5-羧基-1,3,4-三氮唑偶氮)-5-二乙氨基酚与钴的显色反应的研究

研究了新显色剂2-(5-羧基-1,3,4-三氮唑偶氮)-5-二乙氨基酚与钴的显色反应,试剂与钴在pH 6.0～8.0范围内形成稳定的紫红色络合物,其组成比为1:3,λ_(max)=540nm,络合物表观摩尔吸光系数为5.7×10~4,Co~(2+)在0～0.8mg·L~(-1)范围内符合比耳定律,络合物在强酸溶液中能稳定存在,可消除大量离子的干扰,有良好的选择性,方法可以不经分离直接测定维生素B_(12)和合成工业废水中的微量钴,结果满意。     

声场控制技术及其应用

随着多功能厅堂的发展和数字信号处理技术及其电声硬件设备的迅速进步,引入电声设备以支援和控制厅堂的声场或音质,即所谓声场控制(Active Field Control),是近年来厅堂音质设计中的一个引入注目的发展动向.本文阐述有关声场控制技术的原理、分类和特性,并介绍它们的典型的应用实例.