准完全带隙胶体非晶光子晶体

三维面心立方结构的固有的高对称性使其只具备非完全光子带隙,而非晶结构可降低对称性导致准完全光子带隙的出现.实验结果表明非晶胶状晶体具有准完全光子带隙.非晶胶状光子晶体中的光子带隙的禁带宽度与波长均不随光入射到样品池的角度的变化而明显变化.其禁带宽度比SiO₂小球面心单晶的禁带宽度宽得多 关键词： 光子带隙 非晶 光谱     

不同形貌介孔二氧化硅的可控制备与表征

介孔材料由于具有比表面积和孔体积较大、孔径均一、纳米尺寸可调、二氧化硅无生理毒性、热稳定性较好等一系列特点而引起了人们广泛的兴趣和关注.控制介孔二氧化硅的形貌和尺寸可以拓展介孔二氧化硅的应用,尤其是开发介孔二氧化硅在生物医学、色谱以及便于调控的催化材料等方面的用途.     

单分散ZnS及其复合颗粒的制备

本文以硫代乙酰胺（ＣＨ_３ＣＳＮＨ_２,简称ＴＡＡ）和醋酸锌（Ｚｎ（Ａｃ）_２）为主要原料,采用均匀沉淀法在水相体系中制备出了球形、分散较好的ＺｎＳ微粒子。在此基础上采用一种新方法,在ＺｎＳ表面原位合成ＺｎＳ／Ａｇ纳米微粒,并研究了其光谱性质。     

微量仪器非水滴定法测定硫酸铵

利用自行研制的微量容量仪器,采用非水滴定法测定硫酸铵的含量。对微型滴定法与常量滴定法的平行测定结果进行了比较。     

8-3线优先编码器74LS148的级联分析及研究

74LS148是一种带扩展功能的8-3线优先编码器,将多片74LS148集成8-3线优先编码器级联构成不同的编码器,能够灵活、有效地扩大编码器的使用范围。不同的74LS148进行级联时,任何时候只对其中优先级别最高的输入信号进行编码,编码器的工作状态由使能输入端决定。     

Electronic Transport of the Adsorbed Trigonal Graphene Flake： A First Principles Calculation

In recent years, electronic transport through molecular devices has attracted much attention due to the progress in experimental techniques for ma- nipulating individual molecules and the availabil- ity of the first-principles method to describe the elec- trical properties of devices. Graphene, a two- dimensional （2D） network of sp2 hybridized carbon atoms, has stimulated great research interest due to its unique electronic transport properties and its pro- found potential for future device applications. Chemical doping with foreign atoms is generally cho- sen to modify the electronic transport properties of carbon materials. The possibility of functionalizing graphene with radicals such as O, F, and H atoms has been experimentally demonstrated. One- dimensional GNRs and zero-dimensional graphene quantum dots （GQDs）, including triangular, rectangular and hexagonal shapes, which can be ob- tained through the geometry cutting method, pro- vide the possibility to explore low-dimensional trans- port properties for carbon-based nanoelectronics. The trigonal graphene flake （TGF）, a kind of representa- tive zero-dimensional GQD, is prominent in electronic and magnetic properties due to its n-fold degenerated half-filled zero-energy states. This novel property was revealed by both experimental and theoretical studies.     

船用捷联惯性导航系统姿态算法精度评估研究

分析了捷联惯性导航系统姿态解算中不可交换性误差产生原因，提出并分析了一种旋转矢量误差估计模型，并从该模型出发推导了几种高精度的捷联姿态算法，提出了由角速度提取角增量的梯形算法。以船舶为应用对象，进行了数字仿真和算法精度分析比较，结果表明：等效旋转矢量法和梯形算法可以提高系统的姿态解算精度。     

Hadronic Decays of the Spin-Singlet Heavy Quarkomium under the Principle of Maximum Conformality

The principle of maximum conformality （PMC） provides a way to eliminate the conventional renormalization scale ambiguity in a systematic way. By applying the PMC scale setting, all non-conformal terms in a perturbative series are summed into the running coupling, and one obtains a unique, scale-fixed prediction at any finite order. In this study, we make a detailed PMC analysis for the spin-singlet heavy quarkoniums decay （into light hadrons） at the next-to-leading order. After applying the PMC scale setting, the decay widths for all those cases are ahnost independent of the initial renormalization scales. The PMC scales for ηc and he decays are below 1 GeV; to achieve a confidential pQCD estimation, we adopt several low-energy running coupling models to carry out the estimation. By taking the MPT model, we obtain Г（ηc → LH） = 25.09 -4.28^＋5.52 MeV, F（ηb →LH） 14.34-0.84^＋0.92 feV, Г（hc →LH） = 0.54-0.04^＋0.06 MeV and Г（hb →LH） = 39.89-0.46^＋0.28 keV, where the errors are calculated by taking mc E[1.4OGeV, 1.60GeV] and mb C[4.50GeV, 4.70GeV]. These decay widths agree with the principle of minimum sensitivity estimations, in which the decay widths of ηc,b are also consistent with the measured ones.     

CdS-ZnSe和CdSe-ZnS量子点的合成和F(o)rster能量转移研究

采用分步合成法成功合成了CdS-ZnSe(Ⅰ型)和CdSe-ZnS(Ⅱ型)核-壳结构量子点.并首次构建了CdS-ZnSe/CdSe-ZnS结构F(o)rster能量转移对.利用吸收光谱(UV-Vis),光致发光谱(PL),时间分辨光致发光谱(TRPL),透射电子显微镜(TEM)对比研究了不同配比的CdS-ZnSe/CdSe-ZnS结构Fö rster能量转移.分析结果表明:在能量转移发生时,CdS-ZnSe荧光强度显著下降,荧光寿命明显缩短,F(o)rster能量转移确实存在于CdS-ZnSe/CdSe-ZnS量子点之间.     

几种金属盐催化剂对苯甲醛肟重排生成苯甲酰胺的催化作用

考察了SnCl2,CdCl2,Cr(CH3COO)3,Cr(NO3)3四种金属盐对苯甲醛肟重排生成苯甲酰胺反应的催化作用;以SnCl2作为模型催化剂,探讨了催化剂用量、反应温度及反应时间等因素对产率的影响,确定了最佳反应条件.结果表明,SnCl2对苯甲醛肟重排生成苯甲酰胺反应的催化效率最高;最佳反应条件为:n(SnCl2)∶n(苯甲醛肟)=2∶5,反应温度110℃,反应时间19h,相应的苯甲酰胺产率达57.6%.