全文获取类型
收费全文 | 164篇 |
免费 | 10篇 |
国内免费 | 30篇 |
专业分类
化学 | 52篇 |
晶体学 | 2篇 |
力学 | 66篇 |
综合类 | 5篇 |
数学 | 23篇 |
物理学 | 56篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 5篇 |
2021年 | 7篇 |
2020年 | 8篇 |
2019年 | 2篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 14篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 13篇 |
2012年 | 6篇 |
2011年 | 10篇 |
2010年 | 6篇 |
2009年 | 6篇 |
2008年 | 10篇 |
2007年 | 10篇 |
2006年 | 10篇 |
2005年 | 8篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 3篇 |
1997年 | 10篇 |
1996年 | 5篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
排序方式: 共有204条查询结果,搜索用时 15 毫秒
71.
72.
The paper presents the analytical geometric details of the mathematical modeling of a single point cutting tool with a generic profile. The grinding angles and the ground depths on the tool are allowed to vary along the tool flanks and face, altering the cutting angles from point to point. The surface modeling begins with the creation of a tool blank model. Then unbounded surfaces are considered and transformed to get the cutting tool surfaces. The intersection of these surfaces gives the complete model of the tool. Starting from the basic model where the tool face and flank are planar, the generalization of the geometric design has been done in two steps to give free-form shapes to the tool surfaces, termed as the two generations of the generic profile. Then a forward and inverse mapping has been presented for the basic model and the two generations of the generic tool to relate the grinding angles with the prevalent nomenclatures (ASA, ORS and NRS). The model has been validated and the variation of tool angles with the grinding parameters has been illustrated with an example. 相似文献
73.
Srinivasan K Kayalvizhi K Sivakumar K Stalin T 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(1):169-178
The photophysical, electrochemical and photoprototropic behaviors of diphenylamine (DPA) in aqueous β-cyclodextrin (β-CD) solution have been investigated using absorption spectroscopy and cyclic voltammetric techniques. Absorption of the neutral and cationic form of DPA is enhanced due to the formation of a 1:1 complex with β-CD. The formation of this complex has been confirmed by Benesi-Hildebrand plot and docking studies by RasMol tool methods. The solid complex of β-CD with DPA is investigated by FT-IR, XRD and AFM methods. The thermodynamic parameters (ΔG, ΔH and ΔS) of inclusion process are also determined. The pK(a) values of neutral-monocation equilibria have been determined with absorption (conjugate acid-base) titrations. A mechanism is proposed to explain the inclusion process. 相似文献
74.
Gert Nolze 《Crystal Research and Technology》2013,48(7):476-489
A concept based on the application of a cube as a general polyhedron is presented for the visualization of point group symmetry. The cube is used to represent both the highest and lowest crystal symmetries, with differences observable as patterns characteristic to each point group. Patterns are generated using direction‐specific color keys, which enable the recognition of point group‐specific distribution of vectors in an external reference frame. For the visualization of the incoherent hexagonal crystal classes, two twinned cubes are applied in order to generate symmetry operators that would otherwise be missing. The resulting hexagonal dipyramid is described in the frame of a cube, reducing the number of used symmetry operators from 72 to 60. The complete set of 32 polyhedra are suitable, for example, as a visual aid for understanding the crystal symmetry and/or sub‐ and supergroup relationships. 相似文献
75.
《基于设计的结构力学与机械力学》2013,41(4):509-528
Abstract Machine tool chatter is a self-excited vibration generated by chip thickness variation. It severely degrades the quality of the machined surface. The incidence of chatter is greatly affected by the dynamic characteristics of machine tool structure. This article extends chatter stability analysis to a machine tool equipped with a parallel mechanism. The vibration model of a parallel machine tool is derived, in which the legs of the parallel mechanism are considered as spring-damper systems. Then, the regenerative cutting dynamics is combined with the vibration model and stability analysis is performed. The chatter stability charts for various machining parameters are examined, with the example of the cubic parallel mechanism that is specially designed for machine tool use. 相似文献
76.
The effect of post‐oxidizing treatment on the characteristics of modified surface layers produced by salt bath nitrocarburizing on the industrial American Iron and Steel Institute (AISI) 02 tool steel types is investigated. Nitrocarburizing treatment is performed for 6 h and 8 h at 570 °C and post‐oxidizing treatment for 30, 60 and 90 min at 520 °C, using argon–steam mixture. Formed layers are characterized by their basic properties such as thickness layer, depth, surface hardness and wear resistance. Detailed estimation of the modified metal surface quality, in terms of chemical composition, formed phases, microstructures and diffusion mechanisms are performed by metallographic techniques, EDX, X‐ray diffraction, scanning electron microscopy (SEM) and glow discharge optical electron spectroscopy (GDOES). The corrosion resistance was investigated in 0.4 M H2SO4 solutions, using steady‐state electrochemical polarization methods. The obtained results revealed the existence of a superficial oxide layer which consists of magnetite (Fe3O4) and hematite (Fe2O3) and the presence of an ε‐phase associated with a small amount of γ′‐phase. Important improvements in wear, microhardness and corrosion resistance occur after these treatments and it is specifically concluded that the sole application of a nitrocarburizing treatment does not significantly ameliorate the corrosion resistance of the as‐received steel. In fact, post‐oxidation treatment contributes to increase corrosion resistance by forming a dense magnetite layer and at the same time, it partially covers the compound layer pores. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
77.
78.
热冲压模具钢SDCM高温摩擦磨损性能 总被引:1,自引:0,他引:1
为了研究新型热冲压模具材料SDCM钢的高温摩擦磨损性能,对比国外优质热作模具材料CR7V钢,利用扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线衍射分析(XRD),UMT-3型高温摩擦磨损试验机以及Bruker白光轮廓仪等手段研究了新型热冲压模具钢SDCM热处理后组织状态、抗氧化性能以及不同温度高温摩擦磨损后磨痕形貌、截面形貌、表面物相.结果表明:不同温度下SDCM钢磨损机制差异明显,100℃时,材料主要为黏着磨损,经过300℃、500℃轻微氧化磨损与黏着磨损共存的阶段后,700℃时,磨损机制转变为氧化磨损;在100~400℃范围内,CR7V由于含有更多的M23C6型和M7C3型碳化物(分别占总碳化物的3.4%和12.7%),因而具有较高的耐磨性;500~700℃范围内,SDCM因具有更高的抗回火软化能力;同时Cr元素含量较少,抗氧化能力较弱,能够及时形成摩擦氧化层,作为"润滑剂",提高材料的耐磨性. 相似文献
79.
合适的冷却润滑方式是改善切削摩擦,降低切削温度和切削力,提高刀具寿命的关键技术.采用干切、水冷、微量润滑(Minimum quantity lubrication,MQL)以及菜籽油润滑等四种方式进行了不同工艺参数下纯铁材料的车削试验,研究了冷却润滑方式对纯铁车削刀具磨损的影响机理.结果表明:纯铁车削时刀具磨损形态以主、副切削刃处的沟槽磨损和后刀面磨损为主,前刀面上黏结有工件材料并形成积屑瘤;MQL条件下的刀具寿命最长,而水冷时最小;扩散磨损、氧化磨损和黏结磨损是纯铁车削刀具的主要磨损机理;四种冷却润滑方式下切削力、前刀面与切屑间平均摩擦系数和表面显微硬度的显著差异是造成刀具寿命明显不同的根本原因. 相似文献
80.