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71.
72.
Two new Zn(Ⅱ)-MOFs were synthesized based on an asymmetric Schiff-base ligand LH, which is obtained by the condensation of 5-formyl-8-hydroxyquinoline and 3-pyridinecarboxylic acid hydrazide. In different mixed solvents, we get two new isomorphism compounds, [Zn(L)2]·C4H8O2·2MeOH(1) and [Zn(L)2]·CH2Cl2·2MeOH(2). Compounds 1 and 2 have been characterized by single-crystal X-ray diffraction, elemental analysis and IR. Compound 1 crystallizes in monoclinic, space group P21/c, with a = 13.856(4), b = 14.156(4), c = 9.620(3) , β = 110.167(5)°, V = 1771.3(9) 3, Dc = 1.500 g/cm3, C38H38N8O8 Zn, Mr = 800.13, F(000) = 832, μ(MoKα) = 0.761 mm-1, Z = 2, the final R = 0.0596 and wR = 0.1221 for 2112 observed reflections(I 2σ(I)). Compound 2 belongs to monoclinic, space group P21/c, with a = 13.575(3), b = 14.130(3), c = 9.485(2) , β = 107.908(3)°, V = 1731.2(6) 3, Dc = 1.529 g/cm3, C35H32Cl2N8O6 Zn, Mr = 796.96, F(000) = 820, μ(MoKα) = 0.926 mm-1, Z = 2, the final R = 0.0527 and wR = 0.1395 for 2501 observed reflections(I 2σ(I)). The Zn(Ⅱ) centers in both 1 and 2 display a distorted octahedral coordination geometry. The octahedral Zn(Ⅱ) nodes and L linkages build up 2-D nets consisting of parallelogram-like grids in the ab plane. The neighboring nets stack through hydrogen bonds to generate 3-D rhombic channels. In 1, the 1,4-dioxane and MeOH guests alternatively arrange in the channels and effectively take up the free space; while in 2, the CH2Cl2 guests are arranged in the channels. In addition, the encapsulated MeOH molecules are bonded to the framework by hydrogen bonds. 相似文献
73.
Simple examples are given of proper algebraic actions of the additive group of complex numbers on ?5 whose geometric quotients are, respectively, a?ne, strictly quasia?ne, and algebraic spaces which are not schemes. Moreover, a Zariski locally trivial action is given whose ring of invariant regular functions defines a singular factorial a?ne fourfold embedded in ?12. The geometric quotient for the action embeds as a strictly quasia?ne variety in the smooth locus of the algebraic quotient with complement isomorphic to the normal a?ne surface with the A2?singularity at the origin. 相似文献
74.
Let X be a partially ordered set, R a commutative 2-torsionfree unital ring and FI(X, R) the finitary incidence algebra of X over R. In this note we prove that each R-linear Jordan isomorphism of FI(X, R) onto an R-algebra A is the near-sum of a homomorphism and an anti-homomorphism. 相似文献
75.
John Krueger 《Annals of Pure and Applied Logic》2018,169(10):1044-1081
We prove the consistency, assuming an ineffable cardinal, of the statement that CH holds and any two normal countably closed -Aronszajn trees are club isomorphic. This work generalizes to higher cardinals the property of Abraham–Shelah [1] that any two normal -Aronszajn trees are club isomorphic, which follows from PFA. The statement that any two normal countably closed -Aronszajn trees are club isomorphic implies that there are no -Suslin trees, so our proof also expands on the method of Laver–Shelah [5] for obtaining the -Suslin hypothesis. 相似文献
76.
Yang Yun-xia Xu Min Dong Wenjing Ding Keying 《Molecular Crystals and Liquid Crystals》2018,664(1):69-76
By using 4,4′-dihydroxydiphenylsulfone (BPS) and 4,4′-dihydroxydiphenylsulfide (BTS) react with amidinethiourea and tetrabutylammonium respectively, two isomorphs of inclusion compounds of (n-C4H9)4N+·C12H9O4S?·C2H4N4S (1) and (n-C4H9)4N+·C12H9O2S?·C2H4N4S (2) were prepared and characterized by Single crystal X-ray diffraction. Although two varied types of V-shaped molecules were selected to react in the actual experimental process, two isomorphs with similar packing modes were finally obtained. Interestingly, amidinothiourea molecule occurred in situ oxidation reaction to generate a new compound of 3,5-dimido-1,2,4,-thiadiazole during the experiments, and these two inclusion compounds here are the pioneer examples of thiadiazole and tetraalkylammonium and can be regarded as two isomorphs due to their similar crystallization modes. In these two isomorphs, thiadiazole molecules derived from amidinothiourea link with various V-type molecules to develop the similar dumbbell-type hydrogen-bonded ribbons by the alike hydrogen bonding modes, then the ribbons interpenetrate with tetrabutylammonium to result in two stable isomorphism structures. 相似文献
77.
《Acta Crystallographica. Section C, Structural Chemistry》2018,74(6):760-768
The polyfluorinated title compounds, [MBr2(C18H16F8N2O2)] or [4,4′‐(HCF2CF2CH2OCH2)2‐2,2′‐bpy]MBr2, ( 1 ) (M = Pd and bpy is bipyridine) and ( 2 ) (M = Pt), have –CH(α)2OCH(β)2CF2CF2H side chains with methylene H‐atom donors at the α and β sites, and methine H‐atom donors at the terminal sites, in addition to aromatic H‐atom donors. In contrast to the original expectation of isomorphous structures, ( 1 ) crystallizes in the space group C2/c and ( 2 ) in P21/n, with similar unit‐cell volumes and Z = 4. The asymmetric unit of ( 1 ) is one half of the molecule, which resides on a crystallographic twofold axis. Both ( 1 ) and ( 2 ) display stacking of the molecules, indicating a planar (bpy)MBr2 skeleton in each case. The structure of ( 1 ) exhibits columns with C—H(β)…Br hydrogen bonds between consecutive layers which conforms to a static (β,β) linkage between layers. In the molecular plane, ( 1 ) shows double C—H(α)…Br hydrogen bonds self‐repeating along the b axis, the planar molecules being connected into infinite belts. Compound ( 2 ) has no crystallographic symmetry and forms π‐dimer pairs as supermolecules, which then stack parallel to the a axis. The π‐dimer‐pair supermolecules exhibit (Pt—)Br…Br(—Pt) contacts [3.6937 (7) Å] to neighbouring π‐dimer pairs crosslinking the columns. The structure of ( 2 ) reveals many C—H…F(—C) interactions between F atoms and aromatic C—H groups, in addition to those between F atoms and methylene C—H groups. 相似文献
78.
《Acta Crystallographica. Section C, Structural Chemistry》2018,74(5):590-598
Crystals of mononuclear tris[bis(2,6‐diisopropylphenyl) phosphato‐κO]pentakis(methanol‐κO)lanthanide methanol monosolvates of lanthanum, [La(C24H34O4P)3(CH3OH)5]·CH3OH, ( 1 ), cerium, [Ce(C24H34O4P)3(CH3OH)5]·CH3OH, ( 2 ), and neodymium, [Nd(C24H34O4P)3(CH3OH)5]·CH3OH, ( 3 ), have been obtained by reactions between LnCl3(H2O)n (n = 6 or 7) and lithium bis(2,6‐diisopropylphenyl) phosphate in a 1:3 molar ratio in methanol media. Compounds ( 1 )–( 3 ) crystallize in the monoclinic P21/c space group and have isomorphous crystal structures. All three bis(2,6‐diisopropylphenyl) phosphate ligands display a κO‐monodentate coordination mode. The coordination number of the metal atom is 8. Each [Ln{O2P(O‐2,6‐iPr2C6H3)2}3(CH3OH)5] molecular unit exhibits four intramolecular O—H…O hydrogen bonds, forming six‐membered rings. The unit forms two intermolecular O—H…O hydrogen bonds with one noncoordinating methanol molecule. All six hydroxy H atoms are involved in hydrogen bonding within the [Ln{O2P(O‐2,6‐iPr2C6H3)2}3(CH3OH)5]·CH3OH unit. This, along with the high steric hindrance induced by the three bulky diaryl phosphate ligands, prevents the formation of a hydrogen‐bond network. Complexes ( 1 )–( 3 ) exhibit disorder of two of the isopropyl groups of the phosphate ligands. The cerium compound ( 2 ) demonstrates an essential catalytic inhibition in the thermal decomposition of polydimethylsiloxane in air at 573 K. Catalytic systems based on the neodymium complex tris[bis(2,6‐diisopropylphenyl) phosphato‐κO]neodymium, ( 3′ ), which was obtained as a dry powder of ( 3 ) upon removal of methanol, display a high catalytic activity in isoprene and butadiene polymerization. 相似文献
79.
80.