Liquid–liquid equilibrium of the ternary system water + acetic acid + sec-butyl acetate

Experimental liquid–liquid equilibrium (LLE) of the water–acetic acid–sec-butyl acetate ternary system was investigated at 298.15, 303.15, 308.15 and 313.15 K and at atmospheric pressure. Separation factors were also evaluated for the immiscibility region. The NRTL and UNIQUAC models were applied to fit the experimental data for the ternary system. The binary interaction parameters obtained from both models were found to be successfully correlated with the equilibrium compositions. The UNIFAC group contribution method was employed to predict the observed ternary LLE data. It was found that four types of the UNIFAC model (UNIFAC, UNIFAC-LL, UNIFAC-DMD, and UNIFAC-LBY) did not provide a good prediction of the LLE data for this ternary system.     

一种在二步相移数字全息中实现准确相移的方法

相移数字全息中的相移准确性决定了重建结果的质量,本文提出了在二步相移数字全息中.实现准确相移的方法.该方法使用数字电压源开环控制普通的压电陶瓷微位移器,通过连续以微小的间隔来改变施加在压电陶瓷微位移器上的电压,可以获得一系列对应于不同相移角的全息图像,进而可以利用这些全息图像重建出来物光波在全息面上的强度分布.实验中采...     

Intensity and spatial correlation properties of tightly focused partially coherent radially polarized vortex beams

By expanding the Debye theory into the tight focusing of partially coherent field, the intensity and spatial correlation properties of partially coherent radially polarized vortex beams are studied. Expressions are derived for the intensity distribution and the spectral degree of coherence in the focal region. It is found that the intensity and the transverse and longitudinal coherence degrees in the focal region change with the variation of the topological charge and coherence length of the vortex beam. In addition, the degree of coherence is shown to exhibit phase singularities.     

730 eV电子碰撞He原子(e, 2e)电离的三重微分截面

考虑初态He原子电子间的关联效应、末态敲出电子与剩余束缚电子间的关联效应和末态屏蔽效应, 计算和分析了在共面、大能量损失和小动量转移这一特殊几何条件下730eV电子离化He原子的三重微分截面. 所得结果与Stevenson等人的相对实验数据和CCC理论计算结果进行比较发现: 所得到的理论曲线能够反映实验数据给出的三重微分截面的结构特征.     

Bosonic enhancement of spontaneous emission near an interface

We show how the spontaneous emission rate of an excited two-level atom placed in a trapped Bose-Einstein condensate of ground-state atoms is enhanced by bosonic stimulation. This stimulation depends on the overlap of the excited matter-wave packet with the macroscopically occupied condensate wave function, and provides a probe of the spatial coherence of the Bose gas. The effect can be used to amplify the distance-dependent decay rate of an excited atom near an interface.     

Scaling characteristics of ocean wave height time series

Fluctuations in the significant wave height can be quantified by using scaling statistics. In this paper, the scaling properties of the significant wave height were explored by using a large data set of hourly series from 25 monitoring stations located off the west coast of the US. Detrended fluctuation analysis (DFA) was used to investigate the scaling properties of the series. DFA is a robust technique that can be used to detect long-range correlations in nonstationary time series. The significant wave height data was analyzed by using scales from hourly to monthly. It was found that a common scaling behavior can be observed for all stations. A breakpoint in the scaling region around 4-5 days was apparent. Spectral analysis confirms this result. This breakpoint divided the scaling region into two distinct parts. The first part was for finer scales (up to 4 days) which exhibited Brown noise characteristics, while the second one showed 1/f noise behavior at coarser scales (5 days to 1 month). The first order and the second order DFA (DFA1 and DFA2) were used to check the effect of seasonality. It was found that there were no differences between DFA1 and DFA2 results, indicating that there is no effect of trends in the wave height time series. The resulting scaling coefficients range from 0.696 to 0.890 indicating that the wave height exhibits long-term persistence. There were no coherent spatial variations in the scaling coefficients.     

Correlation structure of time-changed Pearson diffusions

The stochastic solution to diffusion equations with polynomial coefficients is called a Pearson diffusion. If the time derivative is replaced by a distributed order fractional derivative, the stochastic solution is called a distributed order fractional Pearson diffusion. This paper develops a formula for the covariance function of distributed order fractional Pearson diffusion in the steady state, in terms of generalized Mittag-Leffler functions. The correlation function decays like a power law. That formula shows that distributed order fractional Pearson diffusions exhibits long range dependence.     

Chemical Shift and Its Uses as an Electronic Parameter in Structure-Activity Correlations

Apparent correlations are found between the N-H chemical shifts of congeneric series of compounds and the dipole moments of the molecules, such as lactams and thiolactams, cyclic ureas and thioureas. When there is a high degree of correlation, either the N-H chemical shift or the dipole moment of the molecule can be used as an electronic parameter in correlating the biological activity with the chemical structure. In a series of substituted salicylaldehydes the Hammett σ constant gives better correlation with the biological activity than the O-H chemical shift. This is probably due to the anisotropic effect of the substituent besides the electronic effect. Other factors affecting the N-H chemical shift, e.g. intramolecular hydrogen-bonding of nitrosoureas and the deshielding effect of a benzene ring, in o-phenyleneureas are also presented. In spite of the limitations, the chemical shifts of many compounds can be obtained very easily, therefore, their uses in structure-activity correlations deserve further investigation.     

Effect of Temperature and Composition on the Density and Viscosity of Binary Mixtures of Ionic Liquid with Alcohols

Density and viscosity were determined for the binary mixtures containing the ionic liquid 1-butyl-3-methylimidazolium thiocyanate ([BMIM][SCN]) and 1-alcohols (1-butanol, 1-pentanol and 1-hexanol) at six temperatures (298.15, 308.15, 318.15, 328.15, 338.15 and 348.15) K and ambient pressure. The density and viscosity correlation for these systems was tested by an empirical second-order polynomial and by the Vogel-Fucher-Tammann equation in wide ranges of temperatures. Excess molar volumes were described by the Redlich-Kister polynomial expansions. The density and viscosity variations with composition were described by polynomials. A qualitative analysis of the trend of the properties with solvent and temperature was performed. The obtained results indicate that ionic liquid interactions with 1-alcohols are strongly dependent on the special trend of packing of this ionic liquid into hydroxylic solvents. As previously observed, an increase of the 1-alcohol carbon-chain length leads to lower interactions on mixing. Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.