A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

IntroductionSince Wilson and co- workers successfullysynthesized three- dimensional microporousaluminophosphates (Al PO4 - n ) [1] in the 1 980 s,much attention has been focused on the explorationof1 - D chain,2 - D layer and3 - D open- frameworkmetal phosphates from aqueous or non- aqueoussystems.The number of metals incorporated intothe frameworks of these materials is continuouslyincreasing and the metals include Be[2 ] ,Ga[3] ,In[4 ] ,Sn[5] ,Sb[6 ] ,and the transition metals Zn[7] ,Ni…     

Effects of the Specific Area and the Thermal Stability of a Polymer on the Catalytic Activities of Polymer Immobilized Co-Pd Catalysts by SAMI

Co-Pd bimetallic catalysts immobilized with four kinds of resins with different specific areas were prepared by means of the solvated metal atom impregnation (SMAI) method. The results of the XRD and the magnetic measurement showed that as the specific area of the resin increased, the particle sizes of Co and Pd on the catalysts with the same metal content decreased, so the catalytic activity of the catalysts for the hydrogenation of diacetone alcohol as well as the reduction of oxygen on the fuel cell electrode increased. Below 140 , the conversion of diacetone alcohol increased as the reaction temperature increased, and above 140 , the conversion decreased because of the rupture of the resin.     

A Fluorescence Optical Fiber Sensor for Amrinon Using a New Oxazole Compound

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不同铺层角度复合材料Ω形柱的吸能特性

复合材料Ω形柱在碰撞吸能和轻量化方面具有一定的应用潜力，为研究铺层角度和加载速率对复合材料Ω形柱吸能性能的影响，开展了碳纤维复合材料Ω形柱的轴向压缩实验，深入分析了其吸能评价指标及破坏机理。主要研究内容及结果如下：进行了3种铺层角度([0/90]_3s、[0/45/90/-45]₃和[±45]_3s)Ω形柱的准静态和动态压缩实验研究。准静态加载时，[0/90]_3s和[0/45/90/-45]₃铺层角度试样均表现为渐进破坏，而[±45]_3s铺层角度试样表现为非稳态破坏，破坏模式的不同导致其比吸能约为前2种铺层试样的1/2；动态加载时，3种铺层角度的Ω形柱均表现为渐进破坏，且比吸能较为接近。其中，[0/90]_3s和[0/45/90/-45]₃铺层角度Ω形柱在动态加载时的比吸能较准静态分别降低了29.70%和20.97%，而[±45]_3s比吸能较准静态提高了46.10%，破坏模式的转变是其比吸能提高的...     

The Elastic Continuum Limit of the Tight Binding Model

The authors consider the simplest quantum mechanics model of solids,the tight binding model,and prove that in the continuum limit,the energy of tight binding model converges to that of the continuum elasticity model obtained using Cauchy-Born rule.The technique in this paper is based mainly on spectral perturbation theory for large matrices.