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621.
N. N. Makhova V. Yu. Petukhova T. V. Chabina L. I. Khmel'nitskii 《Russian Chemical Bulletin》1993,42(9):1602-1603
Unsubstituted 1,3,5-triazabicyclo[3.1.0]hexane has been syntesized for the first time by treating a Henry solution with NaOCl.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1665–1666, September, 1993. 相似文献
622.
Aleksandra Konopacka Joanna Pająk Guido Maes Zbigniew Pawełka 《Monatshefte für Chemie / Chemical Monthly》2007,138(12):1233-1238
Summary. The optimal geometries, energies, polarities, infrared frequencies, and intensities of the non-polar and polar conformers
of 1,3,5-triacetylbenzene were calculated using DFT/B3LYP/6-311G** and semi-empirical (AM1 and PM3) methods. All the methods revealed that the non-polar conformer prevails in vacuum.
The infrared spectra in the solid state, in Ar matrix, and in liquid solutions as well as the dipole moments of 1,3,5-triacetylbenzene
in many solvents show the distinct influence of the environment on the non-polar conformer ⇌ polar conformer equilibrium.
The effect of solvent polarity on the standard Gibbs energy of this conformational equilibrium is quantitatively discussed in terms of the continuum-homogenous dielectric model. 相似文献
623.
Thermal decomposition of 2,4,6-trinitrotoluene in the temperature range from 200 to 340 °C in melt and in solutions was studied. The main features of the process (high initial rates, activation energies lower than those in the gaseous phase, a higher acceleration at the catalytic stage, and the effect of nonpolar solvents on initial rates) are explained in terms of a kinetic scheme corresponding to a degenerate branched chain reaction.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 266–271, February, 1995. 相似文献
624.
Mikhailichenko S. N. Chesnyuk A. A. Konyushkin L. D. Zaplishnyi V. N. 《Russian Chemical Bulletin》2003,52(10):2157-2160
Reactions of (4,6-disubstituted 1,3,5-triazin-2-yl)trimethylammonium chlorides with glycine sodium salt in the presence of Et3N afforded bis(triazin-2-yl) ethers instead of the expected triazinylaminoacetic acids. The structures of the resulting compounds were established by the independent synthesis, spectroscopic data, and X-ray diffraction analysis. 相似文献
625.
Lozinskaya N. A. Tsybezova V. V. Proskurnina M. V. Zefirov N. S. 《Russian Chemical Bulletin》2003,52(3):674-678
Novel data were obtained concerning the reaction of aromatic aldehydes with ammonia. A preparative method for the synthesis of new substituted 1,3,5-triaryl-2,4-diazapenta-1,4-dienes was developed. These products are the starting reactants for syntheses of cis- and trans-2,4,5-triaryl-2-imidazolines and 2,4,5-triarylimidazoles. 相似文献
626.
M. Spoliti L. Bencivenni J. J. Quirante F. Ramondo 《Journal of Molecular Structure》1997,390(1-3):139-148
The molecular conformers of the molecule 1,3,5-benzenetriol have been studied by ab initio and density functional methods to determine optimized equilibrium geometries, harmonic vibrational frequencies and relative stability. The results of the quantum-chemical calculations have been used to investigate the functional theory-infrared (FT-IR) spectrum of the 1,3,5-benzenetriol vapors trapped in Ar matrix at 12 K. 相似文献
627.
628.
Dalinger I. L. Cherkasova T. I. Vorob"ev S. S. Aleksandrov A. V. Popova G. P. Shevelev S. A. 《Russian Chemical Bulletin》2001,50(12):2401-2405
The direction of the nitro group substitution (the ratio of the ortho/para substitution) in 2,4,6-trinitrobenzonitrile under the action of anionic nucleophiles (MeO–, RS–, and N3
–) as well as of HCl was studied. The factors favoring ortho substitution were revealed. 相似文献
629.
Aminomethylation of 2,6-diamino-4-aryl-4H-thiopyran-3,5-dicarbonitriles in the Mannich reaction with p-toluidine and formaldehyde unexpectedly gave pyrimido[4,3-b][1,3,5]thiadiazine derivatives. The same compounds were obtained in an independent way involving a multicomponent cascade
condensation of aromatic aldehydes, cyanothioacetamide, p-toluidine, and formaldehyde.
For Part 5, see Izv. Akad. Nauk, Ser. Khim., 2007, 1384 [Russ. Chem. Bull., Int. Ed., 2007, 56, 1437].
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1420–1422, July, 2007. 相似文献
630.
Kazuaki Shimada Yaling Gong Hidenori Nakamura Rei Matsumoto Shigenobu Aoyagi Yuji Takikawa 《Tetrahedron letters》2005,46(21):3775-3778
Treatment of a benzene or a CH2Cl2 solution of bis(N,N-dimethylcarbamoylseleno)methanes with SnCl4 afforded β-1,3,5-triselenanes, and the key intermediates, acylselonium ions and selenoaldehydes, were successfully trapped by using allyltrimethylsilane or 2,3-dimethyl-1,3-butadiene to obtain the allylation products or the cycloadducts, respectively. 相似文献