不确定混沌系统的径向基函数神经网络反馈补偿控制

对不确定混沌系统控制问题, 研究了一种基于径向基函数神经网络(radial basis function neural network, RBFNN)的反馈补偿控制方法. 该方法首先用RBFNN对混沌系统的动力学特性进行学习, 然后用训练好的RBFNN模型对混沌系统进行反馈补偿控制. 该方法的特点是不需要被控混沌系统的数学模型,可以快速跟踪任意给定的参考信号. 数值仿真试验表明了该控制方法不仅具有响应速度快、控制精度高, 而且具有较强的抑制混沌系统参数摄动能力和抗干扰能力.     

飞秒激光低压N2等离子体特性的实验研究

在低于一个标准大气压的条件下对飞秒激光产生的N₂等离子体光谱进行了实验研究.结果表明, 各种样品气压下的激光N₂等离子体光谱均表现为连续谱和线状谱的叠加.随着样品气压的降低, 连续谱和原子谱线的强度经历了由缓慢增强发展为缓慢降低再到迅速降低的过程, 而正一价离子谱线强度呈现逐步增强的特征.在气压低于0.3 atm (1 atm=101325 Pa)时, 出现了正二价态的离子谱线. 给出了低压N₂等离子体对于飞秒激光传输和能量吸收的物理特性, 并初步讨论了低压等离子体通道特性.这些结果有助于加深了解飞秒激光等离子体的特性和机理, 特别是给出了在实验上测量不同价态离子光谱的条件, 为今后的研究提供了有益的实验依据. 关键词： 飞秒激光 气压 等离子体光谱 激光传输     

色散补偿光子晶体光纤结构参数对其色散的影响

光子晶体光纤由于其灵活可调的色散特性用作色散补偿具有极大的应用潜力. 设计了一种色散补偿光子晶体光纤, 并运用频域有限差分法模拟了其色散特性,从理论上分析了其结构参数孔间距Λ和空气占空比d/Λ对该光子晶体光纤的色散系数的影响, 并且实际制备出了3种不同结构参数的光子晶体光纤. 通过对其色散曲线对比分析表明: 当光子晶体光纤孔间距在1 μm附近时, 其色散系数随着孔间距Λ和占空比d/Λ的增大而增加, 但对于孔间距Λ的变化比占空比d/Λ更为敏感, 并且随着孔间距Λ的增加,其对色散系数的影响能力逐渐减小. 设计并制备的光子晶体光纤在1550 nm处的色散系数为-241.5 ps·nm^-1·km^-1, 相对色散斜率为0.0018, 具有较好的色散补偿能力. 关键词： 色散 色散补偿 光子晶体光纤 结构参数     

Synthesis and characterization of insulin-5-Fu conjugate,enabling insulin as multi-drug carrier via dendritic approach

To enable insulin as multi-drug carrier, we designed and synthesized dendritic linker molecule bearing three 5-Fluorouracil residues at the branch ends. The new conjugate showed excellent water solubility. The stabilities under different conditions were investigated. The results showed that the conjugate was a potential prodrug to release free 5-Fu.     

Capillary electrophoresis with direct chemiluminescence detection for the analysis of catecholamines in human urine

A rapid and sensitive method for the analysis of three catecholamines by capillary electrophoresis(CE)with directchemiluminescence(CL)detection is described.The detection limits(S/N=3)were 1.3*10-8g/mL for isoprenaline,1.0*10-8g/mL for epinephrine and 2.8*10-8g/mL for dopamine.The proposed method was successfully applied to theanalysis of catecholamines in urine samples of cigarette smokers and nonsmokers.The results showed that there is a close relationbetween the release of dopamine in human body fluids and cigarette smoking/nonsmoking.     

Structural Study of Inclusion Complex of Andrographolide with β-Cyclodextrin Prepared under Microwave Irradiation

Andrographolide (Andro) (Figure 1) is a diterpene lactone isolated from Andrographis paniculate Nees1. It has showed several biological activities including analgesic, antipyretic and anti-inflammatory effects2. However, its poor water solubility and unstability towards oxygen restrained its application. In pharmaceutics, b-CD is used to increase solubility and stability3. We have prepared the inclusion compound of Andro/b-CD (Figure 2) under microwave irradiation4. It has been found…     

DSC and NMR Study on the Inclusion Complex of Lappaconitine with b-Cyclodextrin

Lappaconitine (Figure 1) is a diterpenoid alkaloid, naturally occurring in roots and rhizomes of Aconitum and delphinium1. Lap reveals bradycardic and hypotensive activity2. But its application is restrained owing to its poor water solubility, toxicity and side effects on humans. In a number of pharmaceutical studies, b-CD has been reported to interact with many drug molecules to form inclusion complexes for improving the water solubility of drugs, and reducing their toxicity3. We have p…     

Novel Stereoselective Synthesis of (E)-a,b-Unsaturated Esters by the Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction from Phosphonium and Arsonium Salt

Wittigreactionisoneofthemostimportantmethodfortheformationofcarbon-carbondoublebondandhasbeenwidelyusedinthesynthesisofnaturalproducts1,2.Recentlyitwasfoundthatalcoholscanundergoinsituoxidation-Wittigreactionwithphosponiumylidestogivecorrespondingolefinationproducts,whichhasgreatpotentialutilitiesinorganicsynthesis3.Tosimplifytheprocedureofthereactionfurther,weconsideredtocombinethedeprotonationofylide,oxidationofalcoholandWittigreactionintoonetandemreaction.Weutilizedphosphoniumorarsoniumsal…     

双色飞秒脉冲场作用下吡啶分子的弛豫动力学研究

利用自制的飞秒激光系统和飞行时间质谱仪结合泵浦探测的方法对吡啶分子的弛豫动力学进行了研究.用265和398nm的飞秒激光分别作为泵浦光和探测光,通过(1+2′)的共振增强多光电子电离的办法测量了C5H5N+离子强度随时间演化的情况,从而测得吡啶分子在265nm激发的S1电子态有一寿命为(3.3±0.1)ps的快速弛豫过程.     

FIBONACCI SEQUENCE AND CANTOR'S TERNARY SET

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