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61.
62.
M. A. Hegazy S. H. El-Hamouly M. M. Azab S. I. Beshir M. A. Zayed 《Polymer Science Series B》2014,56(2):182-190
N-(2-thiazolyl)methacrylamide (TMA) monomer was synthesized from 2-aminothiazole by two different methods. The homo- and copolymerization of this monomer with methyl methacrylate (MMA), styrene (St), acrylonitrile (AN), and vinyl acetate (VA) were performed in dimethyl formamide using 1 mol% AIBN at 70°C. The copolymerization behavior was studied in a wide composition interval with the mole fractions of TMA ranging from 0.1 to 0.7 in the feed. Characterization using FTIR and 1HNMR techniques confirmed the structure of the monomer and the prepared homo- and copolymers, but the copolymers compositions were determined from sulphur analysis. The monomer reactivity ratios were computed using Fineman and Ross and Kelen and Tüdös methods for the systems TMA-MMA, TMA-St, TMA-AN and TMA-VA and were found to be r 1 = 0.59 ± 0.05, r 2 = 2.72 ± 0.03; r 1 = 0.39 ± 0.02, r 2 = 0.90 ± 0.01; r 1 = 0.77 ± 0.06, r 2 = 1.99 ± 0.04 and r 1 = 0.80 ± 0.08, r 2 = 0.40 ± 0.05 respectively (r 1 corresponds to monomer reactivity ratio of TMA). The Q and e values for TMA monomer were found to be 1.079 and ?0.054. The synthesized monomer and polymers were tested in vitro for biological activity against some microorganisms, using the disk diffusion technique. Generally, all the polymers were effective against the tested microorganisms, but their growth-inhibition effects varied. 相似文献
63.
A method using micellar electrokinetic chromatography coupled with large-volume sample stacking for the determination of ticagrelol was developed and validated. The analysis was performed in a fused silica capillary (41.5 cm effective length, 50 μm diameter) with ultraviolet detection at 195 nm. The background electrolytes were 30 mM phosphate buffer of pH 3.0 with 120 mM sodium dodecylsulfate and 10 % (v/v) acetonitrile (120 s X 50 mbar; 20°C; -18 kV) and 30 mM borate buffer of pH 8.5 with 75 mM sodium dodecylsulfate (120 s X 50 mbar; 20°C; 25 kV); under acidic and alkaline conditions, respectively. The method was found to be reliable with respect to specificity, linearity of the calibration line (R2 > 0.99), repeatability (relative standard deviation 2.56%–3.34%), and accuracy (recovery in the range 101.21%–102.67%). The limits of detection and quantitation were 0.032, 0.071, and 0.087, 0.188 μg/mL, respectively. The method was successfully applied for the determination of ticagrelol concentrations in rat plasma and tablets with good recoveries and reproducibility. The presented method proved to be suitable for monitoring ticagrelor in rat plasma. 相似文献
64.
In this article, the fractional derivatives in the sense of the modified Riemann-Liouville derivatives together with the modified simple equation method and the multiple exp-function method are employed for constructing the exact solutions and the solitary wave solutions for the nonlinear time fractional Sharma-Tasso- Olver equation. With help of Maple, we can get exact explicit 1-wave, 2-wave and 3-wave solutions, which include 1-soliton, 2-soliton and 3-soliton type solutions if we use the multiple exp-function method while we can get only exact explicit 1-wave solution including 1-soliton type solution if we use the modified simple equation method. Two cases with specific values of the involved parameters are plotted for each 2-wave and 3-wave solutions. 相似文献
65.
Zayed MA Hawash MF Fahmey MA El-Habeeb AA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,68(3):970-978
Sertraline (C(17)H(17)Cl(2)N) as an antidepressant drug was investigated using thermal analysis (TA) measurements (TG/DTG and DTA) in comparison with electron impact (EI) mass spectral (MS) fragmentation at 70eV. Semi-empirical MO-calculations, using PM3 procedure, has been carried out on neutral molecule and positively charged species. These calculations included bond length, bond order, bond strain, partial charge distribution and heats of formation (DeltaH(f)). Also, in the present work sertraline-iodine product was prepared and its structure was investigated using elemental analyses, IR, (1)H NMR, (13)C NMR, MS and TA. It was also subjected to molecular orbital calculations (MOC) in order to confirm its fragmentation behavior by both MS and TA in comparison with the sertraline parent drug. In MS of sertraline the initial rupture occurred was CH(3)NH(2)(+) fragment ion via H-rearrangement while in sertraline-iodine product the initial rupture was due to the loss of I(+) and/or HI(+) fragment ions followed by CH(2)NH(+) fragment ion loss. In thermal analyses (TA) the initial rupture in sertraline is due to the loss of C(6)H(3)Cl(2) followed by the loss of CH(3)-NH forming tetraline molecule which thermally decomposed to give C(4)H(8), C(6)H(6) or the loss of H(2) forming naphthalene molecule which thermally sublimated. In sertraline-iodine product as a daughter the initial thermal rupture is due to successive loss of HI and CH(3)NH followed by the loss of C(6)H(5)HI and HCl. Sertraline biological activity increases with the introduction of iodine into its skeleton. The activities of the drug and its daughter are mainly depend upon their fragmentation to give their metabolites in vivo systems, which are very similar to the identified fragments in both MS and TA. The importance of the present work is also due to the decision of the possible mechanism of fragmentation of the drug and its daughter and its confirmation by MOC. 相似文献
66.
E.M.E.Zayed 《数学物理学报(B辑英文版)》2003,23(1):104-116
this paper studies the influence of a finite container on an ideal gas,The trace of the heat kernel Θ(t)=∑(μ=1)^∞ exp(-tλμ),where{λμ}(μ=1)^∞ are the eigenvalues of the negative Laplacian-△n=-∑(p=1)^n (a/axp)^2 in R^n(n=2 or 3) ,is studied for a general mult-connected bounded drum Ω which is surrounded by simply connected bounded domains Ωi with smooth boundaries aΩi(i=1,……,m) where the Dirichlet ,Neumann and Robin boundary Conditions on aΩi(i=1,……,m) are considered.Some geometrical properties of Ω are determined ,The theremodynamic quantities for an ideal gas encolosed in Ω are examined by using the asymptotic expansions of Θ(t) for short-sime t.It is shown that the ideal gas can not feel the shape of its container Ω,althought it can feel some geometrical properties of it. 相似文献
67.
S. M. A. D. Zayed A. Hassan I. Y. Mostafa 《Isotopes in environmental and health studies》2013,49(10):414-417
The metabolism of Dipterex in mammals, insects, plants, and microorganisms is discussed. Based on studies with P32- and C14- labelled Dipterex the degradation of the insecticide and the different metabolic pathways are indicated. Whereas the detoxification of Dipterex in mammals and in cotton plant proceeds mainly via hydrolysis of the phosphonate C–P bond, its degradation in microorganisms invokes only O–CH3 ester cleavage. In Prodenia larvae, Dipterex is metabolized preferentially (70%) by hydrolysis of O–methyl ester linkages and to a minor extent (30%) by splitting of C–P bond. 相似文献
68.
Awen BZ Unnithan CR Ravi S Kermagy A Sasikumar JM Khrbash AS Ekreem WL 《Natural product research》2011,25(9):927-933
Retama raetam (Forssk) Webb & Berthel is well known in the folk medicine of North and East Mediterranean regions for the treatment of microbial infections. The powdered leaves are used to heal circumcision wounds and used as an antiseptic for wounds, skin rash and pruritus. In this study, to validate this antiseptic property, the chemical composition and antimicrobial activity of the essential oil from the flowers of R. raetam was evaluated. The oil was obtained using hydrodistillation and was analysed by gas chromatography-mass spectrometry. The antibacterial activity was achieved using disc diffusion and broth dilution assay against six bacteria species. Analysis of the essential oil revealed the presence of β-linalool (51%), 2-decen-1-ol (6.6%) and limonene (7.4%) as the major components. The results showed significant activity against microorganisms, especially Staphylococcus aureus, with inhibition zones and minimal inhibitory concentration values in the range of 5.0 mm and 3.0 mg mL?1, respectively. The results on the antibacterial activity provide scientific support for the use of these plants in traditional herbal preparations. 相似文献
69.
Simple, rapid and accurate new method is described for the simultaneous determination of ibuprofen (IB) and paracetamol (PA) in two components mixture and Cetofen tablets. The method depends on the derivative of the ratio spectra DD by measurement of the amplitude of 1DD at 225.6 nm and the amplitude of 2DD at 238.9 nm for IB and PA. Calibration graphs are linear in the range 2–32 (LOD 0.53) and 2–24 (LOD 0.57) μg/ml IB and PA, respectively. The proposed method is successfully applied for simultaneous determining IB and PA in authentic mixtures and Cetofen tablets. 相似文献
70.
el-Gamel NE Zayed MA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,82(1):414-423
The synthesis and characterization of binary Cu(II)- (1), Co(II)- (2), Ni(II)- (3), Mn(II)- (4), Cr(III)- (5), Fe(III)- (6), La(III)- (7), UO2(VI)- (8) complexes with sparfloxacin (HL1) and ternary Cu(II)- (9), Co(II)- (10), Ni(II)- (11), Mn(II)- (12), Cr(III)- (13), Fe(III)- (14), La(III)- (15), UO2(VI)- (16) complexes with sparfloxacin (HL1) and dl-alanine (H2L2) complexes are reported using elemental analysis, molar conductance, magnetic susceptibility, IR, UV–Vis, thermal analysis and 1H-NMR spectral studies.The molar conductance measurements of all the complexes in DMF solution correspond to non-electrolytic nature.All complexes were of the high-spin type and found to have six-coordinate octahedral geometry except the Cu(II) complexes which were four coordinate, square planar and U- and La-atoms in the uranyl and lanthanide have a pentagonal bipyramidal coordination sphere. The antimicrobial activity of these complexes has been screened against two Gram-positive and two Gram-negative bacteria. Antifungal activity against two different fungi has been evaluated and compared with reference drug sparfloxacin. All the binary and ternary complexes showed remarkable potential antimicrobial activity higher than the recommended standard agents. Ni(II)- and Mn(II) complexes exhibited higher potency as compared to the parent drug against Gram-negative bacteria. 相似文献