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61.
Dynamic Green's function plays an important role in the study of various wave radiation, scattering and soil-structure interaction problems. However, little research has been done on the response of transversely isotropic saturated layered media. In this paper, the 3D dynamic responses of a multi-layered transversely isotropic saturated half-space subjected to concentrated forces and pore pressure are investigated. First, utilizing Fourier expansion in circumferential direction accompanied by Hankel integral transform in radial direction, the wave equations for transversely isotropic saturated medium in cylindrical coordinate system are solved. Next, with the aid of the exact dynamic stiffness matrix for in-plane and out-of-plane motions, the solutions for multi-layered transversely isotropic saturated half-space under concentrated forces and pore pressure are obtained by direct stiffness method. A FORTRAN computer code is developed to achieve numerical evaluation of the proposed method, and its accuracy is validated through comparison with existing solutions that are special cases of the more general problems addressed. In addition, selected numerical results for a homogeneous and a layered material model are performed to illustrate the effects of material anisotropy, load frequency, drainage condition and layering on the dynamic responses. The presented solutions form a complete set of Green's functions for concentrated forces (including horizontal load in x(y)-direction, vertical load in z-direction) as well as pore pressure, which lays the foundation for further exploring wave propagation of complex local site in a layered transversely isotropic saturated half-space by using the BEMs. 相似文献
62.
63.
Nonlinear Dynamics - Conservative chaotic flows, a category of incompressible chaos, are usually generated from dynamical systems without dissipation. The existing results on conservative chaos are... 相似文献
64.
Jun Xu Victor V. Terskikh Yueying Chu Anmin Zheng Yining Huang 《Magnetic resonance in chemistry : MRC》2020,58(11):1082-1090
Metal–organic frameworks (MOFs) are a class of important porous materials with many current and potential applications. Their applications almost always involve the interaction between host framework and guest species. Therefore, understanding of host–guest interaction in MOF systems is fundamentally important. Solid-state NMR spectroscopy is an excellent technique for investigating host–guest interaction as it provides information complementary to that obtained from X-ray diffraction. In this work, using MOF α-Mg3(HCOO)6 as an example, we demonstrated that 13C chemical shift tensor of organic linker can be utilized to probe the host–guest interaction in MOFs. Obtaining 13C chemical shift tensor components (δ11, δ22, and δ33, where δ11 ≥ δ22 ≥ δ33) in this MOF is particularly challenging as there are six coordinatively equivalent but crystallographically non-equivalent carbons in the unit cell with very similar local coordination environment. Two-dimensional magic-angle-turning experiments were employed to measure the 13C chemical shift tensors of each individual crystallographically non-equivalent carbon in three microporous α-Mg3(HCOO)6 samples with different guest species. The results indicate that the δ22 component (with its direction approximately being co-planar with the formate anion and perpendicular to the C−H bond) is more sensitive to the adsorbate molecules inside the MOF channel due to the weak C−H···O hydrogen bonding or the ring current effect of benzene. The 13C isotropic chemical shift, on the other hand, seems much less sensitive to the subtle changes in the local environment around formate linker induced by adsorption. The approach described in this study may be used in future studies on host–guest interaction within MOFs. 相似文献
65.
A recent experiment [Angew. Chem. Int. Ed. 2017 , 56, 722–727] found that a (1 : 9) blend film of two anthracene derivatives, 2-fluorenyl-2-anthracene ( FlAnt ) and 2-anthryl-2-anthracence ( 2 A ), exhibit both efficient white light emission and high hole mobility, thus promising for organic light-emitting transistors (OLETs). Employing quantum chemistry at the polarizable continuum model (PCM) and the quantum mechanics/molecular mechanics (QM/MM) levels, we investigated the excited-state structures, optical spectra, band structure and the carrier mobility for FlAnt and 2 A from solution to aggregate phases. We suggest using the ratio of intermolecular excitonic coupling J and intramolecular excited state relaxation energy E to judge the bathochromic shift in optical emission in aggregates. For FlAnt , ρ=J/E is calculated to be less than 0.17, a critical value we identified earlier, and the spectra in solution and aggregate phases present quite similar features (blue emission). However, ρ is ∼0.5 for 2 A systems, and the calculated emission in the aggregate phase exhibits a remarkable bathochromic shift. In addition, the 0–0 emission is strongly suppressed in the herringbone stacking. These observations justify the experimental findings that (i) 2 A is blue emissive in solution but yellow-green in the aggregate phase, whereas FlAnt is always blue, and (ii) the blend of them show white emission. By using the “quantum nuclear tunneling” model we proposed earlier, we found the hole mobility for FlAnt and 2 A are 0.5 and 4.2 cm2 V−1 s−1, respectively, indicating both are good hole transport materials. 相似文献
66.
Weak signal detection has been widely used in many fields such as military and national economy. Aiming at the problem that the traditional stochastic resonance (SR) method can’t obtain the signal amplitude when detecting weak signals, the frequency and amplitude of the weak signal are obtained by combining the SR and chaos characteristics of the two-dimensional Duffing system. Firstly, the effects of two-dimensional Duffing system parameters a, b, k, noise intensity D on the Kramers rate and signal-to-noise ratio (SNR) are analyzed under the Gaussian white noise environment. The results show that the damping ratio K can hinder the SR effect of the system to some extent. Secondly, to solve the misjudgment of the state method of the weak signal amplitude in the detection, the Lyapunov exponent is used to assure the threshold's range, and the threshold of the chaotic critical state is found. Finally, the paper gives the processes of frequency and amplitude detection of multiple high-frequency signals, which realizes the effective detection of the frequency and amplitude of multiple high-frequency signals in a Gaussian white noise environment, and successfully applies the method to the accurate detection of boundary voltage amplitude in electrical impedance tomography. 相似文献
67.
层状稀土氢氧化物是一类新型的稀土功能材料,本文采用固体核磁共振(SSNMR)方法研究了同时具备离子交换能力和非线性光学特性的层状La(OH)2NO3化合物,探讨了通过四极核CPMG(QCPMG)脉冲序列和变频谱图采集获取超宽139La SSNMR谱图的方法,并描述了适用于此类实验的滤波方程和谱图重建方法.重建谱图同时包含四极核中心跃迁和卫星跃迁信息,本文使用QUEST软件对超宽139La NMR谱图进行了模拟,获取的四极耦合常数CQ和非对称因子ηQ均与CASTEP密度泛函理论计算值高度吻合.SSNMR实验结果证实层状La(OH)2NO3化合物属于非中心对称结构(P21),解决了对其结构长期以来存在的争论. 相似文献
68.
在无扰动、随机式扰动以及正弦式扰动下,通过对竖直恒温面处状态Ra为1.328×10^9、Pr为6.24的自然对流进行模拟,探索了热边界层的不稳定性和共振强化自然对流换热。结果表明:(1)竖直自然对流边界层上游位置的随机式扰动对热边界层的影响主要体现在稳定阶段;(2)该状态下的竖直自然对流边界层的特征频率为15 067,且相比于无扰动状态,频率为15 067的正弦式扰动能在竖直恒温面处提高5.15%的换热量;(3)在竖直自然对流边界层上游位置加入特征频率的正弦式扰动,竖直恒温面处的局部努塞尔数Nu均出现明显波动,且波动随着边界层高度的增加而增大。 相似文献
69.
为探索油-气-水三相流持气率测量难题,该文开展了脉冲透射式超声传感器持气率测量动态实验研究。首先,利用超声传感器与光纤传感器组合,测取了油-气-水三相流中段塞流、混状流、泡状流的响应信号;其次,提取了超声脉冲信号的最大值序列来反映不同流型时超声传感器响应特性,同时,借助双头光纤传感器与相关测速法,计算得到了流体中气泡弦长序列;最后,结合流型与泡径信息,利用超声传感器测量了不同流型下持气率,并分析了不同流型持气率预测的误差来源,为其他油-气-水三相流持气率测量传感器设计提供了借鉴。 相似文献
70.
Synthesis of Mesoporous Wall‐Structured TiO2 on Reduced Graphene Oxide Nanosheets with High Rate Performance for Lithium‐Ion Batteries 下载免费PDF全文
Mengmeng Zhen Meiqing Sun Prof. Guandao Gao Prof. Lu Liu Prof. Zhen Zhou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(14):5317-5322
Mesoporous wall‐structured TiO2 on reduced graphene oxide (RGO) nanosheets were successfully fabricated through a simple hydrothermal process without any surfactants and annealed at 400 °C for 2 h under argon. The obtained mesoporous structured TiO2–RGO composites had a high surface area (99 0307 m2 g?1) and exhibited excellent electrochemical cycling (a reversible capacity of 260 mAh g?1 at 1.2 C and 180 mAh g?1 at 5 C after 400 cycles), demonstrating it to be a promising method for the development of high‐performance Li‐ion batteries. 相似文献