首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   54117篇
  免费   4522篇
  国内免费   3887篇
化学   29667篇
晶体学   673篇
力学   2795篇
综合类   283篇
数学   11916篇
物理学   17192篇
  2023年   533篇
  2022年   676篇
  2021年   1009篇
  2020年   1199篇
  2019年   1111篇
  2018年   2116篇
  2017年   2350篇
  2016年   1997篇
  2015年   1899篇
  2014年   1988篇
  2013年   2704篇
  2012年   5467篇
  2011年   4644篇
  2010年   3517篇
  2009年   3227篇
  2008年   2452篇
  2007年   2225篇
  2006年   2085篇
  2005年   5691篇
  2004年   4844篇
  2003年   3050篇
  2002年   1214篇
  2001年   900篇
  2000年   597篇
  1999年   646篇
  1998年   471篇
  1997年   334篇
  1996年   321篇
  1995年   286篇
  1994年   249篇
  1993年   200篇
  1992年   314篇
  1991年   281篇
  1990年   265篇
  1989年   207篇
  1988年   177篇
  1987年   115篇
  1986年   98篇
  1985年   90篇
  1984年   68篇
  1983年   49篇
  1981年   39篇
  1979年   40篇
  1976年   90篇
  1975年   50篇
  1974年   43篇
  1973年   50篇
  1972年   44篇
  1970年   39篇
  1969年   42篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
We consider the one-dimensional steady-state semiconductor deviceequations modelling a pnpn device. There are two relevant scalingsof the equations corresponding to small and large applied voltages.In both scalings, the semiconductor equations can be consideredas singularly perturbed. It turns out that the small-voltagescaling breaks down for current values between two saturationcurrents. In that interval, the large-voltage scaling has tobe employed. For both scalings, we derive the first-order termsof an asymptotic expansion and show that the reduced problemhas a solution. An example verifies that the current-voltagecurves obtained have the expected qualitative structure.  相似文献   
63.
Suppose μ is a Radon measure on ℝ d , which may be non doubling. The only condition assumed on μ is a growth condition, namely, there is a constant C0>0 such that for all x∈supp(μ) and r>0, μ(B(x, r))⪯C0rn, where 0<n⪯d. We prove T1 theorem for non doubling measures with weak kernel conditions. Our approach yields new results for kernels satisfying weakened regularity conditions, while recovering previously known Tolsa’s results. We also prove T1 theorem for Besov spaces on nonhomogeneous spaces with weak kernel conditions given in [7].  相似文献   
64.
We present an interpolating, univariate subdivision scheme which preserves the discrete curvature and tangent direction at each step of subdivision. Since the polygon have a geometric information of some original (in some sense) curve as a discrete curvature, we can expect that the limit curve has the same curvature at each vertex as the control polygon. We estimate the curvature bound of odd vertices and give an error estimate for restoring a curve from sampled vertices on curves.  相似文献   
65.
在本文中,给定一组有序空间数据点列及每个数据点的切矢向量,利用加权二次有理Bézier曲线对数据点作插值曲线,使该曲线具有C1连续性,并且权因子只是对相应顶点曲线附近产生影响,同调整两个相邻的权因子可以调整这两个相邻顶点之间的曲线和它的控制多边形.  相似文献   
66.
This paper is devoted to a detailed theoretical study of an ion pair SN2 reaction LiNCO+CH3F in the gas phase and in solution at the level of MP2(full)/6-31+G**//HF/6-31+G**. Two possible reaction mechanisms, inversion and retention, are discussed. There are eight possible reaction pathways. The inversion mechanism is more favorable no matter in the gas phase or in solution based on analyses of the transition structures. Methyl isocyanate should form preferentially in the gas phase and more stable methyl cyanate is the main product in solution. The retardation of the reaction in solvents was attributed to the difference in solvation in the separated reactants and in the transition state.  相似文献   
67.
Comparing with the exact solutions of the model system of one and two particles coupled to an axial rotor, the quality of the semi classical tilted axis cranking approximation is investigated. Extensive comparisons of the energies and M1 and E2 transition probabilities are carried out for the lowest bands. Very good agreement is found, except near band crossings. Various recipes to take into account finite K within the frame of the usual principal axis cranking are included into the comparison. A set of rules is suggested that permits to construct the excited bands from the cranking configurations, avoiding spurious states.  相似文献   
68.
基于相对论平均场理论,研究了各种相互作用参数组(NL1、NL3、NLSH、TM1和GL-97)对中子星物质的性质和中子星整体结构的影响.发现参数组NL1、NL3和NLSH所给出的中子星内部的介子场强度、物质的组成比例、物态方程和中子星的整体特点基本相同,但与TM1和GL-97之间有较大的差别.相对于其他参数组,GL-97给出的介子场强度最弱,中子星的相对数密度最大,物态方程也最软,同时采用GL-97参数组计算的中子星的最大质量也最小.  相似文献   
69.
光纤光栅的温度补偿   总被引:17,自引:1,他引:16  
提出了一种简单、小型的光纤光栅温度补偿器件,将光纤光栅粘贴在具有负热膨胀系数的材料上,实现了光纤光栅的温度补偿。该器件在-20~44℃温度范围内光栅波长变化0.08m,是未补偿光纤光栅的1/8。  相似文献   
70.
We have synthesized a blue‐light‐emitting polyfluorene (PF) derivative ( PF‐CBZ‐OXD ) that presents bulky hole‐transporting carbazole and electron‐transporting oxadiazole pendent groups functionalized at the C‐9 positions of alternating fluorene units. The results from photoluminescence and electrochemical measurements indicate that both the side chains and the PF main chain retain their own electronic characteristics in the copolymer. An electroluminescent device incorporating this polymer as the emitting layer was turned on at 4.5 V; it exhibited a stable blue emission with a maximum external quantum efficiency of 1.1%. Moreover, we doped PF‐CBZ‐OXD and its analogue PF‐TPA‐OXD with a red‐light‐emitting iridium phosphor for use as components of phosphorescent red‐light emitters to investigate the effect of the host's HOMO energy level on the degree of charge trapping and on the electrophosphorescent efficiency. We found that spectral overlap and individual energy level matching between the host and guest were both crucial features affecting the performance of the electroluminescence devices. Atomic force microscopy measurements indicated that the dipolar nature of PF‐CBZ‐OXD , in contrast to the general nonpolarity of polydialkylfluorenes, provided a stabilizing environment that allowed homogeneous dispersion of the polar iridium triplet dopant. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2925–2937, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号