全文获取类型
收费全文 | 2342篇 |
免费 | 54篇 |
国内免费 | 8篇 |
专业分类
化学 | 1356篇 |
晶体学 | 10篇 |
力学 | 57篇 |
数学 | 324篇 |
物理学 | 657篇 |
出版年
2021年 | 28篇 |
2020年 | 30篇 |
2019年 | 35篇 |
2018年 | 15篇 |
2017年 | 25篇 |
2016年 | 48篇 |
2015年 | 31篇 |
2014年 | 47篇 |
2013年 | 107篇 |
2012年 | 104篇 |
2011年 | 122篇 |
2010年 | 61篇 |
2009年 | 44篇 |
2008年 | 92篇 |
2007年 | 101篇 |
2006年 | 89篇 |
2005年 | 112篇 |
2004年 | 75篇 |
2003年 | 78篇 |
2002年 | 62篇 |
2001年 | 62篇 |
2000年 | 56篇 |
1999年 | 34篇 |
1998年 | 23篇 |
1997年 | 38篇 |
1996年 | 28篇 |
1995年 | 47篇 |
1994年 | 41篇 |
1993年 | 43篇 |
1992年 | 41篇 |
1991年 | 32篇 |
1990年 | 35篇 |
1989年 | 20篇 |
1988年 | 22篇 |
1987年 | 21篇 |
1986年 | 17篇 |
1985年 | 33篇 |
1984年 | 26篇 |
1983年 | 17篇 |
1982年 | 26篇 |
1981年 | 33篇 |
1980年 | 21篇 |
1979年 | 34篇 |
1978年 | 28篇 |
1977年 | 31篇 |
1976年 | 34篇 |
1975年 | 29篇 |
1974年 | 26篇 |
1973年 | 37篇 |
1972年 | 26篇 |
排序方式: 共有2404条查询结果,搜索用时 46 毫秒
61.
Akiba Y Beavis D Beery P Britt HC Budick B Chasman C Chen Z Chi CY Chu YY Cianciolo V Cole BA Costales JB Crawford HJ Cumming JB Debbe R Engelage J Fung SY Gonin M Gushue S Hamagaki H Hansen O Hayano RS Hayashi S Homma S Kaneko H Kang J Kaufman S Kehoe WL Kurita K Ledoux RJ Levine MJ Miake Y Morrison DP Morse RJ Moskowitz B Nagamiya S Namboodiri MN Nayak TK Olness J Parsons CG Remsberg LP Roehrich D Rothschild P Sakurai H Sangster TC Seto R Soltz R Stankus P Steadman SG Stephans GS Sung T 《Physical review letters》1996,76(12):2021-2024
62.
63.
64.
65.
A high performance liquid chromatography (HPLC) method with fluorescence detection including an on-line purification was established for determination of catecholamines in human urine. The method was evaluated using samples of pooled urine spiked with catecholamines and validated for measurements of catecholamines in urine of healthy individuals in a field study. The laboratory method evaluation study showed that the recovery of the method was 0.82 (confidence interval (CI): 0.79-0.86) and 0.92 (CI: 0.89-0.95) for noradrenaline and adrenaline, respectively. Thus, correction factors of 0.82(-1) and 0.92(-1) were applied to correct the measurement results for this systematic effect. Furthermore, an uncertainty budget was generated for the analytical method using the BIPM-approach recommended by the International Organization for Standardization. The relative uncertainty of the method was estimated to be 10-12%, which was consistent with the observed relative variability found in the method evaluation. The method was evaluated in accordance with EURACHEM Guidance Document No 1 concerning accreditation for chemical laboratories with respect to accuracy and precision. The field study showed that the standard deviation of the method was sufficiently low to distinguish between persons working with two different processes of garbage collection, i.e. collection using four wheeled containers versus collection using bins. 相似文献
66.
Cahn's phenomenological theory of wetting of a solid substrate by a saturated vapor is generalized to the case where the substrate is charged and the wetting film contains counterions, with or without added salt. The electrostatic contribution to the grand potential associated with these ions is calculated within a nonlinear Poisson-Boltzmann theory. In the salt-free case, when the wetting film includes only counterions released by the substrate, the wetting transition is always first order, regardless of its nature in a neutral system. When salt is present, other wetting scenarios may arise, depending on the salt concentration and substrate surface charge. Over a restricted range of salt concentrations, a wetting scenario similar to that of prewetting, is predicted to occur along the liquid-vapor coexistence line. This scenario includes a discontinuous wetting transition between microscopic and mesoscopic film thicknesses, followed by a continuous divergence of the film thickness at higher temperatures. 相似文献
67.
68.
69.
H. E. Hansen R. Talja H. Rajainmäki H. K. Nielsen B. Nielsen R. M. Nieminen 《Applied Physics A: Materials Science & Processing》1985,36(2):81-92
Molybdenum single crystals are irradiated at 20 K with 6 MeV protons. The radiation damage and lattice defect annealing is studied by positron lifetime spectroscopy in the temperature range from 15 to 720 K. Loss of vacancies due to recombination with mobile interstitials is observed at 40 K (Stage I) in agreement with resistivity measurements. This is the first time Stage I is observed by positrons below 77 K. The implanted hydrogen decorates the vacancies around 100 K, which is consistent with a hydrogen migration energy in molybdenum:E
M
H
= 0.3–0.4 eV. Clustering of spatially correlated vacancies takes place in a wide temperature region below the usual vacancy clustering stage (Stage III). Stage III is observed at rather low temperatures (400–480 K) due to the very high vacancy concentration. Hydrogen bound to vacancies and vacancy clusters is released above 540 K, which puts an upper limit to the hydrogen binding energy:E
B
H
1.4 eV. The present work emphasizes the advantage of employing a vacancy sensitive technique to study hydrogen in metals, where its intrinsic solubility is low. In such metals (as molybdenum) both the effective solubility and the effective mobility of hydrogen are strongly influenced by the presence of vacancies. 相似文献
70.
The acid catalysed dienone-phenol rearrangement of methyl substituted o-propargyl-cyclohexadienones (scheme 3) was investigated. The rearrangements were carried out in acetic anhydride containing about 10/00 sulfuric acid. Under these conditions acetoxy benzenium ions are formed as intermediates. These then undergo charge-controlled [3s, 4s]- and [1s, 2s]-sigmatropic rearrangements. Thus, the [3s, 4s]-process leads to the formation of the corresponding allenyl-phenol acetates ( 19 , 21 , 23 , 25 , 28 , 30 ) whereas the [1s, 2s]-process yields propargyl-phenol acetates ( 20 , 22 , 24 , 26 , 29 ), respectively (cf. scheme 4). 相似文献