水泥粉煤灰加固有机质土的试验研究

对于高有机质含量的泻湖相软土,单纯采用水泥不能有效提高该软土的力学性能,因此提出了采用水泥和粉煤灰作为固化剂的加固方法。通过不同水泥掺入量、粉煤灰掺入量和龄期下水泥土的无侧限抗压强度试验,分析了水泥粉煤灰固化土的强度规律和变形规律,探讨了水泥和粉煤灰加固高有机质含量软土的机理。结果表明,粉煤灰对于水泥试块的早期强度影响较小,对后期强度影响较大;粉煤灰最佳掺入量为12％,超过此掺入量水泥土强度反而会降低,粉煤灰水泥土的破坏应变、E50也在粉煤灰掺量为12％时分别达到最低值和最大值。水泥掺加粉煤灰可有效地提高高有机质含量软土的强度。     

水泥熟料定量分析的全谱拟合法

对Rietveld全谱拟合定量分析应用程序进行了移和改编,使其能进行更大数据量的处理计算,并提供了一个更好的操作界面。在此基础上,对水泥熟料样品进行了物相定量分析,研究了影响全谱拟合定量分析结果准确性的各种因素。结果表明,用该法对水泥熟料矿物进行定量分析,具有常规X射线衍射定量分析方法无法比拟的优越性。     

基于近红外光谱检测技术的水泥生料成分含量检测研究

近红外光谱检测技术已经成功应用于水泥生料成分的快速检测,但我国水泥企业在生产水泥生料时所用原材料品种不一,使用不同的原材料进行生产时对近红外光谱建模带来一定影响.为了研究不同原料生产的水泥生料近红外光谱建模差异,对不同地区水泥生产线所生产的水泥生料进行建模研究.选取两个不同地区水泥生产线的水泥生料样本各95份和82份,...     

套管中模式波的响应特征*

在固井质量评价中主要利用套管中模式波的幅度或衰减变化反映水泥的胶结状况,不同测井仪器在套管中激发的模式波的类型不同,研究套管中各模式波的传播特征和影响因素可充分挖掘测量数据的潜在应用价值。CBL和SBT等测井仪器在套管中主要激发拉伸波,类同于平板中的零阶对称Lamb波,水泥环封隔测井仪器的斜入射模式在套管中主要激发套管弯曲波,类同于平板中的零阶反对称Lamb波,垂直入射模式激发套管共振波,类同于平板中的高阶对称Lamb波。该文重点分析了这些模式波的衰减特征及其对微环的响应,套管弯曲波在套后耦合轻质水泥时对微环不敏感,但在套后耦合常规水泥或重水泥时,其衰减明显高于胶结良好的状况;拉伸波对微环的存在最为敏感;套管共振波对微环不敏感。     

Deterioration of hardened cement paste under combined sulphate-chloride attack investigated by synchrotron XRD

The exact mechanisms of the phase transitions caused by a combined sulphate-chloride attack are discussed controversially. The main points concern the mutual influences of sulphate and chloride ions during the secondary binding processes of these anions within cement hydrate phases. We simulated combined sulphate-chloride attack under laboratory conditions using solutions containing NaCl and Na₂SO₄ in different concentrations. Three sample compositions were used for the preparation of the specimens. In two of them, 30% of Portland cement was replaced by supplementary cementitious materials (fly ash, slag).The phase distribution in the samples was determined using synchrotron X-ray diffraction. The analysis with high spatial resolution allows the localisation of the secondary phase formation in the microstructural profile of the sample. A mechanism of the phase developments under combined sulphate-chloride attack is derived.     

Résistance d'un milieu poreux à phase solide hétérogène

The strength of a porous medium, the solid phase of which is made up of composite spheres is determined in the framework of a micromechanical self-consistent reasoning. The strength of the spherical cores is infinite while the surrounding layers are made up of a von Mises material. Application of the modified secant method yields an analytical expression of the macroscopic strength. Such results can be used in order to predict the setting and strength criterion of a cement paste during hydration. To cite this article: J. Sanahuja, L. Dormieux, C. R. Mecanique 333 (2005).     

Development of an online X-ray fluorescence analysis system for heavy metals measurement in cement raw meal

ABSTRACT

Particulate matters, gaseous chemicals, and heavy metals emitted from industrial processes into the environment could be directly transmitted to humans through air inhalation. In order to accurately estimate health risk and control the source of pollution caused by cement raw meal, an online X-ray fluorescence analyzer system, consisting of an X-ray fluorescence analyzer with data acquisition software and a laser rangefinder, was developed to carry out the measurement of heavy metals in cement raw meal. The X-ray fluorescence analyzer was mounted on a sled, which can effectively smooth the surface of cement raw meal and reduce the impact of surface roughness during online measurement. The laser rangefinder was mounted over the sled for measuring the distance between cement raw meal sample and the analyzer. Several heavy metals and other elements in cement raw meal were online measured by the X-ray fluorescence analyzer directly above a conveyor belt. The limits of detection for Pb, Cr, Fe, Ti, Ca, and S by the analyzer were 47 ± 1, 33 ± 1, 37 ± 1, 44 ± 1, 246 ± 4, and 118 ± 1 mg kg^?1, respectively. The relative standard deviation (RSD) for the elements mentioned was less than 10.7%. By comparison with the results by inductively coupled plasma mass spectrometry (ICP-MS) and CHNS/O elemental analyzer, relative deviation (D) of the online X-ray fluorescence analyzer was less than 7.4% for Fe, Ti, Ca, and S, between 1.71% and 12.10% for Pb and Cr.     

Ultrasonic measurement of viscoelastic shear modulus development in hydrating cement paste

A test procedure for measuring changes in amplitude and phase of SH ultrasonic waves from the interface between fused-quartz and cement paste samples is presented. The phase change is determined from the temporal shift in the reflected signal relative to the incident signal. The sensitivity of the measured parameters to changes in acoustic impedance of the materials in contact with fused-quartz is evaluated for different angles of incidence. It is shown that a reflection measurement at normal incidence at nano-second temporal resolution does not provide sufficient sensitivity to measure the viscous component of shear modulus of low viscosity fluids and cannot be applied to cement paste while it is in a fluid state. Monitoring the measured amplitude and phase at oblique angle of incidence allows for measuring fluids with acoustic impedance comparable to cement paste. The reflection measurements are used to determine the evolution of elastic and viscous components of shear modulus cement paste with time. Influence of sampling rate and temperature effects on the phase measurements are evaluated and shown to be significant. It is shown that the initial loss of workability of cement paste through setting process is associated with a larger relative increase in the viscous component of shear modulus. Following the initial rapid rise of the viscous component of shear modulus, there is a larger relative increase in the elastic component, which can be related to the emergence of a solid structure capable of retaining an imprint.     

Influence of cement flow and aggregate type on the mechanical and acoustic characteristics of porous concrete

The influence of cement flow and aggregate type on the mechanical and acoustic characteristics of porous concrete is systematically investigated in the present study. Three levels of cement flow (80%, 110%, and 140%) and five types of aggregates (normal aggregates of 8-13 mm and 13-19 mm and lightweight aggregates of 4-8 mm, 8-12 mm, and 12-19 mm) are used, and effects of the application of AE admixtures in paste were also studied. Single-layered and double-layered porous concrete specimens are fabricated to examine the effect of different layer configuration on the acoustic characteristics. For the purpose of comparison, the void ratio, compressive strength, and sound absorption coefficient of the specimens are used as evaluation parameters. Based on the findings of the study, a sound absorbing porous concrete with a maximum absorption coefficient of approximately 1.00 is developed, and the minimum absorption coefficient of the ‘double-layered porous concrete’ structure is shown to be more than 0.60 with a frequency of 400 Hz or above, considering the tolerant error.