Synthesis of Dimethyl Carbonate from CO2 , Methanol, and Epoxides Using Re（CO） 5 Cl/K2 CO3 as Catalyst System

IntroductionOver the past few years, dimethyl carbonate(DMC) has been proven to be an efficientmethylating,methoxylating, and methoxycarbonylating agent inorganic syntheses, in which DMC is used to replace thetoxic methyl halides, dimethyl sulfate or carb     

新试剂二溴氟基偶氮氟胂分光光度法快速测定热镀锌合金中微量铈

报道了新试剂DBF-FAsA的合成及其应用于测定锌合金中添加微量元素铈量的方法。在强酸性体系中铈与二溴氟基偶氮氟砷(DBF-FAsA)形成蓝紫色配合物,其最大吸收波长为624nm,表观摩尔吸光系数ε为1.20×105L·mol-1·cm-1,线性范围为0～1.0μg/mL。该法可用于锌合金或中间锌合金材料中微量铈的测定。     

论微极弹性动力学的一类守恒律

本文用无穷小变换群使作用量不变的思想,直接导出线性微极弹性动力学的一类守恒律,对线性均匀微极弹性固体证明了在纯量变换下不可能有守恒律,对线性微极弹性动力学而言,可看出守恒律(4.7)式是新的和独特的。     

La1-xNdxSrCoO4催化剂的合成及其催化性能

采用聚丙烯胺溶胶-凝胶法制备了类钙钛矿La1-xNDxSrCoO4(x=0.1～0.9)复合氧化物催化剂,考察了其对CO和C3H8的催化氧化活性,并运用XRD、IR和TPR等手段对催化剂进行了表征.结果表明,所制备的样品均具有K2NiF4型结构,适量Nd2O3的加入增加了LaSrCoO4的催化活性,使LaSrCoO4催化剂粒度变小、晶格畸变率变大及与氧的结合能力减弱,从而有利于CO和C3H8氧化活性的提高.     

B物理中的难题

讨论单举B介子衰变中的难题, 包括直接CP非对称性及纵向极化分支比, 这些难题可能皆归因于量子色动力学的不准确度, 并非新物理的讯号.     

Analysis of X（1576） as a Tetraquark State with the QCD Sum Rules

We take the viewpoint that X（1576） is the tetraquark state which consists of a scalar diquark and an antiscalar-diquark in relative P-wave, and calculate its mass in the framework of the QCD sum rule approach. The numerical value of the mass mx= （1.66 =k 0.14） GeV is consistent with the experimental data. There might be some tetraquark components in the vector meson X（1576）.     

山奈黄素荧光分光光度测定痕量锗的新方法

锗与山奈黄素在H3PO4介质中发生配合反应, 形成配合比为2：1的配合物, 此配合物在乙醇溶液中具有很强的荧光强度, λex=438 nm, λem=478 nm. 用山奈黄素荧光分光光度法测定痕量锗, 检出限为0.15 μg/L, 线性范围为1.0～50 μg/L. 高、中、低3种浓度锗的相对标准偏差分别为 0.85%、 2.5%、 2.8%, 加标回收率为95.7%～103.9%.     

Effect of Nonradiative Recombination on Carrier Dynamics in GaInNAs/GaAs Quantum Wells

The nonradiative recombination effect on carrier dynamics in GalnNAs/GaAs quantum wells is studied by timeresolved photoluminescence （TRPL） and polarization-dependent TRPL at various excitation intensities. It is found that both recombination dynamics and spin relaxation dynamics strongly depend on the excitation intensity. Under moderate excitation intensities the PL decay curves exhibit unusual non-exponential behaviour. This result is well simulated by a rate equation involving both the radiative and non-radiative recombinations via the introduction of a new parameter of the effective concentration of nonradiative recombination centres in the rate equation. In the spin dynamics study, the spin relaxation also shows strong excitation power dependence. Under the high excitation power an increase of spin polarization degree with time is observed. This new finding provides a useful hint that the spin process can be controlled by excitation power in GaInNAs systems.     

稀土固体超强酸SO2-4/TiO2-La3+催化硝化甲苯的研究

研究了以固体超强酸SO2-4/TiO2-La3+作为催化剂,浓硝酸和甲苯为原料合成硝基甲苯,并考察了影响反应的因素.结果表明,催化剂用浓度为1.0 mol·L-1硫酸浸泡3小时,反应催化剂用量为硝酸质量的10%,反应时间为3小时,反应温度为55℃是最适宜的反应条件,甲苯转化率达90.14%,邻对比达0.89.     

催化动力学光度法测定痕量铝

痕量铝在硝酸介质中能催化加速过氧化氢和高碘酸钾与二甲苯胺兰FF之间的褪色反应。研究了反应的最佳实验条件,建立了测定痕量铝的新方法。方法检出限为6.1×10-10gAl3+/mL,检测范围为0-1.0μgAl3+/25mL。本方法具有高灵敏度,选择性较好,操作简便,快速的特点。用以测定水样中的痕量铝,获得满意结果。