全文获取类型
收费全文 | 2298篇 |
免费 | 39篇 |
国内免费 | 81篇 |
专业分类
化学 | 383篇 |
晶体学 | 7篇 |
力学 | 12篇 |
综合类 | 14篇 |
数学 | 1722篇 |
物理学 | 280篇 |
出版年
2024年 | 5篇 |
2023年 | 10篇 |
2022年 | 13篇 |
2021年 | 20篇 |
2020年 | 16篇 |
2019年 | 79篇 |
2018年 | 71篇 |
2017年 | 30篇 |
2016年 | 21篇 |
2015年 | 23篇 |
2014年 | 81篇 |
2013年 | 233篇 |
2012年 | 32篇 |
2011年 | 156篇 |
2010年 | 140篇 |
2009年 | 142篇 |
2008年 | 165篇 |
2007年 | 196篇 |
2006年 | 151篇 |
2005年 | 111篇 |
2004年 | 78篇 |
2003年 | 69篇 |
2002年 | 66篇 |
2001年 | 33篇 |
2000年 | 40篇 |
1999年 | 31篇 |
1998年 | 30篇 |
1997年 | 17篇 |
1996年 | 58篇 |
1995年 | 38篇 |
1994年 | 44篇 |
1993年 | 29篇 |
1992年 | 32篇 |
1991年 | 34篇 |
1990年 | 17篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 17篇 |
1986年 | 6篇 |
1985年 | 13篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有2418条查询结果,搜索用时 15 毫秒
51.
A new extraction method for ginsenosides from ginseng roots, ginseng leaves and ginseng drug preparations by Sep-Pak C18 cartridges has been studied. Ginsenoside extraction by Sep-Pak cartridges is a rapid, efficient, reproducible method. In addition, the extracts were analyzed by high performance thin layer chromatography (HPTLC) and reverse phase high performance liquid chromatography (HPLC). The major components of ginseng saponins were effectively separated using an ODS-120T column. 相似文献
52.
The microbiological transformation of 7-oxo-ent-kaur-16-ene by the fungus Gibberella fujikuroi gave fujenoic acid as the main compound, whilst the incubation of 18-hydroxy-7-oxo-ent-kaur-16-ene and 3α,18-dihydroxy-7-oxo-ent-kaur-16-ene afforded the corresponding 6β-hydroxy-derivatives. These facts indicate that the formation of fujenoic acid in this biotransformation should occur via a 7-oxo-6β-hydroxy derivative. In the three biotransformations, an 11β-hydroxylation was also produced, in low yield, indicating that a 7-oxo-group also directs hydroxylation at C-11. 相似文献
53.
16R-Bromopregnane-3S,20S-diol reacted with potassium t-butoxide to afford androst-16-en-3S-ol in a moderate yield via fragmentation reaction. The latter is a key intermediate for the synthesis of 5α-androst-16-en-3-one, as boar sex pheromone, and other steroidal drugs. In addition, 16R,20S-epoxypregnane-3S-ol was also obtained as a major product by changing the reaction solvent. 相似文献
54.
Instead of environmentally toxic chromium oxidant, singlet oxygen generated photcchemically was used as environmentally friendly and benign oxidizing agent to accomplish the transformation of pseudodiosgenin diacetate to diosone efficiently in a low toxic and less expensive solvent acetone. Accordingly 16-dehydropregnenolone acetate(16-DPA), an important intermediate for preparation of steroidal drugs, was prepared in good yield (75%) when photoreaction was run in acetone/acetic anhydride/pyridine system. The mild reaction condition as well as simple and environmentally friendly process made the method commercially viable and important for production of 16-DPA in industrial scale. 相似文献
55.
N. V. Kas’yan A. V. Shvets S. A. Sergienko V. G. Il’in 《Theoretical and Experimental Chemistry》2006,42(4):255-259
The zeolite IPC-3, isomorphous with germanate zeolite ASU-16, and its silicon, aluminum, and titanium analogs, were obtained
in the presence of 1,6-diaminohexane as a template. It is possible to incorporate selectively the elements in different crystallographic
positions, determined by the nature of the element, particularly its valency and its coordination number with respect to oxygen.
Silicon takes tetrahedral positions in the IPC-3 lattice, Al either tetrahedral or octahedral positions, and Ti octahedral
positions. Small amounts of the lithium cations facilitate tetrahedral coordination and increase the Al content in IPC-3.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 4, pp. 246–251, July–August, 2006. 相似文献
56.
Yuichi Michiue 《Journal of solid state chemistry》2006,179(8):2578-2583
Phase relations of rutile, freudenbergite, and hollandite structures were examined in the pseudobinary system NaCrO2-TiO2 (i.e., NaxCrxTi8−xO16) at 1350 °C. The hollandite structure was obtained in the composition range 1.7?x?2.0. The symmetry of the samples at room temperature was tetragonal for x=1.7 and 1.75, and monoclinic for x=1.8 and above. Single crystals of monoclinic hollandite Na2Cr2Ti6O16 were grown and the structure refinement has been carried out using an X-ray diffraction technique. The space group was I2/m and cell parameters were a=10.2385(11), b=2.9559(9), c=9.9097(11)Å, and β=90.545(9)° with Z=1. The Na ion distribution in the tunnel was markedly deformed from that in the tetragonal form. It was suggested that Cr/Ti ratios were different between the two framework metal sites. 相似文献
57.
2-{[1-(3,4-Dihydroxyphenyl)methylidene]amino}benzoic acid (DMABA) was loaded on Amberlite XAD-16 (AXAD-16) via azo linker and the resulting resin AXAD-16-DMABA explored for enrichment of Zn(II), Mn(II), Ni(II), Pb(II), Cd(II), Cu(II), Fe(III) and Co(II). The optimum pH values for extraction are 6.5-7.0, 5.0-6.0, 5.5-7.5, 5.0-6.5, 6.5-8.0, 5.5-7.0, 4.0-5.0 and 6.0-7.0, respectively. The sorption capacity was found between 97 and 515 μmol g−1 and the preconcentration factors from 100 to 450. Tolerance limits for foreign species are reported. The kinetics of sorption is fast as t1/2 is ≤5 min. The chelating resin can be reused for 50 cycles of sorption-desorption without any significant change (<1.5%) in the sorption capacity. The limit of detection values (blank +3 s) are 1.12, 1.38, 1.76, 0.67, 0.77, 2.52, 5.92 and 1.08 μg L−1 for Zn(II), Mn(II), Ni(II), Pb(II), Cd(II), Cu(II), Fe(III) and Co(II), respectively. The enrichment on AXAD-16-DMABA coupled with monitoring by flame atomic absorption spectrometry (FAAS) is used to determine all the metal ion ions in river and synthetic water samples, Co in vitamin tablets and Zn in milk samples. 相似文献
58.
IntroductionThepreparativeapproachofaneffectivebilTldslliccatalystisalwaysasubjectofboortantsignificanceinheterogeneouscatalysis.InourrecentstUdies,wefoundthatthebAnetallitcarbonylclustercoCo3(CO)12favorablygivesthebAnetalliccoCo3clusterontheSiOZsubdueaft… 相似文献
59.
A novel flow-injection system is proposed for the rapid measurement of the fish freshness indices K1 and K2: K1=[([HxR+[Hx])×100/([IMP]+[HxR]+[Hx])] and K2=[[Hx]×100/([HxR]+[Hx])], where [IMP], [HxR] and [Hx] are inosine-5′-monophosphate, inosine and hypoxanthine concentrations, respectively. For the estimation of index K1, 5′-nucleotidase immobilized reactor and nucleoside phosphorylase (NP)/xanthine oxidase (XO) coimmobilized reactor were incorporated in series in the flow-injection line made up by a 16-way switching valve with two sample loops. For the estimation of index K2, NP and XO immobilized reactors were also incorporated in the similar flow-line. Two sample portions passed through the flow-line with different residence times so that two peaks were obtained. The first and second peaks obtained in the K1-determining system corresponded to the total of HxR and Hx and the total of Hx, HxR and IMP, respectively. Similarly, the first and second peaks obtained in the K2-determining system corresponded to Hx and the total of Hx and HxR, respectively. Therefore, the indices K1 and K2 can be estimated by where i1 and i2 present the peak current of the first and second peaks, respectively, and f the ratio of the peak currents of the first and second peaks for a Hx standard solution. A sea bream was selected as a model fish and it was stored at 4 °C after death. A good correlation was found between the index K1 and the storage time over a period of 400 h, with a correlation coefficient of 0.992, but no correlation between the index K2 and the storage time. The measurements could be performed at a rate of 22 samples per hour with satisfactory precision (0.6–1.2% R.S.D.), without calibration for each species, accurate weighing of fish meat and any interferences in fish meat. 相似文献
60.