Ni2P-NiS双助剂促进g-C3N4光催化产氢动力学

本文通过简单的一步水热法得到Ni₂P-NiS双助催化剂,之后采用溶剂蒸发法将Ni₂P-NiS与g-C₃N₄纳米片结合构建获得无贵金属的Ni₂P-NiS/g-C₃N₄异质结。研究结果表明,优化后的复合材料具有良好的光催化产氢活性,其产氢速率最高可到6892.7 μmol·g^-1·h^-1,分别为g-C₃N₄ (150 μmol·g^-1·h^-1)、15%NiS/g-C₃N₄ (914.5 μmol·g^-1·h^-1)和15%Ni₂P/g-C₃N₄ (1565.9 μmol·g^-1·h^-1)的46.1、7.5和4.4倍。这主要归因于Ni₂P-NiS相比Ni₂P和NiS单体具有更好的载流子转移能力,其与g-C₃N₄形成的肖特基势垒能有效促进光生载流子在二者界面上的分离,同时Ni₂P-NiS能进一步降低析氢过电势,进而显著增强了表面析氢反应动力学。本研究为开发稳定、高效的非贵金属产氢助剂提供了实验基础。     

A SINGULAR VALUE DECOMPOSITION BASED TRUNCATION ALGORITHM IN SOLVING THE STRUCTURAL DAMAGE EQUATIONS

The structural damage identification through modal data often leads to solving a set of linear equations. Special numerical treatment is sometimes required for an accurate and stable solution owing to the ill conditioning of the equations. Based on the singular value decomposition (SVD) of the coefficient matrix, an error based truncation algorithm is proposed in this paper. By rejection of selected small singular values, the influence of noise can be reduced. A simply-supported beam is used as a simulation example to compare the results to other methods.Illustrative numerical examples demonstrate the good efficiency and stability of the algorithm in the nondestructive identification of structural damage through modal data.     

CARBON NANOTUBES VIA METHANE DECOMPOSITION ON AN ALUMINA SUPPORTED COBALT AEROGEL CATALYST

An alumina-supported cobalt aerogel catalyst prepared from a sol-gel and a supercritical drying method was used in the catalytic decomposition of methane.The physical-chemical properties of the catalyst were characterized and its activity for methane decomposition was investigated.The effects of calcination and reaction temperatures on the activity of the catalyst and the morphology of the carbon nanotubes produced were discussed.A COAl2O4 spinel structure formed in the calcined catalyst.The quantity of the nanotubes produced in the reaction increases with the amount of cobalt in the reduced catalyst.A higher reaction temperature leads to a higher reaction rate,though faster deactivation of the catalyst occurs with the change.The carbon nanotubes grown on the catalyst have smooth walls and uniform diameter distribution.     

部分输入未知条件下结构动力复合反演的分解算法

在充分利用部分输入已确知而部分输入未知的激励特性的基础上，提出了结构动力复合反演的分解算法，该算法从源头上消除了迭代过程中参数识别与荷载反演的相互影响，降低了问题的计算规模。对于线性参数系统，该算法不经过任何迭代计算即可一次性完成结构参数识别及荷载反演。将其与松弛法结合，可解决非线性参数系统的识别问题，与文献[4]的方法比较，其收敛速度有显著提高。     

EMD-RLS联合滤波算法及其在北斗多路径削弱误差中的应用

多路径误差是全球导航卫星系统高精度定位的主要误差源。针对北斗导航定位系统的多路径特性,结合经验模态分解(EMD)和递归最小二乘算法(RLS)算法的优势,提出了一种EMD-RLS联合滤波算法来削弱北斗多路径特性的影响。首先,利用EMD将原始信号分解成固有模态函数(IMF),利用两个指标将其细化成三类,即噪声IMFs、混合IMFs和信息IMFs;然后,利用RLS算法对混合IMFs进行滤波,将经RLS滤波后得到的"干净"的数据与信息IMFs进行重构,最终达到去噪结果,即得到北斗多路径误差改正模型。仿真数据和北斗实测数据的处理结果表明:EMD-RLS算法相对于EMD和RLS算法,降噪效果更好;其建立的多路径误差改正模型有效地削弱多路径效应的影响,N、E、U三个方向精度分别提高了39%、70%、58%。     

有限变形梯度“和分解”的存在性与客观性

本文使用张量的不变表示,对有限变形梯度“和分解”的存在性、唯一性和客观性进行了讨论.对该分解的存在条件给出了严谨的证明;指出在几何大变形条件下这种分解是有条件的,对观察者有强烈的依赖性,因而是不客观的.这说明,如何使用这一分解还有待进一步的研究.     

HIGH PERFORMANCE SPARSE SOLVER FOR UNSYMMETRICAL LINEAR EQUATIONS WITH OUT-OF-CORE STRATEGIES AND ITS APPLICATION ON MESHLESS METHODS

A new direct method for solving unsymmetrical sparse linear systems(USLS) arising from meshless methods was introduced. Computation of certain meshless methods such as meshless local Petrov-Galerkin (MLPG) method need to solve large USLS. The proposed solution method for unsymmetrical case performs factorization processes symmetrically on the upper and lower triangular portion of matrix, which differs from previous work based on general unsymmetrical process, and attains higher performance. It is shown that the solution algorithm for USLS can be simply derived from the existing approaches for the symmetrical case. The new matrix factorization algorithm in our method can be implemented easily by modifying a standard JKI symmetrical matrix factorization code. Multi-blocked out-of-core strategies were also developed to expand the solution scale. The approach convincingly increases the speed of the solution process, which is demonstrated with the numerical tests.     

本征正交分解技术在屋盖风压场重建与预测中的应用

给出利用本征正交分解(POD)对屋盖风压场进行重建和预测的研究结果.对一个双坡屋盖用同步多点压力扫描系统进行了风洞试验,根据POD技术采用前若干阶本征模态重建屋盖风压场.采用两种方案预测未布置测压点位置的风压时间序列.第一种方案中利用插值技术获得没有测压点位置的本征模态值.第二种方案对参考屋盖和需预测的新屋盖分别进行试验,结合由参考屋盖试验萃取的本征模态和由新屋盖试验的风压数据计算的主坐标,预测出新屋盖未知区域的风压时间序列.文中对风压场重建和预测的效果作了分析,而且比较了根据测量的风压数据和预测的风压数据所计算的屋盖风致响应.     

复合随机振动分析的扩阶系统方法

提出了随机结构系统反应的子空间次序正交分解的思想．基于这一思想，文中导出了一类用于考虑随机激励的随机结构复合随机振动分析的扩阶系统方法，从而可以应用传统的确定性结构随机振动各种分析方法求解复合随机振动问题．作为特例，本文给出了使用模态分析法求解的过程．将文中算例与随机模拟结果相比较，证实了本文思想与方法的实用性．     

地震检波器的参数受温度影响的研究

研究温度对动圈式地震检波器的参数的影响．在对精密测量的地震检波器的参数进行数据分析的基础上，揭示了地震检波器输出电阻、自然频率、阻尼和灵敏度等4个参数的温度响应，分析讨论了有关参数对温度的变化规律．提出了控制这种变化的对策，初步实验结果证实了其可行性．最后，指出地震检波器参数的变化是可控的，同时认为如无原理上的重大改进，高精度的超级检波器最可能实现在10-20Hz频率范围中．