Energy dependence of the 6Li + 16O elastic scattering versus that of 7Li + 16O

The European Physical Journal A - Existing data for the 6Li + 16O elastic scattering at $ E_{c.m.}=3.27$ -36.8MeV were analyzed within the optical model and coupled-reaction-channels method. The...     

A Galois-Theoretic Approach to the Covering Theory of Quandles

The purpose of this article is to clarify the relationship between the algebraic notion of quandle covering introduced by M. Eisermann and the categorical notion of covering arising from Galois theory. A crucial role is played by the adjunction between the variety of quandles and its subvariety of trivial quandles.     

Sono and electrochemical synthesis and characterization of copper core–silver shell nanoparticles

Cu–Ag core–shell nanopowders have been prepared by ultrasound-assisted electrochemistry followed by a displacement reaction. The composition of the particles has been determined by X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). The XRD patterns versus time displacement show that higher are the silver peaks intensities, weaker are the copper ones. That exhibits the progressive recovering of copper by silver. EDX results and quartz crystal microbalance results indicate that various reaction mechanisms are implied in this process. Transmission electron microscopy (TEM) points out variable nanometric diameter grain and some small agglomerates. Elemental mapping obtained by electron energy-loss spectroscopy (EELS) underlines the core–shell structure.     

A survey of dual-feasible and superadditive functions

Dual-feasible functions are valuable tools that can be used to compute both lower bounds for different combinatorial problems and valid inequalities for integer programs. Several families of functions have been used in the literature. Some of them were defined explicitly, and others not. One of the main objectives of this paper is to survey these functions, and to state results concerning their quality. We clearly identify dominant subsets of functions, i.e. those which may lead to better bounds or stronger cuts. We also describe different frameworks that can be used to create dual-feasible functions. With these frameworks, one can get a dominant function based on other ones. Two new families of dual-feasible functions obtained by applying these methods are proposed in this paper.     

Study of Electrical Conductivity of Para-Toluene Sulfonic Acid Doped Polyaniline/Polyester-Based Polyurethane Blends in the S-Band Frequency Range

Conducting polymer blends were prepared using polyaniline doped with para- toluene sulfonic acid (PTSA-PANI) and a polyester polyol-based polyurethane (PU). The morphological, thermal and dielectric properties of the PTSA-PANI/PU blends in the frequency range of 1–5 GHz (S band) were investigated. It was found that the morphology of the samples was affected by the PTSA-PANI loading, resulting in the formation of agglomerates and pathways when above 10 wt%. The thermal stability of the composites was improved with increased PTSA-PANI loading. The electrical conductivity percolation threshold was obtained at 2.5% of PTSA-PANI loading and the electrical conductivity reached the value of 0.13 S/m at a PTSA-PANI loading of 30 wt%. The obtained results for the PTSA-PANI/PU blends prepared indicate a high potential for their successful use in electrical and electromagnetic applications.     

Synthesis and Structural Assignment of 1-O-Acetyl-2,3,5-tri-O-benzoyl-4-(thymin-1-yl)-α-l-lyxofuranose

Abstract

Analogues of nucleosides in which the nucleobase is fixed onto the C-4 of the sugar moiety are generally prepared either from 4,5-unsaturated sugar derivatives or via a formaldehyde condensation.¹ We tested the furanosyl bromide reactivity of 1 ² towards a series of nucleophiles, mostly azides or cyanides, without success. Conversely, the nucleosidation of 1 using 5-methyl-2,4-bis(trimethyl-silyloxy)pyrimidine in the presence of stannic chloride took place at the second anomeric position (C-4) and led to the isolation in acceptable yield (47%) of a unique anomer 2 (Scheme 1).     

Development of SPME on-fiber derivatization for the sampling of formaldehyde and other carbonyl compounds in indoor air

Solid-phase microextraction on-fiber derivatization applied to carbonyl compounds is known, but application to indoor air is poorly developed and the methods deserve to be complemented and optimized. In this work, two derivatization reagents, pentafluorophenylhydrazine and o-2,3,4,5,6-(pentaflurobenzyl)hydroxylamine (PFBHA), and three fiber coatings were tested in order to select the best combination. As Carboxen-based coatings were proven to induce the formation of by-products during the thermal desorption step, a polydimethylsiloxane–divinylbenzene fiber in association with PFBHA was finally chosen. The study of the derivatization kinetics showed that the reaction of PFBHA with carbonyl compounds was instantaneous, except for acetone. Analyses were performed by gas chromatography coupled with flame ionization detection and mass spectrometry. For 5 min fiber exposure, the limits of detection are below 0.5 μg m^-3 in selected ion monitoring mode, the reproducibility was 15 % on average, and the linearity of the calibration curves was satisfactory. For on-site application, the influence of air humidity and the conditions in which the impregnated fibers were stored were studied. It is possible to store the fibers for 3 days before and for at least 2 days after sampling. The relative humidity of air was shown to have no influence on solid-phase microextraction sampling in the range from 0 to 70 %. For formaldehyde, the method was compared with sampling on 2,4-dinitrophenylhydrazine cartridges, and the first results showed good agreement. Finally, the method was applied to three different indoor environments to check its feasibility.     

Characterization of oligosorbents and application to the purification of ochratoxin A from wheat extracts

The aim of this work was to optimize the preparation of an anti-ochratoxin A (OTA) oligosorbent (OS), a solid-phase extraction sorbent based on OTA aptamers covalently immobilized on sepharose. Different syntheses were carried out by modifying the side of the oligonucleotide chain bound to the sepharose, the length of the spacer arm between the aptamer and the sepharose and the amount of the aptamers introduced during the covalent grafting. Indeed, the capacity of OSs prepared using 3′- or 5′-amino-modified sequences with a C6 or a C12 was studied. In the best conditions, the concentration of aptamers sequence used during their grafting was increased and a capacity close to 40 nmol g^?1 of OS was reached. The potential of the resulting OSs was also studied in pure media. For this, their selectivity was checked by comparing them to a control sorbent prepared without immobilizing aptamers. Extraction recoveries close to 100 % were obtained on all OSs, while no retention was observed on the control sorbent. OS does not demonstrate any cross-reactivity towards OTA metabolites, i.e., ochratoxin B and ochratoxin hydroquinone. The oligosorbent was finally applied to the clean-up of OTA from wheat sample extracts. Extraction recoveries were not affected by matrix interferences and the resulting chromatogram clearly highlights the selectivity of the sorbent that allows the removal of matrix components thus improving the reliability of the quantitation of OTA in real samples.     

Effective temperature scattering matrix and kinematic mechanism of cooper instability in antiferromagnetic rare-earth intermetallides

An effective temperature-dependent scattering matrix for a localized subsystem is obtained in the periodic Anderson model by summing itinerant variables in the diagrammatic series of perturbation theory. The effective interaction that occurs in this case can lead to an antiferromagnetic phase, a superconducting phase, and the phase of coexisting superconductivity and antiferromagnetism observed in heavy-fermion intermetallic compounds.