双边二次电子倍增效应分析

 根据高功率微波源相互作用腔结构,建立了一种双边二次电子倍增效应模型。采用概率统计和蒙特卡罗模拟方法,计算了敏感曲线和二次电子的时间演化规律,分析了射频场参数和结构参数对二次电子倍增效应的影响。结果表明：高频场比低频场更容易发生二次电子倍增效应;二次电子倍增效应的时间演化与射频场的大小和腔结构呈非单调关系,且电子掠入射时比正入射时的共振区域要大得多,这与理论分析的结果一致。     

铁基合金激光熔覆层的高温磨损性能

 为提高40Cr钢表面耐磨性,采用预置激光熔覆法在40Cr基体表面制备Fe基涂层,利用HT-500摩擦磨损实验机测定干摩擦条件下,基体和熔覆层的摩擦因数随温度变化的规律。利用表面粗糙度轮廓仪测量磨痕的深度和宽度,SEM观察熔覆层以及磨痕的显微组织形貌,使用HV-1000型显微硬度仪检测基体和熔覆层结合部分的硬度。研究结果表明:熔覆层平均显微硬度值达到373.8HV(0.2);显著高于基体硬度198.4HV(0.2)。在干摩擦条件下,随着温度升高,磨损过程逐渐变平缓,平均摩擦因数降低,磨损率增加,耐磨性下降;在350~400 ℃之间,熔覆层磨损性能优于基体。     

高功率全固态紫外四倍频激光器

 通过对谐振腔腔镜失调灵敏度的计算,分析了声光调Q开关位置对调Q脉冲输出稳定性的影响。计算表明:Q开关放置在输出镜一侧会使脉冲序列更加稳定。在基模输出的条件下,获得了峰值功率为几十kW的调Q脉冲输出。采用BBO晶体对Nd:YAG激光器四倍频,获得了1.9 W的266 nm紫外激光输出。     

Simplified method and synchronization for a class of complex chaotic systems

This paper is devoted to investigate a class of complex chaotic systems and a linear correlation between the real and imaginary component of complex variables in these systems is found. Based on this linear relationship, a simplified law is proposed. First, complex Lorenz system is given to show the linear correlation, then it is simplified. Second, a simplified law is proposed to determine whether the complex system can be simplified, and the complex Lü system and hyperchaotic complex Lü system are used to verify the simplified law. Finally, a new synchronization control is proposed to synchronize complex Lorenz system and real Lorenz system. The theoretical analysis and numerical simulation prove the feasibility and better performance of this method.     

Laser micro-processing of cardiovascular stent with fiber laser cutting system

A metallic cardiovascular stent cutting system based on fiber laser was designed in this study. In order to achieve the cutting of stent, the main modules and the key technologies were analyzed and achieved. Then with the cutting system, the kerf width size was studied for different cutting parameters including laser output power, pulse length, repeat frequency, cutting speed and assisting gas pressure. Finally, a high quality of cutting of 316L stainless steel cardiovascular stent was achieved.     

A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3+

A Tb³⁺ based coordination polymer (NKU-115) with free N sites was successfully constructed, featuring strong green light emission and selective quenching response toward Fe³⁺ in aqueous solution.     

Superhydrophilic Phytic‐Acid‐Doped Conductive Hydrogels as Metal‐Free and Binder‐Free Electrocatalysts for Efficient Water Oxidation

Recently, metal‐free, heteroatom‐doped carbon nanomaterials have emerged as promising electrocatalysts for the oxygen evolution reaction (OER), but their synthesis is a tedious process involving energy‐wasting calcination. Molecular electrocatalysts offer attractive catalysts for the OER. Here, phytic acid (PA) was selected to investigate the OER activity of carbons in organic molecules by DFT calculations and experiments. Positively charged carbons on PA were very active towards the OER. The PA molecules were fixed into a porous, conductive hydrogel with a superhydrophilic surface. This outperformed most metal‐free electrocatalysts. Besides the active sites on PA, the high OER activity was also related to the porous and conductive networks on the hydrogel, which allowed fast charge and mass transport during the OER. Therefore, this work provides a metal‐free, organic‐molecule‐based electrocatalyst to replace carbon nanomaterials for efficient OER.     

Stability and elastic properties of B2 CoX (X = Ti,Zr and Hf) intermetallic compounds as a function of pressure

By means of first-principles calculations within the generalised gradient approximation (GGA), phase stability, elastic properties and electronic structures of B2 CoX (X = Ti, Zr and Hf) compounds as a function of pressure have been investigated. The formation energy indicates that CoTi is the most stable phase in these three B2 phases under different pressures. The elastic properties of B2 Co (X = Ti, Zr and Hf), calculated via the Voigt–Reuss–Hill (VRH) approximation, increase with increasing pressure. The mechanical anisotropies are characterised by the universal anisotropy index (A^U) and the Zener anisotropy index (A^Z). The sound velocities, Debye temperatures and melting temperature under applied pressure are also evaluated. Electronic structure show that the changes in the charge distribution are moderate under applied pressure, resulting in the general characteristics of the bonding between X (X = Ti, Zr and Hf) and Co remain unchanged.     

Two-Scale Picard Stabilized Finite Volume Method for the Incompressible Flow

In this paper, we consider a two-scale stabilized finite volume method for the two-dimensional stationary incompressible flow approximated by the lowest equal-order element pair $P_1-P_1$ which does not satisfy the inf-sup condition. The two-scale method consists of solving a small non-linear system on the coarse mesh and then solving a linear Stokes equations on the fine mesh. Convergence of the optimal order in the $H^1$-norm for velocity and the $L^2$-norm for pressure is obtained. The error analysis shows there is the same convergence rate between the two-scale stabilized finite volume solution and the usual stabilized finite volume solution on a fine mesh with relation $h =\mathcal{O}(H^2)$. Numerical experiments completely confirm theoretic results. Therefore, this method presented in this paper is of practical importance in scientific computation.     

高效液相色谱-离子阱质谱法测定尿液中β2-受体激动剂及β-受体阻断剂

建立了尿液中23种β2-受体激动剂及5种β-受体阻断剂的高效液相色谱-离子阱质谱(HPLC-IT-MS)测定方法。尿液样品采用冷冻高速离心沉淀蛋白,上清液过ExtrelutTM硅藻土柱,用乙酸乙酯洗脱后,洗脱液经旋转蒸发仪浓缩并复溶待测。HPLC分离采用AtlantisT3-150 mm色谱柱,以甲醇和含0.1%甲酸的水溶液为流动相梯度洗脱,IT-MS采用电喷雾离子源在多反应离子监测模式下测定。定量分析选择9种经过氘代同位素标记的β2-受体激动剂为内标。各化合物的线性范围为0.005～0.16 mg/L,尿液中的检出限均能达到0.2 μg/L。空白尿液样品中不同加标水平的回收率为57.1%～127.1%,相对标准偏差为1.1%～31.1%。该方法简便快速,灵敏度高,适用于人或动物尿液中23种β2-受体激动剂及5种β-受体阻断剂的定性和定量分析。