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作报道了用X射衍射法对Bi2Sr2-yMyCuO6+δ(M=LaPr0.0<y<1.0)系列单晶样品进行结构的研究,根据晶体结构的不同性质,我们将掺杂区分为三个区域,第一个区域的掺镧量在0.0<y<0.10之间,在此区域中晶体的平均结构为单斜结构,其调制波矢具有两个非公度分量q=βb+γc,第二个掺杂区的掺镧量在0.10<y<0.60之间,晶体的平均结构由单斜转变为正交结构,调制波矢具有单个非公 相似文献
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An epitaxial ZnO thin film was entirely fabricated by pulsed laser deposition. Both the orientation and the size of the crystallites were studied. The X-ray diffraction (XRD) patterns of the film show strong c-axis oriented crystal structure with preferred (002) orientation. The Phi-scan XRD pattern confirms that the epitaxial ZnO exhibits a single-domain wurtzite structure with hexagonal symmetry. In situ high-temperature XRD studies of ZnO thin film show that the crystallite size increases with increasing temperature, and (002) peaks shift systematically toward lower 2θ values due to the change of lattice parameters. The lattice parameters show linear increase in their values with increasing temperature. 相似文献
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Controllable syntheses of different-sized gold nanoclusters are of great significance for their fundamental science and practical applications.In this work,we achieve the controllable and selective syntheses of Au7 and Au13 clusters through adding HCl to the traditional Au11 synthetic route at different reaction time.Time-dependent mass spectra and UVVis spectra were employed to monitor these two HCl-directed processes,and revealed the distinct roles of HCl as an etchant or a growth promotor,respectively.Furthermore,parallel experiments on independent synthetic routes involving only non-chlorine H+(acetic acid) or Cl-(tetraethy lammonium chloride) instead of HCl were performed,which illustrated the main role of H+-etching and Cl--assisted growth in HCl-directed cluster synthetic routes.We propose the HCl-etching is mainly achieved via the H+ action to break the Au (I)-PPh3 part of clusters,while the HCl-promoted growth is realized via the attachment of Au-Cl species to the pre-formed clusters. 相似文献