Investigation of third-order nonlinear optical properties of two azo-nickel chelate compounds

This paper investigates the third-order nonlinear optical properties of two azo-nickel chelate compounds by the optical Kerr gate method at 830 nm wavelength with pulse duration of 120 fs. Both of the two compounds exhibited large third-order optical nonlinearity. The second-order hyperpolarizability,γ, of Compound 1 is of 1.0 × 10^-31 esu. Due to the charge transfer, the γ of Compound 2 with electron donor and acceptor group is 4.9 × 10^-31 esu, which is a four-time enhancement in comparison with Compound i. The absorption spectra show that the electron push-pull effect, which induces intramolecular charge transfer, leads to the increased optical nonlinearity.     

湍流火焰自相似临界微尺度分析

自相似临界尺度表征了湍流火焰内保持自相似特性的最大尺度，是确定湍流各相同性的特征尺度．本文利用光学显微技术和计算机图像处理技术，提取并分析了湍流火焰微尺度结构的曲线度和线性回归均方差在不同放大倍率下的变化规律，提出了利用相似度偏差和临界放大倍率来确定自相似临界尺度的思路，并借助于Ｋｏｌｍｏｇｏｒｏｖ微尺度η的定义，推导出临界尺度η＇的数学关联式．     

钛蓝宝石飞秒超快光谱技术及其应用进展

介绍飞秒激光技术的进展、钛宝石飞秒激光放大技术及飞秒分辨相关测量技术.并介绍了飞秒分辨光荧光上转换和光克尔实验技术及其在各种学科中的应用. 关键词： 飞秒激光 飞秒光谱 光克尔 光荧光     

光纤布喇格光栅低温传感的特性研究

从光纤布喇格光栅的温度传感模式出发,对光纤布喇格光栅的温度传感特性进行了分析,推导出了光纤光栅的一阶与二阶温度灵敏度系数,并运用MATLAB对实验数据进行了拟和,所得多项式和理论值吻合得很好.并对低温传感进行了实验,将在常温下得出的多项式进行了热光系数的修正,所得的结果同时符合常温与低温的传感特性,解决了低温与常温情况下的理论计算与实验的不一致性.     

阴极Pt负载量和背压对PEMFC性能的协同影响规律

结合静态模型计算和实验测试,从活化过电势、欧姆损失和浓差过电势三个方面量化分析了阴极Pt负载量和背压协同对质子膜燃料电池(PEMFC)性能的影响规律。考察了阴极Pt负载量为0.1、0.2、0.4mg·cm－2,背压为100、150、200kPa条件下的燃料电池性能。通过比较发现,在上述条件任意组合下,随着电流密度增加,活化过电势、欧姆损失和浓差过电势逐渐加大,直接影响燃料电池性能;但在相同背压条件下,随着电流密度增加,低Pt负载量时的浓差过电势比高Pt负载量时增加得更快;同时发现,背压增加对提高燃料电池的性能有帮助,但背压增加对低Pt负载量比对高Pt负载量效果更明显。因此对于低Pt燃料电池,应适当提高运行背压以优化其性能。本文对上述实验结果的产生机理进行了探讨,并期望该结果能对低Pt/超低Pt燃料电池的设计及性能优化提供参考与借鉴。     

DYNAMICS OF IONIZATION-ENHANCED SPECTRAL EXPANSION IN WATER INDUCED BY AN INTENSE FEMTOSECOND LASER BEAM

The dynamic process of white-continuum generation in water was investigated by the pump－probe technique with a femtosecond intense laser at 805nm. The spectrum width of the probe beam was broadened at the blue side and varied with different delay times. This blueshift was attributed to the ionization-enhanced optical nonlinearity, in which both the multi-photon ionization and avalanche ionization had an effect.