N-羟基邻苯二甲酰亚胺与8-羟基喹啉氧钒(Ⅳ)配合物协同催化分子氧氧化乙苯

研究了钒化合物对N-羟基邻苯二甲酰亚胺(NHPI)催化分子氧氧化乙苯反应中的调变效应.结果表明,由8-羟基喹啉及其衍生物与乙酰丙酮氧钒(Ⅳ)配位制得的8-羟基喹啉氧钒(Ⅳ)配合物的催化活性比乙酰丙酮氧钒(Ⅳ),NH4VO3和V2O5的高.在优化的反应条件下,乙苯转化率和苯乙酮选择性可分别达60％～69％和97％.基于液...     

关于圆形薄板的轴对称非线性弯曲问题

本文应用多重尺度法讨论了圆形薄板的轴对称非线性弯曲问题。导出了解的N阶递推方程,并具体求得一阶渐近解并与实验曲线作了比较,从而看到用多重尺度法所得到的解与实验结果吻合较好。     

一类非方系统的Morgan问题 *

讨论一类特殊情形的非方系统的Morgan问题,得到了问题有解的充分必要条件,给出了这一类系统判断其Morgan问题是否有解的算法.     

线性奇异摄动系统的降维观测器

对于带有慢变与快变模型的线性奇异摄动系统,J. O'Reilly讨论并给出了它的全阶观测器,该观测器的增益矩阵由相应的慢、快变子系统的全阶观测器的增益阵确定。 为了降低这一类补偿器的阶数,我们利用Luenberger的降维观测器理论,来构造奇     

核工业人爱国奉献的楷模——纪念王淦昌同志诞辰100周年

我国核工业是在党中央几代领导集体的亲切关怀和正确领导下创建发展起来的．五十多年的奋斗历程所取得的辉煌成就，源于全国人民和各行各业的大力支持，源于几十万核工业人的顽强拼搏和无私奉献．老一辈科学家和广大核科技工作者为发展我国核事业作出了巨大贡献，王淦昌同志就是他们当中最杰出的代表之一．     

Effects of Different Dispersion Methods on the Microscopical Morphology of TiO2 Film

Nanocrystalline porous TiO2 films were prepared on conducting glass supports （ITO） by processed commercial TiO2 nanometre powder （P25）. Three methods of physical dispersing for TiO2 powder, i.e. grinding, magnetic stirring, sonicleaning, were used to disperse TiO2 nanometre powder. Surface morphologies of TiO2 films were observed by optic-microscope and SEM. It is found that the surface morphologies of TiO2 films are determined not only by the dispersing methods but also by the percentage of TiO2 powder in the dispersing system. Different film morphologies can be obtained under the same preparation condition but with different dispersing methods. A lot of cracks exist on the film surface for which the TiO2 slurry is dispersed by grinding. Magnetic stirring leads to some white points and micro-holes on the film surface. Only a few of micro-holes can be observed on the film surface, in which the TiO2 slurry is dispersed by sonicleaning. Different surface morphologies can also be found with different thicknesses of TiO2 films. Different film thicknesses are due to different percentages of TiO2 powder in the slurry. The related mechanism leading to different features of the surface morphologies for the TiO2 films is discussed.     

准相位匹配PPKTP晶体连续倍频13 mW绿光输出

采用高压脉冲电场极化,通过电光效应实时监控、倍频通光二维监控等手段的应用,制备出周期为9μm、长为8 mm、宽为3 mm、厚为1 mm的周期极化KTiOPO4晶体(PPKTP);倍频通光实验中,当波长1064 nm的基频光功率为1 W时,得到了功率为13.5 mW的532 nm连续倍频绿光输出,单通倍频转换效率为1.35%,归一化转换效率为1.69%/(W.cm),接近理论最大值。     

Efficiency Enhancement of Dye-Sensitized Solar Cells： Using Salt CuI as an Additive in an Ionic Liquid

Energy conversion efficiency of the dye-sensitized solar cell is improved from 3.5% to 4.5% by adding a small amount of CuI into an ionic liquid electrolyte. It is found that other copper-I salts, for example, CuBr, have the same effect for the dye-sensitized solar cell. Experimental results show that no Cu^2＋ ions exist in this electrolyte. It is suggested that this improvement is caused by the adsorption of Cu^＋ onto the TiO2 porous film.     

添加钇提高不锈钢耐蚀性能的AES研究

用俄歇能谱仪对比研究了添加０．２％Ｙ对高硅不锈钢在９３％Ｈ２ＳＯ４介质中所形成的钝化膜中各元素浓度分布的影响，添加０．２％Ｙ增大了ＳｉＯ２在不锈钢钝化膜中的比例，从而使合金中Ｓｉ可充分形成富ＳｉＯ２的钝化膜。     

奇异系统的能控性

对于 det E=0的奇异线性控制系统E(?)=Ax Bu,(1)我们总假定矩阵束(sE—A)是正则的,即总假定 det(sE—A)(?)0。由微分方程理论知,在此条件下,对系统(1)所容许的初始值,当 u(t)是足够多次可微时,上述方程总是有解的。