含氟聚合物修饰碳纳米管及其聚氨酯复合疏水膜的研究

利用羟基碳纳米管上的羟基与2-溴异丁基酰溴之间的简单反应, 在碳纳米管上引入了含溴ATRP引发剂, 并进一步引发含氟丙烯酸酯的ATRP聚合, 从而在碳纳米管表面接枝上了低表面能的含氟聚合物. 红外光谱(FT-IR)、热重分析(TGA)和透射电镜(TEM)的研究结果表明碳纳米管与含氟聚合物之间为化学键连接. 以此低表面能聚合物包裹的碳纳米管作为填充粒子, 采用溶液浇铸方法制备了聚氨酯/碳纳米管复合膜, 并利用溶剂四氢呋喃(THF)刻蚀表面获得了不同碳纳米管裸露程度的复合膜材料. 静态接触角测试结果表明, 无论是羟基碳纳米管还是低表面能修饰的碳纳米管均可提高其复合膜的疏水性能, 且其疏水性能随碳纳米管含量的增加而增加; 相同含量时, 含氟聚合物接枝后的碳纳米管使复合膜具有更佳的疏水性能, 膜表面经溶剂刻蚀后可显著提高其疏水性能. 采用扫描电子显微镜(SEM)研究了加入碳纳米管和溶剂刻蚀对聚合物表面微观结构以及材料表面疏水性能的影响. 上述结果表明: 利用接枝聚合物可改变碳纳米管本身的疏水性能, 并可进一步制备新型的具有表面疏水性能的聚合物纳米复合材料.     

恒电流库仑分析法测定硫酸亚铁铵等基准试剂的纯度

在1．8mol／L硫酸介质中,以恒电流通过含有Mn^2＋的电解质溶液,使工作电极铂阳极上电生出Mn^3＋,Mn^3＋与溶液中待测基准试剂硫酸亚铁铵、草酸钠或草酸定量反应,以永停终点法确定库仑滴定终点,通过测量电解电流及电解时间,利用法拉弟电解定律计算基准试剂的纯度。该方法的相对误差为0．32％～0．36％,测量结果的相对标准偏差为0．045％-0．050％（n=11）。     

On Extensions of the Frank-Wolfe Theorems

In this paper we consider optimization problems defined by a quadratic objective function and a finite number of quadratic inequality constraints. Given that the objective function is bounded over the feasible set, we present a comprehensive study of the conditions under which the optimal solution set is nonempty, thus extending the so-called Frank-Wolfe theorem. In particular, we first prove a general continuity result for the solution set defined by a system of convex quadratic inequalities. This result implies immediately that the optimal solution set of the aforementioned problem is nonempty when all the quadratic functions involved are convex. In the absence of the convexity of the objective function, we give examples showing that the optimal solution set may be empty either when there are two or more convex quadratic constraints, or when the Hessian of the objective function has two or more negative eigenvalues. In the case when there exists only one convex quadratic inequality constraint (together with other linear constraints), or when the constraint functions are all convex quadratic and the objective function is quasi-convex (thus allowing one negative eigenvalue in its Hessian matrix), we prove that the optimal solution set is nonempty.     

全光纤波长可调谐调Q激光器

实现了全光纤波长可调谐主动调Ｑ和自调Ｑ激光脉冲输出。波长可调谐范围为５．７ｎｍ。主动调Ｑ激光脉冲的最高峰值功率可达２．６Ｗ,平均功率１ｍＷ。观察到了自调Ｑ现象,且对自调Ｑ现象给予了初步的解释。     

Novel Bandwidth Sensor Based Fiber Grating

In this paper, the basic principle and the design method of the bandwidth sensing of fiber grating are expounded, respectively. Several novel bandwidth sensor based fiber grating are analyzed and discussed.     

结晶聚合物的辐照效应——Ⅰ.尼龙-1010的聚集态结构对其辐射化学反应的影响

本文用DSC,WAXD,ESR和介电谱以及凝胶分数测定等技术,研究Nylon-1010的聚集态对γ-辐射化学反应以及辐照后热处理结果的影响。结果表明,辐照Nylon-1010的交联与裂解反应主要发生在非晶区或结晶表面,进一步证明了非晶区也是辐射后交联和后裂解主要反应区。     

Synthesis and properties of cyano-bridged nickel(II)-iron(III) complexes

Summary Four kinds of novel CN-bridged Ni^II-Fe^III complexes, [NiLn(NC)Fe(CN)₅] ^–, have been synthesized and characterized by elemental analysis, i.r. and u.v.-vis. spectral analysis, and magnetic moments. The formation of cyanide bridges is evident from the i.r. and u.v.-vis. spectra by the appearance of v(CN) shifts and changes in _max with respect to the mononuclear parent complex [Fe(CN)₆]^3–. The magnetic properties indicate the existence of magnetic spin interactions between Ni^II and Fe^III through the cyanide bridge.     

4,5—环氧—2—戊烯醛多相催化加氢

研究了多相钯和镍催化剂上4,5-环氧-2-戊烯醛的催化加氢。发现钯催化剂上加氢产物为4,5-环氧戊醛(1)和2-羟基四氢吡喃(2),而镍催化剂上加氢产物为2和1,5-戊二醇(3)。1、2和3的最高收率分别为58.8%、62.0%和84.7%。讨论了不同催化剂对加氢产物组成的影响。     

An interior point method, based on rank-1 updates, for linear programming

We propose a polynomial time primal—dual potential reduction algorithm for linear programming. The algorithm generates sequencesd ^k andv ^k rather than a primal—dual interior point (x ^k ,s ^k ), where and fori = 1, 2,,n. Only one element ofd ^k is changed in each iteration, so that the work per iteration is bounded by O(mn) using rank-1 updating techniques. The usual primal—dual iteratesx ^k ands ^k are not needed explicitly in the algorithm, whereasd ^k andv ^k are iterated so that the interior primal—dual solutions can always be recovered by aforementioned relations between (x ^k, s^k) and (d ^k, v^k) with improving primal—dual potential function values. Moreover, no approximation ofd ^k is needed in the computation of projection directions. © 1998 The Mathematical Programming Society, Inc. Published by Elsevier Science B.V.