Magnetic structure of the La3NiGe2-type Tb3NiGe2 and Mn5Si3-type Tb5NixGe3−x (x=0 and 0.3)

We present a neutron powder diffraction investigation of the magnetic structure of La₃NiGe₂-type Tb₃NiGe₂ and Mn₅Si₃-type Tb₅Ni_xGe_3−x (x=0, 0.3) compounds. It is found that below∼135 K Tb₃NiGe₂ exhibits a commensurate b-collinear ferrimagnetic ordering with C_2h′={1, m_z, 1′×2_z, 1′×1?} magnetic point group. The Mn₅Si₃-type Tb₅Ge₃ and Tb₅Ni_0.3Ge_2.7 compounds are found to present a flat spiral type antiferromagnetic ordering at 85 and ≥89 K, respectively. The Ni for Ge substitution is found to decrease the flat spiral ordered magnetic unit cell from a×a×40c of Tb₅Ge₃ (below 40 K) down to a×a×5c for Tb₅Ni_0.3Ge_2.7 (below ∼10 K).     

基于席夫碱配体和两种苯甲酸盐构筑的两例Dy4配合物的合成、结构及单分子磁体性质

使用Dy(NO₃)₃·6H₂O与席夫碱配体2-(((2-羟基-3-甲氧基苄基)亚氨基)甲基)-4-甲氧基苯酚(H₂L)和2个辅助配体PhCO₂H和2-NO₂-PhCO₂H在乙醇中反应,得到2例Dy₄配合物[Dy₄(L)₄(PhCO₂)₂(NO₃)₂(EtOH)₂](1)和[Dy₄(L)₄(2-NO₂-PhCO₂)₂(NO₃)₂(EtOH)₂](2)。单晶X射线衍射解析表明配合物1和2均由Dy₂基本单元构建,形成中心对称的四核线性链状结构。配合物1和2中Dy₂单元中的一个Dy(Ⅲ)离子呈现七配位几何构型,另一个Dy(Ⅲ)离子呈现八配位几何构型。2例配合物均为单分子磁体,其能垒分别为110和108 K。通过理论计算对1和2的磁性能进行了分析。     

Photodriven Active Ion Transport Through a Janus Microporous Membrane

Precise control of ion transport is a fundamental characteristic for the sustainability of life. It remains a great challenge to develop practical and high‐performance artificial ion‐transport system that can allow active transport of ions (protons) in an all solid‐state nanoporous material. Herein, we develop a Janus microporous membrane by combining reduced graphene oxide (rGO) and conjugated microporous polymer (CMP) for controllable photodriven ion transport. Upon light illumination, a net ionic current is generated from the CMP to the rGO side of the membrane, indicating that the rGO/CMP Janus membrane can realize photodriven directional and anti‐gradient ion transport. Analogously to the p‐n junction in photovoltaic devices, light is firstly converted into separated charges to trigger a transmembrane potential, which subsequently drives directional ion movement. For the first time, this method enables integration of a photovoltaic effect with an ionic field to drive active ion transport. With the advantages of scaled up production and easy fabrication, the concept of photovoltaic ion transport based on Janus microporous membrane may find wide application in energy storage and conversion, photodriven ion‐sieving, and water treatment.     

Efficient double-strand cleavage of DNA mediated by Zn(II)-based artificial nucleases

Two water-soluble zinc complexes, [Zn(L)Cl(2)] (1) and [Zn(2)(L)(2)(μ-C(2)O(4))(H(2)O)(2)]·(ClO(4))(2)·CH(3)OH (2) (L = N,N-bis(2-pyridylmethyl)methylamine), were prepared to serve as nuclease mimics. The complexes were characterized by X-ray, IR and UV-vis spectroscopy as well as ESI-MS. The electrospray mass spectrum of 2 in solution indicates that dinuclear ion [Zn(2)(L)(2)(μ-C(2)O(4))(ClO(4))](+) (3) is the active species. UV-Vis absorption and fluorescence spectroscopy studies show that the complexes partially intercalate to CT-DNA. In the absence of reducing agent, supercoiled plasmid DNA cleavage by the complexes 1 and 3 was performed and the hydrolytic mechanism was demonstrated by adding standard radical scavengers.     

Novel bending sensor based on a meniscus shaped beam with LPG

A novel bending sensor based on a long period fiber grating (LPG) is presented. A LPG was glued into a V-shaped groove, which lies on the lower surface of a meniscus shaped beam. It is found that the transmission optical power of the LPG changed linearly with the variation of the bending of the beam. The bending applied on the beam can be measured by detecting the intensity variation of the LPG's resonant dip wavelength. Under a relative large bending measured range from 0 to 7.5 m^?1, the sensitivity of 3.003 dB m^?1 and curvature resolution of 0.001 m^?1 have been achieved for the proposed bending sensor.     

基于多芯片封装的半导体激光器热特性

设计了一种由12只单条形芯片分为2组以从高到低阶梯排列的百瓦级半导体激光器结构。针对其在稳态工作条件下的热特性利用ANSYS软件进行了模拟分析,通过改变Cu热沉的宽度、间距和高度差,得到了最高和最低Cu热沉封装的芯片有源区温度及两者温度差值的变化规律。最后设计了一种较为理想的百W级半导体激光器的散热结构。     

由润滑油密度求黏度的新黏压关系式探讨

研究了润滑油密度与黏度的关系,并提出了一个由密度求黏度的新黏压关系式.以Dowson-Higginson密度公式为媒介,新公式只改变一个常数可退化为Barus黏压关系,而改变两个常数可退化为Doolittle自由体积黏压关系.用Dowson-Higginson密压关系消去密度,新公式具有与Roelands黏压关系相同的结构,但对应常数各不相同.以squalane油为例,给出了由实验数据确定新公式中两个待定常数的简单方法,而如此确定下来的新公式可以与全部实验数据吻合良好.应用新公式计算黏度并以squalane油品为润滑剂,可顺利求得等温椭圆接触弹性流体动力润滑的数值解,说明新公式具有良好的适应性.     

Effects of Mn substitution on the structure and properties of chalcopyrite-type CuInSe2

Mn-doped CuInSe₂ compounds (CuIn_1−xMn_xSe₂, x=0.0125–0.20 and Cu_1−yIn_1−yMn_2ySe₂, 2y=0.0125–0.60) were synthesized by high-temperature solid-state reactions. Single phase materials with chalcopyrite structure persist up to 0.10 and 0.20 doping for CuIn_1−xMn_xSe₂ and Cu_1−yIn_1−yMn_2ySe₂, respectively. The chalcopyrite and sphalerite phases co-exist in the Cu_1−yIn_1−yMn_2ySe₂ system for 2y=0.25–0.50. Attempts to introduce greater manganese content, x=0.15–0.20 for CuIn_1−xMn_xSe₂ and 2y=0.60 for Cu_1−yIn_1−yMn_2ySe₂, result in partial phase segregation. For the single-phase samples, the lattice parameters of both systems increase linearly with manganese concentration and thus follow Vegard's law. The temperature of the chalcopyrite–sphalerite phase transition is decreased by manganese substitution for all single-phase samples. The bandgap of the materials remains around 0.9 eV. Additionally, the Mn-doped CuInSe₂ compounds display paramagnetic behavior, whereas pure CuInSe₂ is diamagnetic at 5–300 K. All the CuIn_1−xMn_xSe₂ and Cu_1−yIn_1−yMn_2ySe₂ compounds with chalcopyrite structure show antiferromagnetic coupling and measured effective magnetic moments up to 5.8 μ_B/Mn.     

一个基于恢复时间的新剪稀模型及其对聚合油PAO 650流变特性的模拟

用球-杆比拟流体层上的分子,通过分析两流体层上球-杆的接触、通过和恢复的过程,基于球-杆恢复到原状态的时间,建立了一个新剪稀模型.该模型虽然在形式上与Carreau模型有相似之处,但其公式仅含有两个流变参数,且是经由严格的理论推导得到的.通过与Carreau模型得到的广义黏度曲线的比较,确定了新流变公式的待定参数.在点接触流变热弹流润滑的数学模型中使用新流变公式,数值模拟了大黏度聚合油PAO 650的流变特性,并与该油在文献中的试验曲线进行了比对.结果表明新流变模型能够较好地模拟大黏度聚合油的流变特性,从而证实了其正确性.进一步,使用新公式计算得到了更多工况下的流变特性曲线,光滑的、合理的曲线分布说明新流变模型具有广泛的适用性.     

高效液相色谱-蒸发光散射检测法测定番茄中的番茄皂苷A

建立了测定番茄原料中的番茄皂苷A含量的高效液相色谱-蒸发光散射检测法(HPLC-ELSD)。将实验条件优化后,运用该方法分离番茄皂苷A。结果表明,该方法在番茄皂苷A的质量为0.61～3.05 mg范围内具有良好的线性相关性(r=0.9995),平均回收率为97.9%～104.8%,相对标准偏差(RSD)≤4.14%(n=5)。该方法快速、准确,样品处理简单,可用于番茄原料及其提取物中番茄皂苷A的含量测定与质量控制。