全文获取类型
收费全文 | 4351篇 |
免费 | 479篇 |
国内免费 | 650篇 |
专业分类
化学 | 2483篇 |
晶体学 | 58篇 |
力学 | 174篇 |
综合类 | 190篇 |
数学 | 1155篇 |
物理学 | 1420篇 |
出版年
2024年 | 6篇 |
2023年 | 143篇 |
2022年 | 186篇 |
2021年 | 196篇 |
2020年 | 236篇 |
2019年 | 213篇 |
2018年 | 201篇 |
2017年 | 200篇 |
2016年 | 231篇 |
2015年 | 273篇 |
2014年 | 427篇 |
2013年 | 482篇 |
2012年 | 427篇 |
2011年 | 408篇 |
2010年 | 319篇 |
2009年 | 312篇 |
2008年 | 190篇 |
2007年 | 192篇 |
2006年 | 202篇 |
2005年 | 102篇 |
2004年 | 53篇 |
2003年 | 53篇 |
2002年 | 65篇 |
2001年 | 85篇 |
2000年 | 49篇 |
1999年 | 48篇 |
1998年 | 16篇 |
1997年 | 19篇 |
1996年 | 14篇 |
1995年 | 17篇 |
1994年 | 23篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 6篇 |
1990年 | 8篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1959年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有5480条查询结果,搜索用时 46 毫秒
31.
Novel self activated green phosphors; K2ZnV2O7 (KZV) and K2MgV2O7 (KMV) have been prepared and characterized in details. Both KZV and KMV were prepared by solid state reaction and systematically characterized by a number of techniques like X-ray diffraction (XRD), Fourier transformed Infrared (FTIR), Raman spectroscopy, Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), diffuse reflectance spectroscopy (DRS) and time resolved photoluminescence spectroscopy (TRPLS). XRD studies confirm tetragonal melilite type layered phase for both of them. The presence of pyrovanadate group in both is supported by FTIR and Raman spectroscopic investigations. Raman bands of KMV are blue shifted w.r.t to KZV which may be due to shorter bond lengths of MgO compared to ZnO and lower atomic weight of magnesium compared to zinc. DRS measurements indicated the optical band gap of KMV and KZV are 3.14 and 3.12 eV, respectively. Optical measurements on these samples show the emission of green color on ultra violet light irradiation. The origin of such emission is attributed to electronic transition (charge transfer) from filled 2p orbital of oxygen ion (O2−) to vacant 3d orbital of vanadium ion (V5+). In KZV there are dual emission band (PL1 and PL2) which are respectively attributed to 3T2 → 1A1 and 3T1 → 1A1transition, and the emission zone varies slightly compared to KMV. KZV emits bluish green (cool green) where KMV emits in yellowish green (warm green) region. This is indeed an important step towards realization of cost effective rare earth free luminescence material. It is also oberved that PL intensity of KZV is very high compared to KMV which is supported by the lifetime measurements. 相似文献
32.
33.
In Situ Photocatalytically Heterostructured ZnOAg Nanoparticle Composites as Effective Cathode‐Modifying Layers for Air‐Processed Polymer Solar Cells 下载免费PDF全文
Kai Yuan Prof. Dr. Lie Chen Prof. Dr. Yiwang Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11899-11906
A heterostructured semiconductor–metal ZnO?Ag nanoparticle (NP) composite was constructed through a straightforward photocatalytic strategy by using UV irradiation of ZnO NPs and an aqueous solution of Ag precursor. The ZnO?Ag NP composites serve as an effective cathode‐modifying layer in polymer solar cells (PSCs) with increased short‐circuit current density owing to the light‐trapping effect, and improved optical and electrical conductivity properties compared with pure ZnO NPs. The Ag NPs, which are photodeposited in situ on ZnO NPs, can act as effective antennas for incident light to maximize light harvesting and minimize radiative decay or nonradiative losses, consequently resulting in the enhanced photogeneration of excitons in PSCs. Systematic photoelectron and ‐physical investigations confirm that heterostructured ZnO?Ag NPs can significantly improve charge separation, transport, and collection, as well as lower charge recombination at the cathode interface, leading to a 14.0 % improvement in air‐processed device power conversion efficiency. In addition, this processable, cost‐effective, and scalable approach is compatible with roll‐to‐roll manufacturing of large‐scale PSCs. 相似文献
34.
35.
36.
A new polyoxygenated dihydropyrano[2,3-c]pyrrole-4,5-dione derivative, pyranonigrin F (1), together with a related known compound, pyranonigrin A (2), were isolated and identified from Penicillium brocae MA-231, an endophytic fungus obtained from the fresh tissue of the marine mangrove plant Avicennia marina. The structures of these metabolites were determined based on comprehensive spectral interpretation and the absolute configuration of compound 1 was established by X-ray crystallographic analysis. Compounds 1, and 2 showed potent activity against a broad spectrum of human-, aqua-, and plant-pathogens. 相似文献
37.
38.
39.
Fen Yu Dr. Xuan Fang Huimin Jia Miaoxing Liu Xiaotong Shi Chaowen Xue Dr. Tingtao Chen Prof. Zhipeng Wei Prof. Fang Fang Prof. Hui Zhu Prof. Hongbo Xin Prof. Jing Feng Prof. Xiaolei Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(24):8053-8058
For the first time, the influence of different types of atoms (Zn and O) on the antibacterial activities of nanosized ZnO was quantitatively evaluated with the aid of a 3D‐printing‐manufactured evaluation system. Two different outermost atomic layers were manufactured separately by using an ALD (atomic layer deposition) method. Interestingly, we found that each outermost atomic layer exhibited certain differences against gram‐positive or gram‐negative bacterial species. Zinc atoms as outermost layer (ZnO?Zn) showed a more pronounced antibacterial effect towards gram‐negative E. coli (Escherichia coli), whereas oxygen atoms (ZnO?O) showed a stronger antibacterial activity against gram‐positive S. aureus (Staphylococcus aureus). A possible antibacterial mechanism has been comprehensively discussed from different perspectives, including Zn2+ concentrations, oxygen vacancies, photocatalytic activities and the DNA structural characteristics of different bacterial species. 相似文献
40.
Jiarui Yu Nan Gao Xiaowen Xie Xing Xin Zhanqi Li Shuai Chen Jingkun Xu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(5):794-802
Thermally healing capability of cracks and defects is important and urgent for the safe operation and life extending of electric materials and devices. Here, by the combination of thermally driven reversible Diels–Alder (DA) interaction and in-situ chemical oxidative polymerization of 3,4-ethylenedioxythiophene (EDOT), a series of intrinsically conductive poly(3,4-ethylenedioxythiophene) (PEDOT)/DA composites possess intrinsically self-healing property under low-temperature (reverse DA reaction at 100°C; DA crosslinking at 60°C) stimulus were achieved. The crosslinking DA bonding reactions are multiple from the co-existence of pre-synthesized macromolecular polyurethane attached DA units (PU-DA) and 2,4-hexadiyne-1,6-diol (DADOL) in the films. PU-DA involved in the polymerization process of EDOT to endow PEDOT with outstanding solution-processability, uniform film making, and structural self-healing capability, while DADOL was added to enhance the cross bonding between polymer chains. This work will accelerate the research and application development of intrinsically self-healing conducting polymers for commercial capacitors, antistatic coatings, implantable, printable electronics, and so on. 相似文献