一种新实验应力分析方法——声弹性实验应力分析方法简介

1940年S.OKA发现了应力引起的声双折射现象.此后,随着发射和检测超声波技术的进展,近年来有人提出各种方法用来测定应力引起的声双折射、声速和声频谱变化.测出这些变化便能定出施加在物体上的外力和残余应力.目前,超声波应力分析方法引起了人们的广泛注意,并开始形成一门与光弹性力学相类似的新学科——“声弹性力学”.     

基于灰色马尔科夫模型的中国女子竞走成绩的预测

以中国女子竞走年度最好成绩作为原始数据序列建立灰色马尔科夫预测模型.研究表明:灰色马尔科夫预测模型对中国女子竞走成绩的预测具有更高的精确度与实用价值;通过对女子竞走年度最好成绩进行预测,预测结果显示中国女子竞走与世界女子竞走的年度最好成绩呈现出拉大趋势.     

1,8-位修饰杂芴类有机光电功能材料的合成与应用

以氧、硫、硅、氮、磷等杂原子取代芴中sp3杂化的碳原子所形成的杂芴,不仅可以通过杂原子和π共轭体系间的相互作用有效地调控材料的电子结构,而且可以影响芴不同位置的修饰,从而得到了广泛关注。本文详细分析了1,8-位修饰杂芴的分子结构特点和光电特性,根据不同的杂原子分类论述了相关材料的合成方法和原理,综述了1,8-位修饰杂芴类材料在磷光主体材料、电致发光材料、太阳能电池材料以及有机配体材料等方面的应用进展,展望了其在有机光电材料方面的应用前景和发展趋势。     

静态顶空气相色谱法测定有机残留溶剂二甲基亚砜

建立了高灵敏度、高精确度的静态顶空气相色谱结合氢火焰离子化检测器测定药物辅料中二甲基亚砜残留溶剂的方法.以液体石蜡为溶解溶剂,优化了顶空瓶的液相体积,并对顶空气相色谱的关键实验参数:自动进样时间、顶空加压时间、顶空平衡温度、顶空平衡时间及气相柱温箱升温程序等进行了优化.在最优条件下,确定了方法的检出限和定量限分别为1....     

Dual-Band Negative-Index Materials with Sandwich Configuration

Dual-band negative-index properties of the silver-SU-8-silver sandwich configuration, perforated with a square array of cross dipole apertures, are simulated and analyzed in the midinfrared region. The first and the second negative-index bands correspond to the （1,0） and （1,1） internal surface plasmon polariton （SPP） modes, respectively. The internal and external SPP modes acquired by the SPP dispersion relation of the metal/dielectric/metal model match well with the simulated transmission peaks. The effective parameters for the two negative-index bands are retrieved using simulated S parameters. The coupling effect between the （1,1） internal SPP mode and the localized resonance mode can be tuned by the arm length of cross dipole, which can weaken or destroy the negative electromagnetic response of the second negative-index band. The electric quadrupole mode of the second negative-index band accounts for its strong dependence on the dielectric loss of the interlayer.     

前沿分析法研究对-羟基苯甲酸印迹整体柱的热力学行为

采用矩形前沿分析法对原位聚合的对-羟基苯甲酸印迹整体柱的热力学吸附等温线进行了测定. 印迹整体柱的吸附等温线是分别以乙腈、甲醇、 四氢呋喃和含有体积分数分别为1%, 3%, 5%和7%乙酸的乙腈为流动相以及在以甲醇为流动相时柱温分别为20, 40和50 ℃的条件下测定的. 吸附等温线表明, 印迹整体柱对模板分子的吸附能力比其结构类似物(邻-羟基苯甲酸)的吸附能力强. 用双Langmuir方程对不同条件下得到的实验数据进行拟合, 得到模板分子和邻-羟基苯甲酸在印迹整体柱各种吸附位点上的饱和吸附量和键合常数, 结果表明, 流动相中乙酸含量、有机溶剂的性质和柱温对模板分子容量因子的影响比对邻-羟基苯甲酸的大, 造成印迹聚合物的选择性随条件的变化而发生了明显的改变.     

A novel twice-interpolation finite element method for solid mechanics problems

Formulation and numerical evaluation of a novel twice-interpolation finite element method （TFEM） is presented for solid mechanics problems. In this method, the trial function for Galerkin weak form is constructed through two stages of consecutive interpolation. The primary interpolation follows exactly the same procedure of standard FEM and is further reproduced according to both nodal values and averaged nodal gradients obtained from primary interpolation. The trial functions thus constructed have continuous nodal gradients and contain higher order polynomial without increasing total freedoms. Several benchmark examples and a real dam problem are used to examine the TFEM in terms of accuracy and convergence. Compared with standard FEM, TFEM can achieve significantly better accuracy and higher convergence rate, and the continuous nodal stress can be obtained without any smoothing operation. It is also found that TFEM is insensitive to the quality of the elemental mesh. In addition, the present TFEM can treat the incompressible material without any modification.     

梯度共聚物研究进展

梯度共聚物是一类新型的聚合物,其具有与嵌段共聚物相似的丰富性质,但是合成相对简便,更易于大规模生产进而实现产业化,因此备受关注。 本文从梯度共聚物的定义与结构特点、合成与表征、自组装行为、性质及应用等几个方面综述梯度共聚物当前研究现状,展望其发展方向。     

A novel four-node quadrilateral element with continuous nodal stress

Formulation and numerical evaluation of a novel four-node quadrilateral element with continuous nodal stress（Q4-CNS）are presented.Q4-CNS can be regarded as an improved hybrid FE-meshless four-node quadrilateral element（FE-LSPIM QUAD4）, which is a hybrid FE-meshless method.Derivatives of Q4-CNS are continuous at nodes, so the continuous nodal stress can be obtained without any smoothing operation.It is found that,compared with the standard four-node quadrilateral element（QUAD4）,Q4- CNS can achieve significantly better accuracy and higher convergence rate.It is also found that Q4-CNS exhibits high tolerance to mesh distortion.Moreover,since derivatives of Q4-CNS shape functions are continuous at nodes,Q4-CNS is potentially useful for the problem of bending plate and shell models.