182Hf实验室参考标准的研制与加速器质谱测量

介绍了用于HI-13串列加速器质谱(AMS)测量的¹⁸²Hf实验室参考标准的研制. 通过¹⁸⁰Hf的连续热中子俘获产生¹⁸²Hf, 用热电离质谱对初始参考标准的同位素比进行了精确测量. 取一定量的初始参考标准, 加入已知量的稳定同位素(¹⁸⁰Hf)作为稀释剂, 通过逐级稀释的方法, 最终得到同位素比从10^－6—10^－10的一系列参考标准. 并对该系列参考标准进行了AMS测量, 结果显示¹⁸²Hf/¹⁸⁰Hf的测量值与标称值呈良好的线性关系, 说明该AMS系统可以准确测量同位素比在10^－6—10^－10范围内的样品.     

Recent progress in AMS measurement of 182Hf at the CIAE

In order to improve the accuracy of accelerator mass spectrometry (AMS) measurement for ¹⁸²Hf/¹⁸⁰Hf, a series of measurements have been taken in the AMS laboratory at the China Institute of Atomic Energy (CIAE). The major ones include the instantaneous monitoring of ¹⁸⁰HfF₅^- current, testing the stability of transmission, the alternate measurements of an unknown sample and standard, and the origin identification and minimization of background ¹⁸²W. The experimental details and the improvement in the measurement accuracy, as well as some useful suggestions for better satisfying the requirements of certain practical applications, are presented in this paper.