双峰双波长吸光光度法测定痕量铝

在pH5.5～6.0的六次甲基四胺缓冲溶液中,铝一络天青S—溴化十六烷基毗啶一Triton X-100体系具有正、负两个吸收峰于630nm和475nm处.据此,建立了痕量铝的双峰双波长吸光光度法.铝在0～5μg/25ml范围遵守比耳定律,摩尔吸光系数达1.2×10~5.测定了铝锅开水中痕量铝,结果满意.     

Spectrum Simulation of Li-Like Aluminium Plasma

X-ray emission spectra for L-shell of Li-like aluminium ions are simulated by using the flexible atomic code based on the collisional radiative model. Atomic processes including radiative recombination, dielectronic recombination, collisional ionization and resonance excitation from the neighbouring ion （Al^9＋ and Al^11＋ ） charge states of the target ion （Al^10＋） are considered in the model. In addition, the contributions of different atomic processes to the x-ray spectrum are analysed. The results show that dielectronic recombination, radiative recombination, collisional ionization and resonance excitation, other than direct collisional excitation, are very important processes.     

Antiphase State in Passively Q-Switched Yb：YAG Microchip Lasers with a Nd,Cr：YAG as Saturable Absorber

We experimentally investigate the antiphase dynamics phenomenon that occurs in a diode-pumped passively Q-switched Yb:YAG multimode laser with a Nd,Cr:YAG saturable absorber. Due to the effect of spatial hole burning, the multimode lasers with one, two, or three modes at different pump power are observed, and the pulses sequences display classic antiphase dynamics.     

超稳Y沸石制备技术对沸石铝分布的影响 Ⅱ.均匀铝分布的超稳Y沸石的制备

对水热处理后得到的USY沸石作进一步的酸处理以及采用改进的氟硅酸盐溶液骨架富硅工艺,分别得到了经XPS剖面分析证实为铝分布均匀的超稳Y沸石HAY-Ⅰ和HAY-Ⅱ。IR分析表明,在酸处理过程中从USY沸石中去掉的那部分非骨架铝类与3690cm~(-1)处羟基有关,仍残留在HAY-Ⅰ沸石中的那部分非骨架铝类与3670cm~(-1)和3600cm~(-1)处羟基有关。XRD和化学分析表明HAY-Ⅰ沸石仍含有约50％的非骨架铝类,而HAY-Ⅱ沸石则基本上不含非骨架铝类,HAY-Ⅱ沸石还显示更高的结晶保留度。DTA分析表明,HAY-Ⅰ和HAY-Ⅱ两种沸石的热稳定性均高于USY沸石。     

电感耦合等离子体发射光谱法测定磷酸中钙、镁、铁、铝

本文叙述了用1CP-AES测定磷酸中的Ca、Mg、Fe、Al的原理,试样处理和测定方法,精密度试验相对误差分别是2.17、0.533、1.676、0.638%。回收率在95.58-105.49%之间。基体和元素间不互相干扰。     

ICP—AES法测定U3O8标样中Al、Cr、Fe、Mg、P、Pb、Ti、V、W

用7402季铵－Kel-F粉萃取色层使铀和待测杂质元素分离，接着用975型ICP光量计测定U3O8标样中Al、Cr、Fe、Mg、P、Pb、Ti、V、W，回收率为95－110％，相对标准偏差≤5％。