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A new Digital Pulse Processing(DPP) module has been developed, based on a domino ring sampler version 4 chip(DRS4), with good time resolution for La Br3 detectors, and different digital timing analysis methods for processing the raw detector signals are reported. The module, composed of an eight channel DRS4 chip, was used as the readout electronics and acquisition system to process the output signals from XP20D0 photomultiplier tubes(PMTs). Two PMTs were coupled with La Br3 scintillators and placed on opposite sides of a radioactive positron22 Na source for 511 ke V γ-ray tests. By analyzing the raw data acquired by the module, the best coincidence timing resolution is about 194.7 ps(FWHM), obtained by the digital constant fraction discrimination(d CFD) method,which is better than other digital methods and analysis methods based on conventional analog systems which have been tested. The results indicate that it is a promising approach to better localize the positron annihilation in positron emission tomography(PET) with time of flight(TOF), as well as for scintillation timing measurement,such as in TOF-?E and TOF-E systems for particle identification, with picosecond accuracy timing measurement.Furthermore, this module is more simple and convenient than other systems. 相似文献
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The uses of methane, the major component in natural gas, have been investigated by many research groups throughout the world. A number of catalysts, single or binary, have been proposed for the oxidative coupling of CH4 with CO2 as the oxidant[1~6]. Binary metal-oxide catalysts, such as La2O3-ZnO and CaO-ZnO, showed higher C2 hydrocarbon selectivity (>80%) with low CH4 conversion (<6%) at high temperatures (750~850 ℃)[7~9]. 相似文献
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在常温常压下,研究了脉冲放电等离子体及其协同催化剂强化CH4氢化偶联反应.结果表明:脉冲电晕等离子体条件下,甲烷中引入氢气可以实现偶联,而且随着氢气引入量的增加甲烷的转化率以及C2收率增大,积碳减少;脉冲电压和重复频率影响CH4的转化;引入Ni/γ -Al2O3催化剂后可改善产物C2烃的分布,等离子体法制备的Ni/γ -Al2O3催化剂性能优于化学法制备的Ni/γ -Al2O3催化剂.开辟了一条甲烷偶联新技术路线. 相似文献
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有氧气氛下等离子体甲烷偶联反应的研究 总被引:2,自引:0,他引:2
近年来,非平衡等离子体应用于甲烷直接转化的研究备受关注,但多数研究工作采用的是低气压下微波或高频放电产生的非平衡等离子体[1-9].在常压下获得非平衡等离子体一般是通过脉冲电晕放电或介质阻挡放电产生的[10,11].Liu等[12]采用电晕放电(非脉冲)研究了CH4+O2+He(pCH4=2.03×104Pa,pO2=5.07×103Pa,He平衡)体系的甲烷偶联反应. 如前文[13]所述,脉冲电晕等离子体是一种新型常压非平衡等离子体,其电子通过上升沿陡峭的窄脉冲电场加速而获得能量(1~20eV).将其应用于甲烷偶联反应,不仅具有反应条件温和(常温常压)… 相似文献
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蚕茧层中色氨酸的高效液相色谱测定法 总被引:1,自引:0,他引:1
本文建立了用高效液相色谱(HPLC)分析蚕茧层中色氨酸的方法,该法未见报道。蚕茧层由丝蛋白组成,丝蛋白是由十八种氨基酸组成。其中十七种氨基酸是用盐酸水解样品,采用氨基酸仪可同时测定。由于盐酸使色氨酸分解,不能测定。为补充测定色氨酸的简便、准确的方法,我们采用不分解色氨酸的碱法处理样品,用HPLC法分析色氨酸。为保护色谱柱,用超滤膜滤去大分子。对各种蚕茧层不同水解情况进行了考察,分析了柞蚕茧、桑蚕茧层中的色氨酸,结果与报道的比色法、荧光法相一致;还分析厂东北天蚕茧层中色氨酸,补充了尚未分析的数据。该法的精度、回收率都令人满意。也证明了虽然文献[1][5]方法复杂粗糙,但也是可行的。 相似文献
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脉冲电晕等离子体作用下甲烷偶联反应--Ⅰ.无氧气氛下 总被引:2,自引:0,他引:2
在常温常压下,对脉冲电晕等离子体应用于甲烷无氧气氛下脱氢偶联反应进行了研究.考察了脉冲电压极性和等离子体注入能量对甲烷脱氢偶联反应的影响,并引入能量效率对等离子体能量与甲烷脱氢偶联反应的耦合进行了讨论.结果表明,正电晕的能量效率高于负电晕.在正电晕条件下,当脉冲重复频率为 66 Hz和能量密度为 1788kJ/mol时,甲烷转化率可达44.6%, C_2烃单程收率可达31.6%,其中乙炔单程收率达30.1%.甲烷转化率与能量密度P/F的关系满足-ln(1—X)=k(P/F).在实验考察的能量范围内,C_2烃收率与能量密度P/F呈顺变关系,但能量效率随能量密度的增加而降低. 相似文献
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A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space group P1 with a = 10.266(2), b = 11.573(2), c = 12.651(3) A, α = 89.95(3), β= 74.64(3),γ = 68.54(3)°, C50H44Cd4N12O18, Mr = 1550.57, V= 1341.1(5)A3, Dc = 1.920 g/cm3, F(000) = 764, p = 1.651 cm-1 and Z = 1. The final refinement gave R = 0.0342 and wR = 0.0738 for 5925 observed reflections with I 〉 2σ(I). The crystal structure involves two different ladder-like chains, which are further connected to form a ladder-like double chain architecture via hydrogen bonding interactions, extending along the b axis. The weak interactions including hydrogen bonds and π-π staking interactions contribute to the alignment of the complex in the crystalline state. 相似文献