1,3,4-噁二唑环金属配体的磷光型铱阳离子配合物:溶剂相关的激发态动力学研究

To elucidate the nature of low-lying triplet states and the effect of ligand modifications on the excited-state properties of functional cationic iridium complexes,the solventdependent excited-state dynamics of two phosphorescent cationic iridium (III) complexes,namely[Ir (dph-oxd)₂(bpy)]PF₆(1) and[Ir (dph-oxd)₂(pzpy)]PF₆(2),were investigated by femtosecond and nanosecond transient absorption spectroscopy.Upon photoexcitation to the metal-to-ligand charge-transfer (MLCT) states,the excited-state dynamics shows a rapid process (τ=0.7-3 ps) for the formation of solvent stabilized ³MLCT states,which significantly depends on the solvent polarity for both 1 and 2.Sequentially,a relatively slow process assigned to the vibrational cooling/geometrical relaxation and a long-lived phosphorescent emissive state is identified.Due to the different excited-state electronic structures regulated by ancillary ligands,the solvation-induced stabilization of the ³MLCT state in 1 is faster than that in 2.The present results provide a better sight of excited-state relaxation dynamics of ligand-related iridium (III) complexes and solvation effects on triplet manifolds.     

基于DGPS航迹偏差的多旋翼无人机磁干扰检测技术研究

为了解决多旋翼无人机在飞行作业过程中受到环境磁干扰导致作业异常的问题,在使用DGPS进行差分定位的基础上,提出了一种基于航迹偏差的多旋翼无人机磁干扰检测技术。其基本原理是,当多旋翼无人机受到磁场干扰时,其飞行航迹会偏离预设航线,检测其航迹的偏离距离,通过与阈值比较,可以用来判断是否存在环境磁干扰。实验结果表明该方法可以有效检测环境磁场异常,在某些情况下比传统的磁航向角误差阈值检测方法可靠性更高,虚警率更小。综合使用航迹偏差检测方法和磁航向角误差检测方法,可有效（提高）环境磁场异常检测的准确度,降低虚警率。     

四种耐热含能化合物电子结构的第一性原理研究

本文模拟计算了2,2’,4,4’,6,6’-六硝基联苯(HNBP)、2,2’,4,4’,6,6’-六硝基二苯乙烯(HNS)、2,5-二苦基-1,3,4-噁二唑(DPO)和5,5''-双(2,4,6-三硝基苯基)-2,2''-双(1,3,4-噁二唑)(TKX-55)四种耐热含能化合物的分子结构、Mulliken电荷布居、分子静电势(MEP)和Hirshfeld表面, 通过研究其分子特性、电子特性以及分子间相互作用, 以了解高耐热性含能化合物的耐热机理. 结果表明, 桥连接结构的复杂性以及分子间强氢键相互作用会增强含能化合物的稳定性. 此外, 本研究还发现中间基团的加入会对四种含能化合物分子两侧芳香环上碳原子的电荷分布以及分子表面正负静电势区域面积产生一定的影响.