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21.
Shouwen Jin Dr. Daqi Wang Zhiwen Zheng Jie Chen Chao Feng Xianghua Ye Yiping Zhou 《无机化学与普通化学杂志》2010,636(8):1617-1624
Five novel coordination polymers, [(Cu(L1)2OH) · Cl · 3H2O] ( 1 ) [L1 = bis(N‐imidazolyl)methane], [Cd(L1)2(NCS)2] ( 2 ), [Zn(L1)2(NCS)2] ( 3 ), [Cu(L1)2(NO3)2] ( 4 ), and [Cu(L2)1.5(NCS)2] ( 5 ) [L2 = 1,4‐bis(N‐imidazolyl)butane] were obtained from self‐assembly of the corresponding metal salts with flexible ligands and their structures were fully characterized by X‐ray diffraction (XRD) analysis, Fourier Transform Infrared (FT‐IR) spectroscopy, elemental analysis and thermogravimetric (TGA) measurements. X‐ray diffraction analyses revealed that complexes 1 , 2 , 3 , and 4 exhibit 1D double‐stranded chain structures, which result from doubly bridged [CuOH], [M(NCS)2] (M = Cd, Zn), and [Cu(NO3)2] units, respectively. The polymeric copper complex 5 displays 1D ladder structure., These complexes, with the exception of complex 1 , are stable up to 300 °C. 相似文献
22.
Xianghua Zeng Zhimei Li Zhiyin Xiao Yanwei Wang Xiaoming Liu 《Electrochemistry communications》2010,12(3):342-345
The synthesis and characterisation of two diiron hexacarbonyl complexes [Fe2(SXS)(CO)6], 1 (SXS = ((?SCH2)2C(CH3)CH2OCOFc, Fc = ferrocenyl group) and 2 (SXS = (?SCH2CH2NHCOFc)2), were described. By using intramolecularly integrated ferrocenyl group(s) in the complexes as an internal standard, the nature of two stepwise one-electron processes of the complexes coupled with a chemical reaction was clearly demonstrated. Examining how the reduction transformed into sole one-electron process with both increasing scanning rate under Ar/CO atmosphere and lowering temperature indicated conclusively that the reduction of both complexes couples to a chemical reaction which involves CO-loss. 相似文献
23.
Zhan C Wang X Wei Z Evans DJ Ru X Zeng X Liu X 《Dalton transactions (Cambridge, England : 2003)》2010,39(46):11255-11262
By using "click" chemistry between a diazide and a diiron model complex armed with two alkynyl groups, two polymeric diiron complexes (Poly-Py and Poly-Ph) were prepared. The two polymeric complexes were investigated using infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), M?ssbauer spectroscopy, and cyclic voltammetry (Poly-Py only, due to the insolubility of Poly-Ph). To probe the coordinating mode of the diiron units in the two polymeric complexes, two control complexes (3 and 4) were also synthesised using a monoazide. Complexes 3 and 4 were well characterised and the latter was further crystallographically analysed. It turns out that in both complexes (3 and 4) and the two polymeric diiron complexes, one of the two iron atoms in the diiron unit coordinates with one of the triazole N atoms. Our results revealed that both morphologies and properties of Poly-Py and Poly-Ph are significantly affected by the organic moiety of the diazide. Compared to the protonating behaviour of the complexes 3 and 4, Poly-Py exhibited proton resistance. In electrochemical reduction, potentials for the reduction of the diiron units in Poly-Py and hence its catalytic reduction of proton in acetic acid-DMF shifted by over 400 mV compared to those for complexes 3 and 4. It is likely that the polymeric nature of Poly-Py offers the diiron units a "protective" environment in an acidic medium and more positive reduction potential. 相似文献
24.
A novel analytical technique termed ultrasonic-assisted drop-to-drop solvent microextraction (USA-DDSME) in a capillary tube was developed to determine trace benzene, toluene, xylene in one drop of a water sample, which was combined with gas chromatography–flame ionization detection (GC–FID). The advantages of this method are rapidity, convenience, ease of operation, simplicity of the device, and extremely little solvent and sample consumption. Extraction conditions including the type of extraction solvent, the volume of extraction solvent, the volume of sample, extraction time and effect of salt concentration were optimized. The best optimum parameters for extraction were achieved with 3 μL of extraction solvent. Chloroform was divided into four equal divisions in 20 μL water sample (without salt addition) in a capillary tube and ultrasonicated for 10 min, centrifugated at 2,500 rpm for 5 min to let the extraction solvent settle at the bottom of the capillary tube, then 1 μL of the separated extraction solvent was injected into the GC–FID for analysis. Linearity of the method was determined by analyzing spiked water samples over a concentration range of 0.1–50 μg mL?1. Correspondingly, the LOD values were 0.01 μg mL?1. All calibration curves were found to have good linearity with correlation coefficients (r 2) > 0.995. The precision (RSD) of the system, measured by six repeated determinations of the analytes at 1 μg mL?1 were in the range of 1.6–3.5%. 相似文献
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孔型立轧过程的三维刚塑性有限元分析 总被引:4,自引:0,他引:4
采用三维刚塑性有限元法对2S-Al板孔型立轧稳态过程进行了分析和比较,所得轧件断面形状,轧制力及轧制力矩与文献「1」的实验结果吻合很好,计算精度有所提高。 相似文献
28.
Highly Efficient Solid‐Phase Labeling of Saccharides within Boronic Acid Functionalized Mesoporous Silica Nanoparticles 下载免费PDF全文
Xianghua Pan Yang Chen Peixuan Zhao Daojin Li Dr. Zhen Liu 《Angewandte Chemie (International ed. in English)》2015,54(21):6173-6176
Labeling is critical for the detection, quantitation, and structural identification of saccharides. However, conventional liquid‐phase labeling suffers from apparent disadvantages, such as time‐consuming, the presence of excessive labeling reagent, and high applicable saccharide concentration. A solid‐phase approach is presented for highly efficient labeling of saccharides, using boronic acid functionalized mesoporous silica nanoparticles (MSNs) as a selective extraction sorbent and nanoscale reactor. The solid‐phase labeling approach exhibited several significant advantages, including: much faster reaction speed (taking only 2 min), high product purity, and much lower applicable saccharide concentration (four orders of magnitude lower than that of liquid‐phase labeling). Thus, this labeling approach opens up new avenues to the facile and efficient labeling of saccharides. 相似文献
29.
Cyclodextrin and its derivatives are widely used as selectors of chiral stationary phases (CSPs) for high performance liquid chromatography (HPLC) due to their unique molecular structure and resolution capability. Three mono(6(A)-N-(ω-alkenylamino)-6(A)-deoxy)perphenylcarbamoylated β-cyclodextrin (PICD) based CSPs with different length spacers have been prepared, with their enantioseparation abilities evaluated with 10 model racemates including aromatic alcohols, flavanone compounds, amine and non-protolytic compounds under normal-phase conditions. The effect of spacer length and surface loading on the enantioseparation performance of CSPs is investigated herewith. The results indicate that higher surface loading 6C-PICD displays the best enantioselectivities towards selected racemates under normal-phase conditions. 相似文献
30.
Chalcogenide glass fibers have been successfully used for remote spectroscopy, temperature sensing and CO2 laser power delivery. In bulk form, chalcogenide glass is the most promising candidate for replacing the expensive germanium lenses for thermal imaging. 相似文献