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21.
β-cyclodextrin (β-CD) based materials have been studied widely as adsorbents and filter membranes for removing pollutants in air or water applications. The present study aimed to develop a sandwich structure of eletrospun nanofibrous membrane based on β-cyclodextrin and PA66 to achieve the high mechanical strength and flow-through adsorption of heavy metal ions in water. The surface and cross section morphology of PA66/β-cyclodextrin/PA66 nanofibrous membranes (PA66/β-CD/PA66 NMs) were examined using scanning electron microscopy (SEM). The physicochemical and mechanical properties of PA66/β-CD/PA66 NMs were analyzed by differential scanning calorimetry (DSC), thermogravimetric (TG) analysis and universal testing machine. The diameter of β-CD and PA66 electrospun fibers are 300–400 nm and 20–40 nm respectively. PA66/β-CD/PA66 NMs show a loosely arranged fibers and layer by layer structure. The tensile strength increases remarkably for PA66/β-CD/PA66 NMs, from 1.33 MPa of β-CD NMs to 23.17 MPa and the Young's modulus increases from 34.8 MPa to 253.3 MPa. The mechanical behavior of PA66/β-CD/PA66 NMs is a typical brittle fracture, and its microcosmic fracture diagrams are also involved. TGA/DSC results confirm the thermal crosslinking reaction is effective and complete. On the basis of SEM, DSC, TG and mechanical behavior analysis results, the molecular mechanism of in situ thermal crosslinking reaction is discussed. Fe3+、Ni2+ were used to confirm the ability to absorb heavy metal ions of PA66/β-CD/PA66 NMs. In conclusion, PA66/β-CD/PA66 NMs could be a promising solution for removal of metal ions by flow-through adsorption. 相似文献
22.
Dr. Tawheed Hashem Dr. Elvia P. Valadez Sánchez Dr. Peter G. Weidler Dr. Hartmut Gliemann Dr. Mohamed H. Alkordi Prof. Christof Wöll 《ChemistryOpen》2020,9(5):524-527
High quality, monolithic UiO-66-NH2 thin films on diverse solid substrates have been prepared via a low temperature liquid phase epitaxy method. The achievement of continuous films with low defect densities and great stability against high temperatures and hot water is proven, clearly outperforming other reported types of MOF thin films. 相似文献
23.
Zirconium-based metal-organic framework materials (Zr−MOFs) have more practical usage over most conventional benchmark porous materials and even many other MOFs due to the excellent structural stability, rich coordination forms, and various active sites. However, their mass-production and application are restricted by the high-cost raw materials, complex synthesis procedures, harsh reaction conditions, and unexpected environmental impact. Based on the principles of “Green Chemistry”, considerable efforts have been done for breaking through the limitations, and significant progress has been made in the sustainable synthesis of Zr−MOFs over the past decade. In this review, the advancements of green raw materials and green synthesis methods in the synthesis of Zr−MOFs are reviewed, along with the corresponding drawbacks. The challenges and prospects are discussed and outlooked, expecting to provide guidance for the acceleration of the industrialization and commercialization of Zr−MOFs. 相似文献
24.
通过溶剂热法成功制备了一种基于金属有机骨架(MOF)的复合材料Cu-Cu2O/UiO-66-NH2,采用傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱(XPS)对材料进行全面表征。在空气作氧化剂条件下,以苯甲醇氧化为苯甲醛作为模型反应,系统地考察了溶剂、温度、催化剂各组分用量等因素对催化效果的影响。研究结果表明,该复合催化剂在醇选择性氧化反应中表现出优异的催化性能,60℃下反应5 h便可将苯甲醇定量转化为苯甲醛,并对其他苄基醇、烯丙基醇和杂芳基醇等底物也展现出良好活性。此外,循环利用3次后,该催化剂活性几乎不变,表明其具有良好的稳定性和重复使用性。 相似文献
25.
《Composite Interfaces》2013,20(2-3):113-126
Polyamide66/polypropylene (PA66/PP) blend, graphite (Gr)-filled PA66/PP composite and nanoclay (NC)-filled PA66/PP nanocomposites were prepared by twin screw extrusion and injection molding. Three-body abrasive wear behaviour of the injection moulded composites was carried out using a rubber wheel abrasion wear tester. In this study, angular silica sand and quartz particles of size ranging from 200 to 250 μm were used as dry and loose abrasives. The tests were carried out for 150, 300, 450 and 600 m abrading distances at a constant load of 36 N. It was observed that inclusion of particulate fillers in PA66/PP have significant influence on wear under varied abrading distances for different abrasive particles. Further, it was found that NC-filled PA66/PP nanocomposite exhibited lower wear rate compared to Gr filled ones for different abrasive particles. In addition, the worn surfaces of the samples were examined by scanning electron microscopy (SEM) and the morphology was also discussed. 相似文献
26.
Jacques Helmstetter 《Advances in Applied Clifford Algebras》2008,18(2):153-196
A meson algebra is involved in the Duffin wave equation for mesons in the same way as a Clifford algebra is involved in the
Dirac wave equation for electrons. Therefore meson algebras too should have geometrical properties after the manner of Grassmann.
Actually it is possible to define interior multiplications with similar properties, and deformations too. Every meson algebra
is a deformation of a neutral meson algebra, in the same way as (almost) every Clifford algebra is a deformation of an exterior
algebra. Some applications follow: the PBW-property is proved for all meson algebras, the injectiveness of Jacobson’s diagonal
morphism is proved with the minimal hypothesis, and the existence of Lipschitz monoids is established at least for meson algebras
over fields.
相似文献
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29.
Nastasia Grubic Philippe G. LeFloch Cristinel Mardare 《Journal de Mathématiques Pures et Appliquées》2014
To begin with, we identify the equations of elastostatics in a Riemannian manifold, which generalize those of classical elasticity in the three-dimensional Euclidean space. Our approach relies on the principle of least energy, which asserts that the deformation of the elastic body arising in response to given loads minimizes over a specific set of admissible deformations the total energy of the elastic body, defined as the difference between the strain energy and the potential of the loads. Assuming that the strain energy is a function of the metric tensor field induced by the deformation, we first derive the principle of virtual work and the associated nonlinear boundary value problem of nonlinear elasticity from the expression of the total energy of the elastic body. We then show that this boundary value problem possesses a solution if the loads are sufficiently small (in a sense we specify). 相似文献
30.
Invariant subspaces and eigenfunctions of regular Hecke operators acting on spaces spanned by products of even number of Igusa theta constants with rational characteristics are constructed. For some of the eigenfunctions of genuses g=1 and g=2, corresponding zeta functions of Hecke and Andrianov are explicitly calculated. 相似文献