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排序方式: 共有329条查询结果,搜索用时 15 毫秒
131.
Masanobu Janado Yuki Yano Miyuki Umura Yôtaro Kondo 《Journal of solution chemistry》1995,24(6):587-600
The partition coefficients Kav between the solution phase and octyl- and phenyl-sepharose CL-4B were determined for three cyclodextrins (CDs), -CD, -CD and -CD in various aqueous solutions, as a measure of their interactions with the two hydrophobic ligands. Kav of the CDs increased in the order of -CD<-CD<-CD for octyl-sepharose CL-4B and -CD<-CD<-CD for phenyl-sepharose CL-4B. In all cases, Kav increased by increasing NaCl concentration in the aqueous solution phase and also by lowering temperature, but in the presence of NaBr and NaSCN, both chaotropic salts, Kav decreased markedly. The spontaneity of the transfer of the CDs from the aqueous solution phases to the gel phases was due to the enthalpy decrease. It was shown that discrete separation of the three CDs can be achieved by the hydrophobic chromatography on a short column (1×25cm) of octyl-sepharose CL-4B by adjusting the NaCl concentration and temperature. 相似文献
132.
Edwin Weber George R. Newkome Frank R. Fronczek Sybille Franken 《Journal of inclusion phenomena and macrocyclic chemistry》1988,6(1):1-7
Crown amide (1) forms a stoicheiometric 1:1 inclusion complex with water, the X-ray crystal structure of which is reported. Crystals of1 · H2O are triclinic, space groupP1, witha=7.503(1),b=11.394(3),c=13.443(2) Å, =107.066(18), =96.627(10), =106.377(14)°, andZ=2.R
F
=0.039 for 1697 MoK reflections [I>3(I)] measured at 24°C. The structure features a hydrogen bonded hostguest relationship with concrete1 · H2O units. Hydrogen bonds are between the water oxygen and O(4), N(4), respectively. The crystal packing shows a cavity arrangement of four ligands around each water molecule.
Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82055 (16 pages). 相似文献
133.
Ella Kh. Kazakova Albina U. Ziganshina Liya A. Muslinkina Julija E. Morozova Nelly A. Makarova Asija R. Mustafina Wolf D. Habicher 《Journal of inclusion phenomena and macrocyclic chemistry》2002,43(1-2):65-69
The flexible bowl-type water-soluble molecule1, consisting of a resorcinol core and fourconvergent tetrasulfonatomethylene groups, existingas a tetraanion in neutral water solution, was studiedas the host molecule for recognition of-aminoacids. Out of 12 examined guestmolecules only those possessing aromatic hydrophobicmoieties or a long hydrophobic chain with a second ionogenic groupform inclusion complexes with 1. The complex formationwas considered with the help of both 1H NMRand pH-metric titration in a broad range of pH.The role of host and guest geometric complementarity aswell as additional – and hydrophobic interactionsis discussed. The lack of these interactions inaqueous media provides domination of the guestsolvation by water over the 1 : 1 complexformation with 1. 相似文献
134.
Rainer Trültzsch Jörg Beger Hans-Jürgen Buschmann Eckhard Schollmeyer 《Journal of solution chemistry》1994,23(1):53-61
The formation of complexes between crown ethers and acetonitrile, chloroform, and nitromethane were investigated in carbon tetrachloride at 25°C. A significant influence of the ring size on the selectivity of the host is evident. The host 18-crown-6 forms complexes for which the reaction enthalpy and entropy are quite high. Host molecules with benzene side groups form complexes of lower reaction enthalpy and entropy and therefore the complexes formed are less stable than that of the analogous crown ethers without aromatic groups. Solvent effects on the stability constant K, the reaction enthalpy H, and the reaction entropy S were studied for the complexation of malonitrile by 18-crown-6. The reaction enthalpy and entropy values change in accordance with the dielectric constant of the solvent used, but no overall effect on complex stability with change in solvent dielectric constant was observed. 相似文献
135.
The
search for the lowest energy conformation of complex {β-cyclodextrin
(β-CD)+chlorambucil} were carried out by molecular mechanics method.
Theoretical calculations of molecular interactions of complex were carried
out using the molecular orbital method. The correlation between energy changes
and molecular structures are discussed. The large interaction energies calculated
by the molecular orbital method bears out the inclusion phenomenon. 相似文献
136.
The syntheses, reactivity and complexing properties of cavitands are reviewed. 相似文献
137.
Anionic Antimony(III) Fluoro Complexes with protonated Azacrownethers as Counterions. Crystal Structures and Mößbauer Spectra of [H2cyclam]2[Sb4F16] · 2H2O, [H4cyclam][Sb2F10] · 2 HF, and [H4(tetramethyl)cyclam]2[Sb4F15][HF2][F]4 (cyclam = 1,4,7,11-Tetraazacyclotetradecane) The title compounds are formed by reaction of SbF3 with the respective azacrownether. [H2cyclam]2[Sb4F16] · 2 H2O contains tetrameric anions which weakly associate to chains. The [H2cyclam]2+ ions possess an unusual conformation due to intramolecular hydrogen bonds. [H4cyclam][Sb2F10] · 2HF contains the dimeric hitherto unknown [Sb2F10]4? ion; two HF molecules are attached to it by hydrogen bonds. The structure of [H4(tetramethyl)cyclam]2[Sb4F15][HF2][F]4 is made up of the two dimensional polymeric [HSb4F17]4? anion. The tetra-protonated tetramethylcyclam ions form host-guest complexes with fluoride ions. 相似文献
138.
B. T. Ibragimov K. K. Makhkamov K. M. Beketov 《Journal of inclusion phenomena and macrocyclic chemistry》1999,35(4):583-593
Crystallization of cyclotriveratrylene (CTV) from solutions in acetone at 40°C gave a new 4:1 host-guest complex instead of the conventional 2:1 clathrate (-phase) whose X-ray crystal structure was determined. Data for 2(C27H30O6) · 0.5(CO(CH3)2): monoclinic, P21/c, a = 18.942(4), b = 24.697(5), c = 10.508(2) Å, = 91.10(2)°, V = 4915(2) Å3, Z = 8, D
x
= 1.257 g/cm3, T = 293 K, R = 0.077 (for 2694 reflections). One of the two crystallographically independent CTV molecules (molecule A) is stacked into columns characteristic of the CTV - or -phase complexes. Molecules B face each other enclathrating inside around the inversion center disordered acetone molecules giving rise to the molecular capsule. The acetone molecule is H-bonded simultaneously to both host molecules by C(H2)--H ··· O type bonds forming centrosymmetric dimers. Dimers are incorporated together with two A molecules into centrosymmetric units also by C(H2)--H ··· O type H-bonds. Packing of these units gives rise to the crystal structure of the clathrate. 相似文献
139.
应用密度泛函理论对杯[4]吡咯及卤素取代杯[4]吡咯模型分子的自由主体以及其卤素离子复合物体系进行计算研究. 结果表明, 杯[4]吡咯β位被卤素拉电子基团取代后, 主体分子的构象特征受吡咯单元的偶极影响; β-卤素取代导致了杯[4]吡咯对卤素离子的结合作用增强, 且当β位为氯取代时, 杯[4]吡咯对卤素离子的结合能力最强. 并从振动光谱、NBO电荷布居、相互作用的前线轨道、“活性”构象的偶极矩和Mulliken成键布居等方面阐述β-卤素取代对杯[4]吡咯与卤素离子之间的主-客体相互作用的影响. 相似文献
140.
Jae-Kon Kim Jaehong Kim Suhee Song Ok-Sang Jung Hongsuk Suh 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):187-192
The article reports the synthesis and chiral recognition properties of a new chiral bis-pyridino-18-crown-6 (7), having urea, diphenyl, and allyloxy groups. The chiral bis-pyridino-18-crown-6 was prepared by a thirteen-steps procedure from the commercially available (S)-(+)-mandelic acid and chelidamic acid. The association constants (K
a) (1.33 × 103–3.20 × 103) for enantiomeric recognition of d- and l-amino acid methyl ester hydrochlorides using the chiral bis-pyridino-18-crown-6 have been examined by 1H-NMR titration method in CDCl3 at 25 °C. The chiral bis-pyridino-18-crown-6 showed higher association constants for the d-series amino acid methyl ester (d-AlaOMe, d-LeuOMe, d-MetOMe) hydrochlorides as compared to the corresponding l-series (l-AlaOMe, l-LeuOMe, l-MetOMe) hydrochlorides. 相似文献