某大酒店顶层环梁工程质量事故分析与处理

本文通过对某大酒店顶层环梁质量事故的分析，提出了钢筋混凝土环梁计算的力学模型，经过计算和分析，找出了环梁支座处出现裂缝的原因，并给出正确的计算结果，使事故得以及时处理     

POLYNOMIAL SOLUTIONS TO PIEZOELECTRIC BEAMS (Ⅰ)——SEVERAL EXACT SOLUTIONS

IntroductionDue to its excellent piezoelectric properties,composites made of piezoelectric materialsare found widespread applications and attracted more attentions[1-10].Because of materialanisotropy and couplingbetween mechanical deformation and electric…     

水喷射淬冷高温壁面的传热实验研究

本文采用直接表面温度测量的方法对水喷射高温壁面的传热过程进行实验研究．系统地研究了射流出口速度、冷却水过冷度、喷嘴至加热面的间距、初始壁温以及水喷雾的流量密度等参数对淬冷表面的膜态沸腾、最小临界点、过渡沸腾、最大临界点等传热过程的影响，给出了有关实验结果，分析了它们的特点。     

顶端受集中力偶的双材料平面界面接合楔体的对数奇异应力场

应用复变函数方法,通过构造复函数形式的特解序列,从理论上研究了顶端受集中力偶的双材料平面界面接合楔体的应力场,给出了相应的经典解,发现其存在一次和二次佯谬,相应的应力具有(Inr)／r2和(In2r)／r2的奇异性。     

Two Typical Examples of Scaling Ionic Partition Scheme for Estimating Correlation Energy of A2 Type Molecules

Based on the calculation results of pair correlation energy contributions of the various electron pairs in Na2 and H2NNH2 systems and the application of the scaling ionic partition scheme for symmetrical A2 type systems, the total correlation energies of Na2 and H2NNH2 have been reproduced by using this simple scheme. The two results show that the absolute deviations are within an acceptable range of error, however, in this way, more than 90% of computational work can be saved. The most attractive result in present paper is that, in these two molecules the coefficients c1 and c2 in the estimation equation can be obtained by the proportion of correlation energy of A^- to that of A^ singlet system. Therefore, it is believed that the proposed ionic partition scheme for symmetrical A2 molecules would be very useful to estimate the correlation energies of large symmetrical molecules.     

抑前胸腺肽溶液构象的2D NMR初步分析

抑前胸腺肽PTSP是一种重要的新发现的昆虫神经肽,能够在体内和体外条件下抑制促前胸腺素PTTH对蜕皮激素合成的促进作用.实验材料PTSP以固相方法合成.用2D NMR技术来考察PTSP的DMSO-d6溶液,并记录COSY,NOESY和13C HMQC-COSY谱用于构象分析.利用2D COSY和NOESY归属了1H NMR谱的全部共振峰;再利用HMQC-COSY使全部αC和βC共振峰也得到了归属.分析得到肽链的1H和13C的化学位移和质子间的NOE,结果表明PTSP在DMSO-d6中构象最有可能为无规卷曲.此构象可能是PTSP与其受体结合前,邻近前胸腺腺体细胞膜表面时的一种状态,而柔性无规蜷曲或许满足了两者正确结合的条件.     

1,2,4,6—四苯基—2—羟基—8—氮杂双环[3、2、1]辛烷的核磁共振研究

用多种核磁共振实验方法并结合其它结构信息,确定1,2,4,6-四苯基-2-羟基8-氮杂双环[3、2、1]辛烷的化学结构,并指定该化合物的核磁共振归属。