Synthesis,Crystal Structure and Electrochemical Property of a Dinuclear Manganese（Ⅱ） Complex [Mn_2（C_（12）H_8N_2）_4（C_8H_5O_4）_2]（C_8H_4O_4）·H_2O

One dinuclear manganese(II)complex [Mn2(C12H8N2)4(C8H5O4)2](C8H4O4)·H2O has been synthesized with o-phthalic acid and 1,10-phenanthroline.The crystal structure was determined by X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a = 1.17767(3),b = 1.22292(2),c = 1.35860(3)nm,α = 110.5300(10),β = 97.6140(10),γ = 93.7300(10)o,V = 1.80307(7)nm3,Dc = 1.404 g/cm3,Z = 2,F(000)= 784,the final GOOF = 1.047,R = 0.0398 and wR = 0.1038.The crystal structure of the title complex consists of one [Mn2(C12H8N2)4(C8H5O4)2]2+ cation,one uncoordinate o-phthalate anion(C8H4O4)2-and one uncoordinate water molecule.In [Mn2(C12H8N2)4(C8H5O4)2]2+,the central Mn(II)ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.     

红外反射-吸收光谱及其在表面和薄膜领域的应用

介绍了红外反射吸收技术的原理、特点、影响灵敏度的因素和光路设置，用近期研究实例介绍了该技术的应用情况     

一维链状锌配位聚合物[Zn（4，4＇-bipy）·（o-ABA）2·（H2O）2]n的合成、晶体结构及热稳定性

锌是重要的生命元素．在生物体内锌以多种形式参与代谢过程，包括糖类、脂类、蛋白质与核酸的合成与降解．对生命体系有着特殊的生物活性和催化作用。模拟合成以锌、铜等为中心离子的配位聚合物并对其结构进行研究．将为人们认识生命体系中与这些金属离子相关的生命现象提供重要的信息。4，4’-联吡啶是一种线状双基刚性配体．无支链，空间位阻少，有较好的桥联作用，     

气相色谱-质谱表征甲醇制烯烃副产汽油中的C5～C7烯烃

采用气相色谱-质谱(GC-MS)对甲醇制烯烃(MTO)副产汽油中的C5~C7烯烃进行了详细的定性表征,对MTO副产汽油中的49个单烯烃、11个二烯烃和9个环烯烃共计69个C5~C7烯烃组分在聚甲基硅氧烷柱上的保留指数进行了测定和定性确认。根据GC-MS定性分析结果建立了MTO副产汽油中C5~C7烯烃的保留指数数据库,采用气相色谱对副产汽油中C5~C7烯烃组分进行了定量分析。定量结果表明:MTO汽油以C5~C7脂肪族烯烃为主,含有少量的二烯烃和环烯烃,烷烃和环烷烃含量很少。MTO副产汽油中C5~C7烯烃的详细表征为其综合利用提供了依据。     

石墨烯/聚邻苯二胺膜修饰碳糊电极电催化性能的研究

研制了一种新型的石墨烯/聚邻苯二胺膜饰碳糊电极(GR/PPD/CPE)。在NaH2PO4-Na2HPO4缓冲溶液(pH 7.3)中,利用循环伏安法研究了对苯二酚(HQ)和邻苯二酚(CC)在该修饰电极上的电化学行为,利用线性扫描溶出伏安法研究了扫速与峰电流或峰电位的关系,利用微分脉冲溶出伏安法测定了HQ和CC的含量,线性范围分别为6.5×10-7~5.0×10-4mol/L和1.0×10-7~5.0×10-4mol/L,检出限(S/N=3)分别为8.0×10-8mol/L和2.0×10-7mol/L。方法用于自来水样中的HQ和CC的测定,回收率在96.5%~102.5%之间。     

LB膜诱导CaF2单晶的生长研究

LB膜作为模板可调控晶体的取向生长。实验中利用SEM，XRD等手段研究转移到硅基底上的LB膜诱导氟化钙单晶的生长情况。发现：在二十二烷基羧酸LB诱导下，氟化钙晶体沿（220）晶面取向生长，这一结果可利用膜与晶体之间的晶格匹配关系得到合理解释。     

Synthesis,Crystal Structure and Properties of the Cobalt(Ⅱ) Complex of Methyl-5-norbornene-2,3-dicarboxylic Acid

A new cobalt complex Co(C10H8N2)(H2O)3[C9H11O2(COO)] with methy-5-norbornene-2,3-dicarboxylic anhydride acid(MNA) and 2,2'-bipyridine as ligands has been synthesized in the mixed solvents of ethanol and water. It crystallizes in monoclinic, space group P21/c with a = 13.0430(13), b = 21.014(2), c = 7.5151(7) ?, β = 102.319(2)o, V = 2012.4(3) ?3, Dc = 1.529 g/cm3, Z = 4, F(000) = 964, GOOF = 1.051, the final R = 0.0457 and wR = 0.0974. The crystal structure shows that the cobalt ion is coordinated with four oxygen atoms from one MNA molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stability and electrochemical properties have studied in this paper.     

镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质

The complex {[Cd₂(C₉H₈O₃N)₂(CH₃COO)₂(4,4′-bipy)₂]·(4,4′-bipy)·(H₂O)₄}_n with 4-acetamidobenzoic acid and 4,4′-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals, forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4′-bipy molecules and the complex molecule forms an one-dimensional double-chain structure. The luminescent properties of the complex were studied. CCDC: 734878.     

梨果及土壤中亚胺唑及其代谢物的气相色谱分析

 介绍了杀菌剂亚胺唑及其代谢物ＩＢＣ－０１在梨果实及土壤样品内的提取、净化方法以及气相色谱的分析测定方法。保留时间：亚胺唑为３８．３６ｍｉｎ，ＩＢＣ－０１为１７．０１ｍｉｎ。变异系数：亚胺唑为０．４５％～１５．５３％，ＩＢＣ－０１为３．０３％～９．５２％。回收率：亚胺唑为８８．２８％～９８．５％，ＩＢＣ－０１为８４．９８％～９８．１３％。     

配合物Cu(3，5-DMBA)2(phen)的合成、晶体结构及电化学性质

A copper(Ⅱ) complex Cu(3，5-DMBA)₂(phen) has been synthesized by self-assembly of 3，5-dimethylbenzoic acid， 1，10-phenanthroline and copper perchlorate. Crystal data for this complex: Monoclinic， space group C2/c with a=2.348 3(5) nm， b=0.984 4(2) nm， c=1.138 4(2) nm， β=103.02(3)°， V=2.563 9(9) nm³， D_c=1.404 g·cm^-3， Z=4， F(000)=1 124， final GooF=1.051， R₁=0.035 0， wR₂=0.099 8. The crystal structure shows that the copper atom is coordinated with two oxygen atoms from two 3，5-dimethylbenzoic acids and two nitrogen atoms from the 1，10-phenanthroline， forming a square-planar structure. The result of the cyclic voltametric behavior analysis shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 650387.