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111.
K. Jin Z. C. Wang Q. Zhang 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,42(2):325-332
We study the absorption spectra of a degenerate V-type
atom, where a resonant driving field and a probe field drive
different branches of transitions and a dc field is applied to
drive the transition between two excited states. The effects of
vacuum induced coherence (VIC) on the absorption spectra are
investigated. It is demonstrated that in some special cases the
VIC can lead to the depression of absorption and narrow resonance.
The origin of these features are discussed. When the pump field
and the dc field have the same intensity, it is interesting to
find that the whole absorption spectrum comes mainly from the
absorptions induced by the interferences among different
transitions between dressed states. 相似文献
112.
X. M. Chen J. X. Shao Z. H. Yang H. Q. Zhang Y. Cui X. Xu G. Q. Xiao Y. T. Zhao X. A. Zhang Y. P. Zhang 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(2):281-286
Al K-shell X-ray yields are measured with highly charged Arq+ ions
(q=12–16) bombarding against aluminium. The energy range of the Ar
ions is from 180 to 380 keV. K-shell ionization cross sections of aluminium are also obtained from the yields data.
The experimental data is explained within the framework of 2pπ
-2pσ rotational coupling. When Ar ions with 2p-shell vacancies are
incident on aluminium, the vacancies begin to reduce. Meanwhile, collisions
against Al atoms lead to the production of new 2p-shell vacancies of Ar
ions. These Ar 2p-shell vacancies will transfer to the 1s orbit of an Al
atom via 2pπ-2pσ rotational coupling leading to the emission of
a K-shell X-ray of aluminiun. A model is constructed based on the base of
the above physical scenario. The calculation results of the model are in
agreement with the experimental results. 相似文献
113.
L. Lammich S. Altevogt H. Buhr H. Kreckel S. Krohn M. Lange D. Strasser R. Repnow M. Grieser R. Schinke Z.-W. Qu H. Zhu D. Schwalm D. Zajfman A. Wolf 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(1):103-111
The fragmentation of LiH2
- anions after electron
impact was investigated at the heavy-ion storage ring TSR.
The main reaction channel was found to be electron detachment followed by a
breakup into LiH + H.
In the first ms after production of the molecular ions in a cesium
sputtering ion source, additional
contributions were observed in the Li + H2 and Li- + H2 channels,
hinting at an initial population of a short-lived state of the anion.
To gain a better understanding of the mechanisms underlying the observed
behavior of the system, ab initio calculations of relevant potential
energy surfaces were performed at selected geometries.
The experimental findings are discussed in the
light of these calculations. 相似文献
114.
M. Gupta K. L. Baluja 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(3):475-483
Electron-H2S collision process is studied using the R-matrix method. Nine low-lying states of H2S molecule are considered in the R-matrix formalism to obtain elastic integral, differential, momentum transfer and excitation cross sections for this scattering
system. We have represented our target states using configuration interaction (CI) wavefunctions. We obtained adequate representation
of vertical spectrum of the target states included in the scattering calculations. The cross sections are compared with the
experiment and other theoretical results. We have obtained good agreement for elastic and momentum transfer cross sections
with experiment for entire energy range considered. The differential cross sections are in excellent agreement with experiment
in the range 3–15 eV. A prominent feature of this calculation is the detection of a shape resonance in 2B2 symmetry which decays via dissociative electron attachment (DEA). Born correction is applied for the elastic and dipole allowed
transition to account for higher partial waves excluded in the R-matrix calculation. The electron energy range is 0.025–15 eV. 相似文献
115.
介孔分子筛Al-MCM-41的合成与催化异构化性能 总被引:1,自引:0,他引:1
采用正硅酸乙酯(TEOS)为硅源,九水硝酸铝为铝源,十六烷基三甲基溴化胺(CTMABr)为模板剂,在室温条件下合成了介孔Al-MCM-41分子筛.通过XRD、N2等温吸附、SEM、FTIR等分析测试手段表征了分子筛的介孔结构和表面性质.结果表明所合成的分子筛有良好的介孔结构和较高的有序度,并且有较高的比表面积(达到816 m2·g-1)和窄的孔径分布.采用程序升温的焙烧方式、凝胶Al/Si比最大范围控制在0.06~0.13有利于合成高度有序的介孔Al-MCM-41分子筛.评价结果表明,所合成的Al-MCM-41分子筛对桥式四氢双环戊二烯(endo-TCD)异构化反应合成挂式异构体exo-TCD及金刚烷具有较高的催化活性和极高的选择性. 相似文献
116.
H. Ueba 《Surface science》2007,601(22):5212-5219
Adsorbate motions are discussed with a primary attention focused on the coupling between a vibrational mode excited by ultrafast laser heated hot-electrons or by inelastic tunneling electrons with scanning tunneling microscope and the reaction coordinate (RC) mode. Recent experimental results have demonstrated an efficient reaction pathways involving an indirect excitation of a frustrated translational mode, rather than its direct excitation for adsorbate hopping on surfaces. Elementary processes are briefly described for hopping of CO molecules on a laser heated stepped Pt surface, where excitation of the frustrated rotation mode has been found to plays an indispensable. Calculation of the inelastic tunneling current (ITC) for excitation of the C-O stretch mode of a CO molecule is combined with a theory of anharmonic mode coupling to activate the frustrated translation mode above the barrier. The hopping rate as a function of the bias voltage agrees with the experimental result. An unified theory of single-, and two-electron processes for ITC-induced motions induced by an indirect excitation of the RC-mode via mode coupling is also applied to reproduce a crossover from hopping to desorption of a single NH3 molecule on Cu(1 0 0) with an increase in the tunneling current. 相似文献
117.
We demonstrate that high-energy, high-resolution reflection electron energy loss spectroscopy can provide unique insights into interface formation, especially for the case where an extended interface is formed. By changing the geometry and/or electron energy the electronic structure can be probed over a range of thicknesses (from 10s of Å to more than 1000 Å). At the same time one resolves the elastically scattered electrons into different components, corresponding to scattering of atoms with different mass (so-called ‘electron Rutherford backscattering’). Thus these high-energy REELS/elastic scattering experiments obtain information on both the electronic structure and the atomic composition of the overlayer formed. 相似文献
118.
在中性原子的磁囚禁实验中,磁阱线圈的电流噪声会激发磁阱中的原子运动,势必对原子团的温度和寿命产生不可忽视的影响。对于非简谐阱,这种激发具有能量选择特性,它又取决于电流噪声的频谱分布。选择了实验中常用的四极阱为研究对象,用直接模拟蒙特卡罗方法来模拟四极阱中原子运动的参变激发现象,得到了原子温度与原子数损失随激发频率的变化关系,并进一步计算了两个共振峰处原子温度随调制时间和调制深度的变化曲线。此外,还研究了弹性碰撞速率对参变激发过程中原子温度上升的影响。这些结果对四极阱参变激发的实验有较好的参考价值。 相似文献
119.
Strong photoluminescence (PL) covering the green-violet band was measured at room temperature in an as-deposited amorphous Si-in-SiNx film, which was prepared by plasma-enhanced chemical vapor deposition on cold (below 60 °C) Si(1 0 0) wafer. With an increase in photon energy of excitation, the PL shifts its peak position from 510 to 416 nm at yet-comparable intensities, thus allowing an energy-selected excitation in practical application. Also, a time-resolved analysis was performed for the emissions at various wavelengths, which showed a decay time shorter than 1.0 ns. These results indicate that the nanostructured Si-in-SiNx can be a promising candidate material for the fabrication of silicon-based optical interconnections and switches. 相似文献
120.
B. Witzel N.A. Papadogiannis D. Charalambidis 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,12(1):21-25
A new device for charged particle coincidence experiments in strong-field, short pulse laser-atom/molecule interactions is
presented. The device consists of a single time of flight spectrometer, common for both positive and negative charge detection.
Experimental parameters required for the use of the device in the high intensity regime are discussed. A demonstration of
electron-ion coincidence measurements in the interaction of Xe atoms with 60 fs laser pulses at 800 nm and an intensity of
W/cm2 is reported.
Received 22 November 1999 相似文献