全文获取类型
收费全文 | 22690篇 |
免费 | 7069篇 |
国内免费 | 15955篇 |
专业分类
化学 | 26720篇 |
晶体学 | 2042篇 |
力学 | 1144篇 |
综合类 | 729篇 |
数学 | 1675篇 |
物理学 | 13404篇 |
出版年
2024年 | 182篇 |
2023年 | 834篇 |
2022年 | 965篇 |
2021年 | 1254篇 |
2020年 | 925篇 |
2019年 | 1190篇 |
2018年 | 907篇 |
2017年 | 1181篇 |
2016年 | 1332篇 |
2015年 | 1430篇 |
2014年 | 2083篇 |
2013年 | 2404篇 |
2012年 | 2288篇 |
2011年 | 2222篇 |
2010年 | 2117篇 |
2009年 | 2176篇 |
2008年 | 2323篇 |
2007年 | 2143篇 |
2006年 | 2419篇 |
2005年 | 2341篇 |
2004年 | 2273篇 |
2003年 | 2066篇 |
2002年 | 1612篇 |
2001年 | 1430篇 |
2000年 | 930篇 |
1999年 | 846篇 |
1998年 | 649篇 |
1997年 | 480篇 |
1996年 | 479篇 |
1995年 | 385篇 |
1994年 | 368篇 |
1993年 | 238篇 |
1992年 | 274篇 |
1991年 | 305篇 |
1990年 | 253篇 |
1989年 | 247篇 |
1988年 | 82篇 |
1987年 | 31篇 |
1986年 | 14篇 |
1985年 | 32篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
111.
112.
温度对PSⅡCP4 7/D1/D2/Cytb559复合物荧光光谱特性的影响 总被引:3,自引:3,他引:0
采用激励光源为514.5 nm的分幅扫描单光子计数荧光光谱装置对经20℃、42℃和48℃不同温度处理后的反应中心复合物CP47/D1/D2/Cyt b559的荧光光谱特性进行了研究.经解析,获得不同温度处理后,CP47/D1/D2/Cyt b559复合物最大峰值未发生变化,均在682 nm,说明Chla670的能量都由Chla682接收,但损耗愈来愈小,在48℃时,损耗程度最小,而其荧光百分比未发生多大变化.振动副带~700 nm和~740 nm的中心波长都发生蓝移,在不同温度下分别为:20℃ 703 nm,749 nm;42℃ 697 nm,744 nm;48℃ 694 nm,740 nm.因此可以推测温度的升高,影响了CP47/D1/D2/Cyt b559色素蛋白的二级结构以及色素分子的空间位置,使最大峰值处的荧光强度逐渐降低,振动副带逐渐蓝移.42℃的温度已造成影响,48℃影响较大. 相似文献
113.
114.
Monte Carlo (MC) simulations are used to simulate the voltage profile and the ionic conductivity s of Li ions in LixMn2O4 and its dependence on the lithium concentration x. The open circuit potential shows clearly the two plateaus in the charge/discharge curve, which agrees well with the experimental results. The two plateaus become more and more steep when the temperature is increased. The simulated ionic conductivity shows an M-shaped curve in the plot of ionic conductivity cr versus x when the simulation temperature is low. Interestingly,the minimum valley, which lies at the middle single-phase area near x=0.5, disappears gradually when the temperature increases to 453K. 相似文献
115.
116.
Theoretical Analysis of Characteristics of GaxInl—x NyAsl—y/GaAs Quantum Well Lasers with Different Intermediate Layers 下载免费PDF全文
Based on the band anticrossing model, the effects of the strain-compensated layer and the strain-mediated layero n the band structure, gain and differential gain of GalnNAs/GaAs quantum well lasers have been investigated. The results show that the GaNAs barrier has a disadvantage in increasing the density of states in the conduction band. Meanwhile, the multilayer quantum wells need higher transparency carrier density than the GalnNAs/GaAs single quantum well with the same wavelength. However, they help to suppress the degradation of the differential gain. The calculation also shows that from the viewpoint of band structure, the strain-compensated structure and the strain-mediated structure have similar features. 相似文献
117.
A novel super-hydrophobic stearic acid (STA) film with a water contact angle of 166o was prepared by chemical adsorption on aluminum wafer coated with polyethyleneimine (PEI) film. The micro-tribological behavior
of the super-hydrophobic STA monolayer was compared with that of the polished and PEI-coated Al surfaces. The effect of relative
humidity on the adhesion and friction was investigated as well. It was found that the STA monolayer showed decreased friction,
while the adhesive force was greatly decreased by increasing the surface roughness of the Al wafer to reduce the contact area
between the atomic force microscope (AFM) tip and the sample surface to be tested. Thus the friction and adhesion of the Al
wafer was effectively decreased by generating the STA monolayer, which indicated that it could be feasible and rational to
prepare a surface with good adhesion resistance and lubricity by properly controlling the surface morphology and the chemical
composition. Both the adhesion and friction decreased as the relative humidity was lowered from 65% to 10%, though the decrease
extent became insignificant for the STA monolayer.
The project supported by the National Natural Science Foundation of China (50375151, 50323007, 10225209) and the Chinese Academy
of Sciences (KJCX-SW-L2) 相似文献
119.
《应用化学》2004,(12)
Oxazolineshavedemonstratedwideutilityinvariouschemicalfields,suchasinasymmetricsynthesis,asaco ordinationligand ,inmedicinalandmacromolecularsynthesis ,andasaprotectinggroupofcarboxylicacids[1~ 3] .Variousmethodshavebeenadvancedforthepreparationof 2 oxazolinesfromthereactionofβ aminoalcoholswithcarboxylicacids,esters,nitriles ,oraldehydessinceitsappearance[1~3] .Reagentssuchascomplexesorstrongacidsorbaseswereusuallyneededinthesevarioussyntheticmethods.Thereactiontakeslongtimetocompletion .… 相似文献
120.
用量子化学从头算方法在B3LYP/6 311G 的水平上 ,研究了RuH2 和RuN2 可能的电子组态和光谱性质 .结果表明 ,RuH2 的3 B2 和5Σ-态对应于静电作用的物理吸附态 .RuN2 的一重态和三重态的计算结果跟钌单晶面上的实验值相接近 .而RuN2 在C∞v对称性时 ,五重态5Σ-的计算频率比实验值稍低 .在C2v对称性时 ,五重态的计算频率值则更低 ,3 B2 和5A1态不能稳定存在 相似文献